马来西亚索谷地区Ketobong金矿地质地球化学特征

总结Ketobong金矿地质特征,对矿床围岩微量元素、稀土元素及氢、氧同位素地球化学特征进行了分析研究.结果表明:有利的地质背景是宏观控矿因素,矿体受近南北向断裂控制作用明显;Ag、Pb、Zn、Cu可作为找矿指示元素;成矿物质来自赋矿地层;围岩稀土总量较高,属轻稀土富集型,具弱负铕异常;成矿流体源自变质水;矿床为与韧性剪切带有关的热液型金矿床.     

江苏甘家巷铅锌矿区稀土元素地球化学特征及指示意义

对江苏南京甘家巷矿区铅锌矿床不同类型岩石和矿石的稀土元素地球化学特征进行研究,探讨了岩石和矿石中稀土元素地球化学行为。结果显示：矿床中稀土元素的分布较为一致;甘家巷矿区稀土元素总量变化大,总体来看,稀土总量在铅锌矿石、底砾岩和粉砂岩中相对富集;在稀土元素配分模式图上,轻稀土相对富集,稀土配分曲线向右缓倾,轻稀土元素随原子序数的增加富集程度降低,重稀土元素分布比较平坦。相对较稳定;稀土元素地球化学特征指示甘家巷矿区为受F₂断裂和不整合面控制的中低温热液矿床。     

河南嵩县下蒿坪金矿地球化学特征及成因探讨

下蒿坪金矿南邻区域性大断裂和燕山晚期花岗岩基,西邻店房中型隐爆角砾岩型金矿,矿区内构造及脉岩发育,成矿地质条件良好。稀土元素分析结果显示,样品具有较高的稀土总量,矿石的稀土平均值达207.7×10~(-6),LREE/HREE为6.81~14.19,轻稀土富集,轻重稀土分异明显,其中金矿石的δEu为0.49~1.37,变化于亏损至富集的2个端元。从合峪岩体→金矿石→爆破角砾岩,稀土总量逐渐增加,暗示成矿热液对岩浆岩的后期影响。微量元素分析结果显示Au、Pb、Cd、Bi、Ag、Cu、As和Zn等亲硫元素高度富集,反映富硫还原的成矿环境。黄铁矿中Pb同位素特征显示物质来源单一,同位素指标与燕山期花岗岩十分接近。矿床成矿时间为(129±45)Ma,与合峪岩体时代相近,暗示与花岗岩有成因联系。     

西华山钨矿床流体包裹体的稀土和微量元素特征

为探讨西华山钨矿床流体的稀土元素和微量元素特征,明确热液和成矿物质的来源,揭示成矿流体性质,采用高精度电感耦合等离子质谱（ICP—MS）方法对该矿石英脉流体包裹体的微量和稀土元素进行了分析测试。结果表明,流体包裹体中稀土元素总量变化大,主要表现为轻稀土富集,轻、重稀土内部分异程度不均一,轻稀土分馏程度明显大于重稀土分馏程度;δEu变化范围比较大,大部分样品表现为δEu的负异常;微量元素之间的比值反映出西华山钨矿床成矿物质从深源到浅源,主要来源于岩浆,同时又有少部分来源于大气水循环作用淋滤围岩地层所产生的矿物质,成矿流体处于流体演化的晚期热液低温阶段。     

广西东桥锑矿地球化学特征及成因探讨

罗富东桥锑矿位于江南台背斜与滇桂台向斜之间的坳陷带,丹池大背斜之次级褶皱罗富背斜中段的北东翼,隶属于丹池成矿带中,矿体产于泥盆系地层中,严格受断裂构造控制,矿物组合特征显示典型的低温热液脉状矿床特征.文章在综合分析成矿地质背景和研究矿床地质、地球化学特征基础上,探讨了罗富东桥锑矿床的成矿条件.地球化学研究表明:围岩与成矿元素的关系密切,是矿区锑矿的物质的重要的基础,罗富锑矿矿石和围岩、稀土元素的配分模式类似,指示了成矿物质有来源于围岩地层的可能性.流体包裹体表明:本矿区石英流体包裹体的形成温度变化范围不大,均一温度在170~230℃,属于中低温热液成矿;成矿流体的盐度变化范围在2.47!~7.39!,主要集中于5.1!左右,为低盐度;流体密度变化范围值为0.790.94~0.99 g/cm3,均值为0.87 g/cm3,为中低等密度;结合以上数据罗富东桥矿区属于中低温热液矿床.     

渣滓溪锑矿床地质特征

矿床位于寻峰弧形构造带中段西南侧，产于２条ＮＥ向断裂所夹持的上升断块内，板溪群五强溪组浅变质的火山－沉积岩系为主要赋矿围岩，矿脉具有成群成带，近于等间距分布特点，其独特的侧伏延伸规律具有普遍意义，矿床属中低温热液充填锑矿床，考虑到在“锡矿山式”锑矿难于发现的情况下，这类锑矿应是湖南省锑矿的重点找矿对象。     

康定大渡河金矿田稀土元素地球化学特征研究

大渡河金矿田是西南地区重要的金成矿集中区,在该区开展稀土元素地球化学特征研究,可为揭示大渡河金矿田成因提供一定的依据。通过含矿石英脉体与围岩的稀土元素特征来探讨康定大渡河流域金矿床的成矿物质及流体来源。采集相关岩矿石样品,测试其稀土元素组成。研究表明,岩矿石均具有轻稀土富集的特征,这是地幔流体作用成矿的标志。含矿脉石英δEu值小于1,是金矿的主要赋存地质体,闪长岩、花岗岩和角闪岩δEu值小于1或约等于1,构成金脉围岩体系。闪长岩、花岗岩和角闪岩稀土配分曲线比较平缓,轻重稀土元素分馏不明显,说明黄金矿矿体与早期围岩无关,属于后期填充,成矿与中新生代造山过程有关。而源于地幔流体的含矿脉石英以及围岩花岗岩具有与地壳相似的稀土元素特征,说明成矿过程中发生了强烈的壳幔物质交换混染。多数样品中Eu亏损并未见Ce异常情况,这说明大渡河金矿床的成矿流体及围岩形成环境具有中高温并且相对氧化性的特征,表明了大渡河金矿床的成矿流体可能属于源于地幔的中高温热液流体。     

下庄铀矿田微量元素和稀土元素地球化学特征

下庄铀矿田是我国最大的花岗岩型铀矿田,本文在详细的野外勘察基础上,对矿田下庄岩体、帽峰岩体以及不同矿化类型(硅化碎裂岩型、蚀变碎裂花岗岩型和碱交代型)矿石的微量元素和稀土元素进行系统分析。结果表明,下庄岩体和帽峰岩体富集大离子亲石元素Rb和稀土元素Ce、Sm、Y,明显亏损Ba、Sr和轻微亏损Nb、Ta,具有较高的Rb/Sr比值和较低的Nb/Ta比值,表明下庄岩体和帽峰岩体高度成熟的地壳演化特征。硅化碎裂岩型和碎裂蚀变花岗岩型矿石Zr亏损明显,反映矿石形成过程中有地壳物质混染;各类型矿石稀土总量ΣREE、Sm-Nd图解、轻-中-重稀土元素三角图解反映出成矿流体运移过程中萃取了不同岩石中的稀土元素,矿石稀土元素主要继承了围岩中稀土元素特征,铀矿田成矿过程处于一个连续的热液体系中。     

滇黔桂地区不同成矿温度热液金矿床磷灰石矿物化学特征：兼论卡林型金成矿流体来源特殊性

滇—黔—桂地区是我国重要的金成矿区之一，分布有众多高温岩浆热液型金（铜）矿床和低温热液型金矿床，但这些矿床的成矿物质来源和形成过程仍存在争议。通过对高温岩浆—热液型金（铜）矿床（姚安金矿床和普朗金铜矿床）和低温卡林型金矿床（八渡和泥堡）中的热液磷灰石进行微量元素统计分析发现：高温富碱斑岩型金（铜）矿床中的磷灰石自形程度较好，具有较高的F和Cl含量，稀土元素呈轻稀土富集，重稀土亏损；相对而言，低温卡林型金矿床中产出的磷灰石自形程度较差，具有相对较低的F和Cl含量，稀土呈中稀土富集模式。另外，磷灰石δEu-δCe图解和球粒陨石标准化稀土元素配分模式揭示卡林型金矿床相对于岩浆热液型铜、金矿床具有更高的氧逸度。结合右江盆地辉锑矿稀土元素地球化学分析，认为磷灰石（包括萤石和方解石）中稀土（MREE）富集特征指示低温成矿流体可能与特殊的盆地基底岩石存在一定联系。综合分析认为：磷灰石在高温—中低温金矿床中具有独特的地球化学特征，能够有效揭示矿床类型及成矿流体演化过程。     

河南双槐树—朱阳关韧性剪切带型锑矿地质特征及控矿规律

河南双槐树—朱阳关韧性剪切带地处华北地台和扬子地台过渡地带,其次级及分枝韧性剪切带控制着区内锑矿床(点)的产出。以王庄锑矿和大河沟锑矿为例,对韧性剪切带型锑矿床地质特征进行了概括;通过研究锑矿床与韧性剪切带的空间分布,认为在脆—韧性变形阶段,引起成矿反应,形成锑的沉淀,并沿糜棱面理的微张裂隙,成矿热液与围岩产生交代作用,形成浸染型矿化;在脆—韧性剪切带活动后期,已矿化的脆—韧性剪切带受区域张应力作用脆性破碎,加速矿质的晶出和分异。     

Rare Earth Element Geochemistry on Magmatic Rocks and Gold Deposits in Shizishan Ore-Field of Tongling, China

REE geochemical characteristics of the magmatic rocks and gold deposits in Shizishan ore-field of Tongling were studied. Three types of the magmatic rocks have almost the same chondrite-normalized REE patterns, Eu and Ce anomalous values, and ∑REE, ∑LREE/∑HREE regular changes, which indicates that their magmas come from the same source and their digenetic mechanism is fractional crystallization. In three gold deposits, the mineral ores and related altered rocks have similar chondrite-normalized REE patterns and sharp Eu positive anomalous values. The REE contents reduced from the magmatic rocks to skamization or alteration magmatic rocks, skam type ores, sulphide type ores, wall-rocks limestone or marble. The REE geochemical characteristics of the ores and related rocks show that primary fluids originated from magmatic differentiation in lower pressure of shallow crust, ore-forming hydrothermal solutions gained REE and mineralization elements further from leaching the magmatic rocks, then superimposed and reformed the limestones or marbles and deposited ore-forming material.     

Geochemical characteristics of rare earth elements and their implications for the Huachanggou gold deposit in Shaanxi Province, China

The Huachanggou gold deposit is located in the south part of the Mian-Lue suture zone in the Qinling orogenic belt. Rare earth element (REE) concentrations determined by ICP-MS are shown to characterize the ore samples and their wall rocks in three ore zones in order to reveal the origin of ore-forming materials and fluid. In AuI, REE chondrite normalized patterns of ore are similar to those of ore-controlling spilite; the ore-forming materials originated from deep magma, and magmatic activity offered main hydrothermal source for gold mineralization. The REE characteristics of AuII and AuIII are similar, and most of the ore samples are similar with the wall rocks. The ore-forming fluids of AuII and AuIII were metamorphic hydrothermal fluids which had extracted ore-forming materials part from the wall rocks, and part from the spilite in AuI.     

甘肃枣子沟金矿床稀土元素地球化学特征

对比研究了枣子沟金矿区内不同类型矿石与成矿有关的岩浆岩及地层的稀土元素地球化学特征,借以示踪成矿物质来源。研究表明,矿床不同类型矿石的稀土元素配分曲线既有相似又有差别,反映成矿物质具有多样性;矿石与容矿岩石（地层、岩浆岩）稀土元素配分曲线颇为相似,总体呈右倾型,具Eu负异常。表明成矿与容矿岩石（地层、岩浆岩）具有一定的成因联系。成矿物质来源于壳源及壳幔混合。地幔流体可能参与了矿床成矿作用。成矿环境表现为早期还原,晚期由还原向氧化转化。     

Rare earth element geochemical constrains on metallogeny of Jiapigou gold belt, Northeast China

Analyses of rare earth elements (REE) in gold-bearing quartz vein, granite and altered wall-rock (amphibolite) collected from Jiapigou gold belt in Southeast Jilin Province were conducted using inductively coupled plasma-mass-spectrometry (ICP-MS). The results in- dicated that the Jiapigou gold belt underwent two periods of gold mineralization: the earlier mineralization was related to the intrusion of Neoarchaean kaligranite, where the REE of earlier gold-bearing quartz veins and Neoarchaean kaligranites were typically featured by lower concentration and positive Eu anomaly; the later mineralization was related to the intrusion of the Yanshanian granite in Mesozoic, where the REE of later gold-bearing quartz veins and Yanshanian granites were typically featured by high concentration and negative Eu anomaly. However, the metallogenic mechanisms of the earlier and of the later gold mineralization periods were analogous, metallogenic materials were heterogenous with metallogenic fluids which mainly originated from magmatic hydrothermal fluids, mixed with metamorphic fluids; the metallogenic materials were mainly derived from the altered wall rock.     

Contrasting REE Signatures on Manganese Ores of Iron Ore Group in North Orissa, India

The distribution pattern of Rare Earth Elements （REE） in three categories of manganese ores viz. stratiform, stratabound-replacement, and detrital of Precambrian Iron Ore Group from north Orissa, India was reported. These categories of Mn-ore differed in their major and trace chemistry and exhibited contrasting REE signature. The stratiform ores were relatively enriched in ∑REE content （697 μg·g^-1） and their normalized pattern showed both positive Ce and Eu anomalies, whereas the stratabound-replacement types were comparatively depleted in ∑REE content （211 μg·g^-1） and showed negative Ce and flat Eu signatures. The detrital categories showed mixed REE pattern. The data plotted in different discrimination diagrams revealed a mixed volcaniclastic and chemogenic source of material for stratiform categories, and LREE （Light Rare Earth Elements） and HREE （Heavy Rare Earth Elements） are contributed by such sources, respectively. In contrast, the stratabound ore bodies were developed during the remobilization of stratiform ores, and associated Mncontaining rocks under supergene condition followed by the redeposition of circulating mineralized colloidal solutions in structurally favorable zones. During this process, some of the constituents were found only in very low concentration within stratabound ores, and this is attributed to their poor leachability/mobility. The detrital ores did not exhibit any significant characteristic in respect of REE as their development was via a complex combination of processes involving weathering, fragmentation, recementation, and burial under soil cover.     

云南镇沅老王寨金矿床地质特征及成因探讨

作为哀牢山金矿带北段的典型矿床,老王寨金矿床空间上位于北西向脆韧性剪切带与东西向逆冲脆韧性剪切带交汇部位,北西向脆韧性剪切带、不同时代的中酸性浅成侵入体、基性和超基性岩侵入体以及哀牢山群变质岩系与金矿体具有密切的时空及成因联系。矿石中石英的流体包裹体分析表明,金矿的成矿流体主要为中低温、低盐度的NaCl-H2O体系。结合同位素、成岩成矿年代的研究认为,成矿物质及成矿流体均主要来自深部的上地幔或下地壳,金的大规模成矿与喜山期深部岩浆作用密切相关。     

Geochemical Characteristics of Rare Earth Elements in Gejiu Tin Polymetallic Deposits, Yunnan Province, China

In order to get a better understanding of metallogeny, the geochemical characteristics of REE and trace element for Gejiu tin polymetallic deposits were studied by comparing concentrations of REE and trace elements in different type ores and rocks, including skarn-type ore, bedded-type ore, vein-type ore, altered granite, country rocks. Results of this study indicated that the metallogenic matters for different type ores in the study area might be derived from the same origin source, which may be mainly related to granitic activities. Furthermore, there are some differences in concentrations of REE in different ores due to their different depositiona! mechanism during that time. LREE concentrations were enriched relatively in the vein-type ores and the bedded-type ores with relatively low total REE concentrations, whereas total REE concentrations were higher in the skarn-type ores with LREE and HREE concentrations in wide variation ranges.     

韧性剪切变形条件下花岗岩中稀土元素变化特征研究

本文对郯庐断裂带南段安徽境内管店花岗岩及其韧性剪切带中的糜棱化岩石进行了主要元素和稀土元素的研究。在详细的野外工作基础上,由岩体向韧性剪切带中心系统测量地质剖面并采集有代表性的岩石样品进行室内分析研究。分析结果显示,随着岩石受剪切变形作用的加强,稀土元素呈富集的趋势。各岩石球粒陨石标准化图解表现为右倾型,即轻稀土富集型。轻稀土也是随着岩石变形作用的加强而较重稀土元素富集。全文详细探讨了韧性剪切变形作用条件下岩石中稀土元素的活化转移的原因,我们认为变质－变形－流体渗滤的联合作用是导致岩石中稀土元素活化转移的主要因素。