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选用了我国适于液化的褐煤──可保褐煤为原料,在半连续装置上,以甲苯、水及水/一氧化碳体系中加入少量氢氧化钠为溶剂进行超临界萃取研究。萃取物分离成油、沥青烯及前沥青烯三个族组分。GC/FTIR的分析结果表明,可保煤水萃取产物主要是含氧有机物、少量的烃类及烃类衍生物。在水/一氧化碳体系中加少量氢氧化钠催化剂萃取的产物主要是烃类及其衍生物。 相似文献
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《合成材料老化与应用》2017,(5)
费托合成是煤炭间接液化的核心反应,生成烃类产品的同时产生大量的反应水以及含氧有机物,包括醇、醛、酸、酮、酯等,对这些含氧有机物组分分析手段有气相色谱、气相色谱-质谱联用、离子色谱等;含氧有机物的分离回收无论是对间接液化技术的经济效益还是对环保都具有重要意义。该文综述了现有费托合成水相中含氧化合物的分析和分离研究,并指出了产品分析标准建立的迫切性和反应水分离工艺研究的重要性。 相似文献
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为有效脱除褐煤中含氧官能团,采用超临界乙醇工艺处理胜利褐煤,研究温度、停留时间和醇煤质量比对胜利褐煤脱氧效果的影响,并利用FT-IR和GC/MS对固液相产物进行表征。结果表明,胜利褐煤超临界乙醇脱氧的最佳工艺条件为:温度270℃,停留时间90 min,醇煤质量比5∶1,此时煤样总氧含量为9.29%,脱氧率为61.40%,固相产率为89.62%。在220℃得到的液相产物中,80%左右为芳香族类化合物,酚类和酯类含氧化合物体积分数低于5%,其他含氧类化合物11.29%。270℃得到的液相产率中芳香族类化合物体积分数降低31.69%,含氧类化合物体积分数增加2.81%,酚类和酯类含氧化合物增至35%左右。褐煤经超临界醇解后,乙醇与煤分子作用发生了醚氧桥键的断裂反应,煤分子发生了脱羧反应,液相产物中含有大量酚类(主要为苯酚及其取代物)和酯类(主要为乙酯类)。 相似文献
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以冷溶剂收集法捕集卷烟主流烟气气相成分,利用气相色谱/质谱联用仪对卷烟主流烟气气相成分进行了分析.分离和鉴定了93种化合物,其中烃类29种、醛类9种、酮类23种、醇类5种、酸类2种、酯类1种、含氮化合物12种、含氧杂环化合物10种、含硫化合物2种. 相似文献
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采用微板流路控制Deans Switch中心切割技术、双火焰离子化检测器的双柱气相色谱系统,建立了测定液化石油气中甲缩醛等多种含氧化合物的方法。在优化的色谱条件下,将适量试样直接注入气相色谱仪中,通过阀的两次切换,将强极性的含氧化合物组分从非极性柱导入到极性柱,使得甲缩醛、二甲醚、甲基叔丁基醚、丙酮、甲醇、乙醇、丙醛和丁醛共9种含氧化合物与液化石油气中烃类组分完全分离。结果显示,甲缩醛等9种含氧化合物在0.01%(v/v)~5.0%(v/v)范围内呈现良好的线性,相关系数均大于0.99,样品重复测定5次,相对标准偏差小于3%,加标回收率在92.11%~104.40%之间,含氧化合物检出限可达0.0003%(v/v)~0.0021%(v/v)。 相似文献
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Joy Mukherjee Ashis Kumar Adak Samit Khan Shrawan Kumar Abhijit Sarkar 《Solid Fuel Chemistry》2010,44(5):299-304
The recent and possible future shortages of petroleum-derived hydrocarbons for use as starting materials for the synthesis
of organic chemicals/products have stimulated renewed interest in the use of coal as raw material for chemical production.
Oxidatively solubilized coal and or lignite (OSC) in alcohol is a potential substitute for value added carbo-chemicals of
the future. Phenomenal increase in the solubility of lignite in organic solvent consequent on treatment with dilute nitric
acid under mild conditions was considered to be an expedient pathway for its direct utilization. The primary requirements
for the solubilization are generation of functional groups like free carboxyl groups and size degradation. For the desired
product the reaction should also be guided in such a manner, so that the aromatic/hydroaromatic moieties of the coal/lignite
are preserved. The present study aims at the selection of the required reaction parameters for the conversion of lignite to
such a product. Characterization of the original lignite and the products have been done chemically and spectroscopically.
FT-IR, 13C (solid state) and 1H NMR spectra have shown that substances posses both aromatic and aliphatic characteristics. The dominant functional groups
which contribute to the reactivity of the substances are phenolic and carboxylic acids. 相似文献
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《Fuel Processing Technology》2006,87(9):829-839
Structural features of a South Moravian lignite and its humic acid (HA) fraction were studied by means of UV–vis, 1H and solid-state 13C NMR, and FT-IR spectroscopy in addition to basic elemental analyses. The structural differences between the original lignite and its HA-type fraction were relatively minor, and their unambiguous differentiation into distinct categories was possible only by statistical methods. The tested model functions speak strongly for the importance of choosing enough sensitive and meaningful structural parameters which most likely reflect the character or type-rank of the coal-like carbon in question. The results verified that certain aliphatic compounds have their special tasks in the complicated structural network of lignite HA material, and powerful aprotic solvents are needed to obtain a fully dissolved HA solution. Despite some organic material was lost during different effective washing purification operations, the purified lignite HA was typified without significant loss of structural information on the original HA fraction. FT-IR experiments correlated well with those obtained by 13C NMR. From environmental points' of view, some water soluble organic trace components released from the original lignite material may be potential troublemakers within the area surrounding the deposit. 相似文献
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Ronald W. Rousseau James K. Ferrell Robert M. Kelly 《Chemical Engineering Communications》1985,34(1):27-35
Experience with the operation of a pilot-scale unit is used to outline potential difficulties in the operation of acid gas removal systems on gases produced from coal. The pilot plant has been used to condition gases produced from subbituminous coal, devolatilized char, peat and lignite. The solvent used in the acid gas removal system has been refrigerated methyl alcohol. Data from this study document accumulation of hydrocarbons, sulfur and nitrogen compounds, and mercury in the circulating solvent. 相似文献
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《Fuel Processing Technology》2002,79(3):233-237
One investigated way to prepare selective adsorbents towards mixtures of volatile organic compounds (VOCs) is to modify lignite by nitrogen-enrichment. These chemically modified coals are prepared by condensation of urea with the lignite before the carbonization/activation steps. This study describes a set of analytical tools able to explain in term of surface composition and of quantitative molecular interaction parameters the evolution of the selective behavior of three adsorbents. For this purpose, the evolution of the surface chemistry and the selectivity with three percentage of burn-off of a nitrogen-enriched lignite is followed by infrared and X-ray photoelectron spectroscopies and gas chromatography (GC)/linear solvation energy relationship (LSER) method. Then, the selectivity of these materials towards two test-pairs of VOCs is discussed. This QSBR investigation reveals the complementarity of these methods linking composition data of the active carbons and their selective properties. 相似文献
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Model organic compounds have been subject to hydrogenolysis reactions using CO and H2O under industrial conditions as used for lignite and residual oil. Twenty-eight compounds, including diphenylmethane, indane, tetralin, anthracene, diphenyl ether, indene, benzophenone and xanthene were used. The purpose is to study the hydrogenolysis behaviour of compounds with structures as found in coal and residual oil. Using a Co-Mo catalyst, scission of the CC chain connecting two aromatic rings is enhanced by increased chain length of the molecule. Ether bonds are broken more easily than CC bonds. With the exception of decalin, cyclic CC bonds are more resistant to cleavage than linear bonds. Alcohol hydroxyl, and carbonyl groups of stilbene are the easiest to reduce but phenolic hydroxyl groups are stable. The Co-Mo catalyst promoted hydrolysis of ether bonds as well as hydrogenolysis. The method of the study is considered to be more effective for hydrogenolysis of organic compounds than the reported use of alkali and tetralin because of milder reaction conditions which are required. 相似文献
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J. Arul Leo Bastin N. Krishnamurthy D. Madhavan P. Vallinayagam M. Palanichamy A. Chellamani 《Solid Fuel Chemistry》2017,51(4):256-266
The study of macromolecular structure of coal has been subjected to intense research. Neyveli lignite was depolymerized using phenol and phosphotungstic acid and the resultant product was subsequently alkylated. The t-butylated depolymerized lignite exhibited enhanced extractability in organic solvents. The t-butylated depolymerized lignite was fractionated into different components using column chromatography (CC). Three major compounds were isolated and were characterized by FTIR, 1H NMR and Mass spectral techniques. 相似文献
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The influence of demineralisation and ammoxidation on the adsorption properties of an activated carbon prepared from a Polish lignite 总被引:1,自引:0,他引:1
Julien Starck Sebastien Muller Guy Furdin Cathie Vix_Guterl Pierre Faure 《Carbon》2006,44(12):2549-2557
The preparation of cheap nitrogen-enriched materials with large adsorptive capacities and selectivity towards volatile organic compounds remains a challenge. Ammoxidation has been used to prepare nitrogen-enriched activated carbons using a demineralised Polish lignite. The lignite samples were demineralised by two different methods before nitrogen-enrichment by ammoxidation and physical activation in steam. The surface chemistry was investigated by elemental analysis, Boehm titration, infrared and XPS spectroscopies and adsorptive properties by a linear solvation energy relationship approach. Results show a quasi-total demineralisation and a higher reactivity towards nitrogen for the demineralised samples. The BET surface is also higher than for the non-demineralised lignite. Active carbons previously ammoxidated and demineralised are more interesting in terms of selective removal of gaseous pollutants. 相似文献