印刷油墨清洗剂的研究及开发进展

印刷油墨清洗剂是印刷行业用来清除印刷油墨的一种精细化学品。文章对传统的汽油、煤油类印刷油墨清洗剂及混合溶剂型,乳液、微乳液型,水基、半水基型,天然成分环保型等新型印刷油墨清洗剂的研究及开发进展进行了综述;概括分析可知传统汽油、煤油类印刷油墨清洗剂,对环境、工作人员的健康有严重的影响,环境友好、安全性高且质优价低是新型油墨清洗剂的研制目标。     

新型油墨清洗剂的研制及其应用研究

成功地研制了一种新型、高效、安全、低成本的油墨清洗剂,克服了直接使用溶剂而带来的易燃、易爆的缺点.此油墨清洗剂是由乳化剂、表面活性剂、溶剂及其它助剂构成的O/W型微乳液.结果表明清洗剂各组分的复配比对清洗剂使用性能具有较大影响,该微乳液可替传统溶剂型油墨清洗剂用于印刷机件上油墨的清洗,且使用效果和安全性能超过汽油、煤油...     

水基印刷线路板油墨清洗剂的研制

研制了一种水基印刷线路板油墨清洗剂。研究了清洗剂中的氢氧化钠、磷酸三钠、三聚磷酸钠、硅酸钠用量对油墨去除率的影响。采用超声辅助清洗工艺,探讨了清洗温度和清洗时间对不同类型印刷线路板油墨去除效果的影响。油墨清洗剂的较优组成为:氢氧化钠6%,磷酸三钠2%,三聚磷酸钠2%,硅酸钠1%,氯化钠2%,亚硝酸钠1%,表面活性剂AES1%,表面活性剂K121%,表面活性剂SAS-601%。该油墨清洗剂具有良好的清洗能力,油墨去除率高。在清洗温度80～90°C、清洗剂中活性物质量分数为17%的条件下,对普通型线路板、烘烤型线路板分别清洗5～8min、45～50min,油墨去除率均可达100%。     

脂肪酶对水基油墨清洗剂洗涤能力的影响研究

采用阴离子和非离子表面活性剂复配体系,研究了不同脂肪酶用量下的水基油墨清洗剂性能。通过稳定性、腐蚀性、净洗力以及泡沫性能对一系列脂肪酶型水基油墨清洗剂进行了评价,优化了配方组成。结果表明:所配制的脂肪酶型水基油墨清洗剂具有良好的高低温稳定性;脂肪酶用量对腐蚀性无影响,含有脂肪酶的油墨清洗剂具有良好的抗腐蚀性能;当脂肪酶用量为0.4%时,体系的净洗力最强、发泡力最低。     

印刷油墨清洗剂的技术现状及发展趋势

对印刷油墨清洗剂的国内外研究进展进行了综述,概括分析了传统汽油、煤油类油墨清洗剂,混合溶剂型,乳化、微乳型,水基、半水基型,植物油基型等新型油墨清洗剂的优点与缺陷,并对油墨清洗剂的发展趋势进行了展望。     

新型水溶性油墨清洗剂的研制及其应用

文章研制出一种新型油墨清洗剂,具有安全、高效、低成本的特点,能克服直接使用溶剂带来的易燃、易爆等缺点.此新型油墨清洗剂是由表面活性剂、乳化剂、溶剂及其它助剂构成的O/W型微乳液.研究结果表明,此油墨清洗剂各组分的复配比对其使用性能具有较大影响,此清洗剂可替传统溶剂型油墨清洗剂用于印刷机件上油墨的清洗,且安全、高效.在清洗温度不低于25℃的条件下,水与清洗剂的稀释比为3∶1,对油墨的去除率达到100％.     

微乳型油墨清洗剂的研制与清洗性能

研制了一种由乳化剂、表面活性剂、溶剂、复合缓释剂及其它助剂构成的O/W型微乳液,研究了温度、水与清洗剂的复配比对清洗剂使用性能的影响。结果表明,该微乳液可替代汽油、煤油用于印刷机件上油墨的清洗,且防锈缓蚀和安全性能超过汽油、煤油等溶剂型清洗剂;清洗剂的使用温度和水与清洗剂的复配比对微乳型油墨清洗剂的使用性能有较大影响,适宜的使用温度以30℃为宜,适宜的水与清洗剂的复配比为(3.0~4.0)∶1.0;在水与清洗剂的复配比为4.0∶1.0,清洗温度不低于25℃的条件下,对油墨的去除率超过95%。     

微乳液型油墨清洗剂的研制

为克服传统溶剂型油墨清洗剂易燃易爆、污染环境等缺点,以复配表面活性剂、溶剂、水及其它助剂制备了一种微乳液型油墨清洗剂,对微乳液稳定性等及油墨去污率进行了测定,研究了不同温度及时间对油墨清洗效果的影响。结果表明,常温下使用时,微乳液型清洗剂的油墨去除率达95%以上,最佳清洗温度为25～40℃,最佳清洗时间为15 min,具有安全性能高、清洗能力强、防锈缓蚀性好及环境友好等特点。     

环保节能型油墨清洗剂的开发

研究制备了一种高效、环保、节能水包油型(O/W)油墨清洗剂,分析讨论了溶剂、乳化剂及其它助剂的选择,研究了该油墨清洗剂的稳定性和清洗去污效率等。结果表明,该清洗剂对印刷机件上的油墨清洗效果良好,完全可以替代汽油、煤油等溶剂型清洗剂。     

D相乳化法制备油墨清洗剂

本文主要介绍了用D相乳化法制备一种特效油墨清洗剂，并对清洗剂性能进行了探讨，这种清洗剂主要成分由烷基酚聚氧乙烯醚、环保油溶剂、十二烷基苯磺酸钠以及水等组成。清洗剂为中性，主要用于清洗印刷操作工手上所沾油墨。这种清洗剂对人体皮肤无伤害，去油墨效果非常显著，且无毒无污染，价格低廉，制作简单，使用方便。     

一种水基型洗网水的研制

丝网印刷用途广泛,在使用过程中经常要对丝网上的油墨进行清洗。目前市场上,清洗丝网的常用清洗剂(洗网水)主要成份均为有机溶剂,闪点低,在使用过程或是仓储、运输过程中都存在一定的安全隐患;并且有机溶剂的有机挥发物(VOC)对环境污染也较大。本项目研制的洗网水以水作为主要成份,其余成份为氢氧化钾2%、甲醇7%、乙二醇丁醚30%、LF221为3%、JFC为1%,该洗网水对丝网无腐蚀,清洁效果好,环保经济,并且安全。     

表面活性剂在印刷工业中的应用

介绍了表面活性剂在印刷工业各个领域中的应用。其中包括在胶版印刷过程、制版过程、PS版的回收再生以及各种油墨和印刷用清洗用品中的应用 ,并介绍了若干相关的配方     

Lithographic and letterpress ink vehicles from vegetable oils

Our objectives for this study were to produce vegetable oil-based printing ink vehicles that did not require any petroleum components, which meet or exceed industry standards for rub-off resistance, viscosity and tackiness for a variety of printing applications. These objectives were satisfactorily met. Vehicles were completely compatible with carbon black, making them suitable for black ink formulations. In addition, the resulting vehicles had exceptionally light colors, and permitted formulations of colored inks that had substantially reduced pigment levels compared to industry standards.     

An ecological approach to printing industry: Development of ecofriendly offset printing inks using vegetable oils and pine resin as renewable raw materials and evaluation of printability

Petroleum-based solvents and synthetic resins are used as raw materials for the production of varnish, which is one of the main components of offset printing inks. These petrochemical compounds that are released to the surrounding in printing process demonstrates harmful effects on environment and human health. In the light of these facts, this study was carried out to investigate the use of renewable natural resources for offset printing inks production to lower environmental impacts and protect human health. In this study, different vegetable-based offset printing inks were developed with safflower oil (SO); grape seed oil (GSO) and Pinus pinaster resin (PPR) and printability analysis were performed. To understand the effect of pine resin in the ink formulation an ink sample with mineral oil (MO) was also produced. Printing tests were carried out with coated papers and the IGT C1 offset printability tester. Color, gloss, rub resistance, viscosity and tack values were measured on the test prints. Comparison of results with standard values figured out the suitability of using the newly developed offset printing inks for printing industry. The color difference values of color differences were in range of tolerance value. The density value of SO-PPR ink was found as same with standard values while the density value GSO-PPR and MO-PPR inks were measured close to standards as 1.45, 1.42, and 1.46, respectively. The results of printability analysis demonstrated appropriate utilization of the renewable sources for ecological development of offset printing inks.     

Properties of ink‐jet printed,ultraviolet‐cured pigment prints in comparison with screen‐printed,thermo‐cured pigment prints

A collection of printed fabrics for men’s shirts was designed and prepared using computer‐aided design/computer‐aided manufacturing technology. The colours for designs were ink‐jet printed on cotton fabrics with pigments and ultraviolet‐cured. These prints represented the target colours for subsequent flat‐screen printing, which was performed using pigment printing pastes and thermal curing. For an exact transfer of colours of the ink‐jet‐printed standard into the screen‐printing process, a computer recipe prediction method was used. A comparison of colorimetric parameters of fabrics printed with both printing techniques shows minimal and acceptable differences in the CIELab colour values. A comparison of colour fastness properties proves that very good colour fastness is achieved on the pigment‐printed fabrics produced with both printing techniques. The flat‐screen‐printed fabrics show better colour fastness to washing, perspiration and rubbing, while ink‐jet‐printed fabrics show better colour fastness to dry‐cleaning and light. The fabrics printed with both printing techniques have high rigidity and non‐elastic properties. The mechanical and physical parameters are strongly dependent upon the amount of the dry substance of the printing media applied on the cotton fabric surface, which is higher on screen‐printed fabrics. The ink‐jet‐printed fabrics show better air permeability than flat‐screen‐printed fabrics.     

印刷油墨用水性聚氨酯的研究进展

简述了环保型水性油墨的特点,着重对印刷油墨用水性聚氨酯的原料选择、制备方法、改性以及应用等方面进行了系统的论述。