共查询到19条相似文献,搜索用时 578 毫秒
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《电镀与涂饰》2017,(18)
以丙烯酸丁酯和甲基丙烯酸甲酯为主要单体,甲基丙烯酸缩水甘油酯和丙烯酸为功能性单体,三羟甲基丙烷三丙烯酸酯(TMPTA)为交联剂,采用乳液聚合法合成了水性丙烯酸树脂。通过测量乳液粒径和黏度,热重分析,机械性能和吸水率测试,考察了TMPTA用量对乳液及其胶膜性能的影响,并用红外光谱表征了胶膜的结构。结果表明,TMPTA的加入可提高胶膜的拉伸强度、硬度、热稳定性和耐水性。当TMPTA用量为6%时,乳液的平均粒径为78.49 nm,黏度为29.77 mPa·s。其胶膜的综合性能最好:交联度96.63%,邵氏硬度44 HA,T剥离强度0.46 kN/m,拉伸强度2.30 MPa,断裂伸长率154.2%,吸水率3.60%,失重率为50%时的分解温度为411℃。 相似文献
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以水性聚氨酯(PU)为种子乳液,以丙烯酸酯(PA)为聚合性单体,采用种子乳液聚合法合成核壳结构聚氨酯-聚丙烯酸酯乳液(PUA)。研究了单体含量对乳液及胶膜性能的影响。实验结果表明:随着乙烯基单体含量的增加,乳液颜色加深,稳定性下降,胶膜的断裂伸长率降低,硬度和耐水性增加。当乙烯基单体和PU百分比(M/P)为25%时,乳液的稳定性大于12个月,胶膜的断裂伸长率为498%,硬度为0.64,吸水性为22.8%。红外光谱分析表明合成了PUA。 相似文献
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《电镀与涂饰》2020,(4)
为了改善丙烯酸酯的力学性能,以丙烯酸酯为主要单体,甲基丙烯酸十二氟庚酯为功能单体,1,4-丁二醇二丙烯酸酯(BDDA)为交联剂,采用核壳乳液聚合法合成了水性含氟丙烯酸酯。考察了反应条件,并对乳液的稳定性、粒径,以及乳液膜的拉伸强度、断裂伸长率、硬度、水接触角和化学结构进行了表征。结果表明,BDDA的加入可以有效提高乳液膜的拉伸强度、断裂伸长率及硬度。当BDDA占单体质量3%时,乳液的平均粒径为63.8 nm,转化率为99.2%,乳液膜的综合性能最好,分别为:吸水率4.9%,水接触角98.8°,拉伸强度1.94 MPa,断裂伸长率743.6%,硬度45.6 HA。其拉伸强度和断裂伸长率分别是未改性含氟丙烯酸酯乳液膜的1.73倍和1.46倍。 相似文献
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硅烷偶联剂KH-602改性水性聚氨酯的研究 总被引:2,自引:0,他引:2
以聚醚(N-210)、异佛尔酮二异氰酸酯(IPDI)为基本单体,以硅烷偶联剂3-(2-氨乙基)氨丙基甲基二甲氧基硅烷(KH-602)作为后扩链剂,通过在后扩链工艺中加入不同比例的KH-602,合成了一系列改性的固含量在28%~40%的水性聚氨酯乳液。用红外光谱对产物结构进行了表征,考察了KH-602加入量对乳液稳定性、胶膜耐水性、力学性能及热性能的影响,同时对乳液进行了接触角的测试。研究表明在一定范围内,随着KH-602加入量的增加,胶膜的拉伸强度增加,断裂伸长率下降,耐热性提高,接触角增大。 相似文献
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The photosensitive and physical and mechanical properties of a novel polysiloxane urethane acrylate (PSUA) for solder mask were investigated using real‐time FTIR, DMTA and TGA. It is noted that PSUA showed a notable photosensitivity and a good compatibility with the acrylic monomers and resins. PSUA cured film exhibited excellent thermal property, tensile strength and toughness, and chemical resistance. The decomposition temperature of PSUA was 402 °C. Thermal weight losses of pure PSUA cured film at 300 °C were only 5%. Elongation percentage of PSUA cured film was up to 59%. PSUA resin can be used for solder mask materials for printed circuit. Technology performances of photosensitive imaging flexible solder mask containing PSUA answers operating requirements of the solder masker for printing circuit board. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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合成了可紫外光固化的低黏度环氧丙烯酸酯树脂,通过红外光谱、核磁共振氢谱、碳谱对树脂结构进行了表征;采用综合热分析仪(DSC-TG)对树脂固化膜的耐热性能进行了分析。结果表明,在树脂中添加活性单体时,随单体官能度的增加,固化膜的耐热性能增加,但双官能团单体的用量对固化膜的耐热性能没有明显影响。固化膜具有较好的耐热性,初始分解温度为330.7℃,玻璃化转变温度为76.9℃。所得树脂黏度仅为3~4Pa.s(60℃),为市售产品的1/3,附着力1级,硬度4 H,耐水性能优异,无需添加单体使用。 相似文献
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A series of UV‐curable B/F/Si‐containing hybrid coatings was prepared by the anhydrous sol‐gel technique. The chemical structure of the coatings was characterized by FTIR, RTIR, and 1HNMR techniques. The UV‐curable coatings were applied to polycarbonate substrates. The physical and mechanical properties of the UV‐cured coatings, such as pendulum hardness, pencil hardness, contact angle, gel content, MEK rubbing test values, tensile strength, abrasion resistance, and gloss, were examined. Thermal gravimetric analysis (TGA) was done. The relative flammability of the hybrid coatings was tested by the limiting oxygen index (LOI) method. Results of all analyses conducted on the free films and coatings are discussed. J. VINYL ADDIT. TECHNOL., 19:39–46, 2013. © 2013 Society of Plastics Engineers 相似文献
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Advanced multifunctional coatings were prepared by UV curing of epoxy based formulations containing hyperbranched polymers (HBP) and an epoxy functionalized alkoxysilane additive. The addition of HBP to the UV curable epoxy resin induced an important flexibilization of the glassy epoxy network with an increase in toughness of the cured polymeric coatings. Adding the functionalized alkoxysilane into the UV curable formulations, as inorganic precursor of silica phase, an improvement on surface hardness was obtained without strongly affecting the flexibilization and the toughness achieved by the addition of the HBP additive. The increase on surface hardness was accompanied with an increase in scratch resistance and modulus. Advanced scratch resistant and tough nanocomposite epoxy coatings were obtained by properly selecting the components of the formulation. 相似文献
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M. K. Uddin Mubarak A. Khan K. M. I. Ali 《Polymer-Plastics Technology and Engineering》2013,52(3):447-459
Leather surface has been modified with UV-cured film of urethane triacrylate in the presence of variable concentrations of mono-functional monomers such as N-vinyl pyrrolidone (NVP) and ethyl hexyl acrylate (EHA). Incorporation of small amounts of plasticizer into the formulation has substantially enhanced both tensile strength and elongation of the coated leather. Addition of a difunctional monomer such as tripropyl glycol diacrylate (TPGDA) to the system has increased the tensile property further. 相似文献
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Summary A reactive type nonionic surfactant, monostearic acid monomaleic acid glycerol diester (MMGD) was synthesized in our laboratory.
Grafting-copolymerization of linear low density polyethylene (LLDPE) with MMGD was carried out by using β ray irradiation
in air in a twin-screw extruder. Evidence of the grafting of MMGD as well as its extent was determined by Fourier-transformed
infrared (FT-IR) spectroscopy. The effects of monomer concentration, reaction temperature and screw run speed on degree of
grafting were studied systematically. The thermal behavior of LLDPE-g-MMGD was investigated by using differential scanning
calorimety (DSC). Compared with neat LLDPE, the crystallization temperature (Tc) of LLDPE-g-MMGD increased about 3 °C, and the melting enthalpy (ΔHm) decreased with increase of MMGD content. It showed that the grafted MMGD monomer onto LLDPE acted as a nucleating agent.
The tensile properties and light transmission of blown films were determined. Comparing with neat LLDPE film, no obvious changes
could be found for the tensile strength, elongation at break and right angle tearing strength of LLDPE-g-MMGD film. The wettability
is expressed by the water contact angle. With an increasing percentage of MMGD, the contact angles of water on film surface
of LLDPE-g-MMGD decrease monotonically. Accelerated dripping property of film samples was investigated. The dripping duration
of LLDPE-g-MMGD film and commercial antifog dripping film at 60 °C were 52 days and 17 days, respectively. 相似文献
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Cycloaliphatic epoxide‐based cationic UV curable coatings containing three different hyperbranched polyols (HBPs) were systematically formulated and characterized. Polyether polyols were found to deter epoxide conversion under low UV intensity. For high UV intensity, the cycloaliphatic epoxide conversion increased with polyol content. Coatings with HBPs had better flexibility and solvent resistance than those containing a reference triol. Compared to the triol and polyester HBPs, polyether HBPs imparted lower Tg and hardness but a better flexibilizing effect to the coatings. At higher R values, the coating solvent resistance decreased except for those with one polyether HBP. A two‐peak phenomenon was discovered in the residual thermal reaction heat curve after photoDSC experiments. These two peaks were found to be related to the thermal relaxation behavior of the photocured inhomogeneous film, and the reactivation and reaction of the ‘trapped living cationic species’. The capability of the polyol to lower the high‐temperature‐peak temperature corresponded well with the flexibilizing ability. Copyright © 2006 Society of Chemical Industry 相似文献
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UV固化丙烯海松酸聚氨酯丙烯酸酯的合成及应用 总被引:1,自引:1,他引:0
以2,4-甲苯二异氰酸酯(TDI)、丙烯海松酸二甘醇聚酯二元醇和丙烯酸羟丙酯(HPA)为主要原料合成了可紫外光固化的涂料用丙烯海松酸聚氨酯丙烯酸酯(APAPUA)低聚物。对产物进行了红外表征,并考察了其光固化行为。测试了APAPUA固化膜的硬度、柔韧性及其他力学性能,同时考察了其热稳定性。结果表明,该低聚物固化膜铅笔硬度达到4H,附着力1级,耐冲击性55 cm,初始分解温度245℃,具有固化速度快,力学性能及耐热性优良等特点,可以作为价格低廉的耐热性低聚物应用于光固化涂料。 相似文献