共查询到20条相似文献,搜索用时 93 毫秒
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聚偏二氟乙烯增强型微孔膜的研制 总被引:6,自引:0,他引:6
本文讨论了聚偏二氟乙烯浓度,添加剂种类及其浓度,空气中溶剂挥发时间,凝胶浴温度对膜性能的影响,通过控制适当的制膜条件,可以制成高通量的0.22μm至3.0μm系列的聚偏二氟乙烯增强型微孔膜。 相似文献
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以聚偏氟乙烯(PVDF)-六氟丙烯(HFP)中PVDF的仲氟原子直接引发甲基丙烯酸(3-磺酸钾)丙酯(SPMA)的原子转移自由基聚合,成功得到以PVDF-HFP为主链、侧链含磺酸基团的接枝聚合物(PVDF-HFP-g-PSPMA)质子交换膜. 通过红外、核磁分析方法对PVDF-HFP-g-PSPMA的结构进行表征. 反应不同时间得到的PVDF-HFP-g-PSPMA离子交换容量为0.051~0.59 meq/g,质子传导率为(2.58~30.9)×10-2 S/m. 相似文献
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Ghadeer Jalloul M. Hadi Hashem Ali Reza Tehrani-Bagha Mohammad N. Ahmad Belal J. Abu Tarboush 《应用聚合物科学杂志》2021,138(7):49861
In this project, an unsupported electrospun poly(vinylidene fluoride)-co-hexafluoropropylene (PVDF-HFP) membrane was used for water desalination using direct contact membrane distillation (DCMD). The membrane was electrospun using a laboratory-scale machine with multiple nozzles that was developed in-house. Critical process parameters, including the applied voltage and polymer concentration, were optimized to obtain bead-free electrospun membranes with fiber diameters less than 300 nm. To improve the membrane thermal stability and performance, the selected electrospun membrane was heat-pressed at 160°C. The untreated and heat-pressed membranes were tested in a DCMD setup at different feed temperatures (60, 70, and 80°C) and feed flow rates (0.4, 0.6, and 0.8 L/min), while maintaining the permeate temperature and flow rate at 20°C and 0.2 L/min, respectively. The modified electrospun membrane exhibited a very high permeate flux (>37.5 kg/m2/h) and a salt rejection rate of 99.99% at a feed temperature of 70°C. The performance of the heat-pressed unsupported PVDF-HFP electrospun membrane was nearly identical to a commercially available polytetrafluoroethylene (PTFE) supported membrane. These promising results demonstrate that relatively low-cost electrospun membranes can be easily produced and successfully used in DCMD to minimize the capital cost and increase the energy efficiency of the process. 相似文献
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ZHANG Mei CUI Zhenyu ZHU Baoku HAN Gaige XU Youyi ZHANG Aiqing 《Frontiers of Chemical Science and Engineering》2008,2(1):89
Lithium ion conducting membranes are the key materials for lithium batteries. The lithium ion conducting gel polymer electrolyte membrane (Li-GPEM) based on porous poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) matrix and cross-linked PEG network is prepared by a typical phase inversion process. By immersing the porous PVDF-HFP membrane in liquid electrolyte containing poly(ethylene glycol) diacrylate (PEGDA) and an initiator to absorb the liquid electrolyte at 25°C, and then thermally cross-linking at 60°C, the Li-GPEM is fabricated successfully. The measurements on its weight loss, mechanical and electrochemical properties reveal that the obtained Li-GPEM has better overall performance than the liquid and blend gel systems used as conductive media in lithium batteries. The ionic conductivity of the fabricated Li-GPEM can reach as high as 2.25 × 10-3 S/cm at 25°C. 相似文献
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Nanocrystalline cellulose reinforced PVDF-HFP membranes for membrane distillation application 总被引:1,自引:0,他引:1
Polyvinylidenefluoride-co-hexafluoropropylene (PVDF-HFP) membranes containing different amounts of nanocrystalline cellulose (NCC) were fabricated by electrospining technique for application in membrane distillation (MD). The effect of incorporating NCC on the mechanical strength, morphology, pore size distribution, and liquid entry pressure (water) of the fibrous was investigated. Incorporation of NCC in PVDF-HFP matrix improved the tensile strength and Young's modulus and narrowed down the pore size distribution of the fabricated membranes. Liquid entry pressure, which is an important parameter to ensure high salt rejection of the membranes in MD, was improved from ~ 19 psi to ~ 27 psi with the addition of 2 wt.% NCC. Fabricated membranes were tested in direct contact membrane distillation (DCMD). MD operation data revealed water flux of 10.2–11.5 Lh− 1 m− 2 with salt rejection of 99% for these NCC-incorporated membranes. 相似文献
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Porous polyvinylidene fluoride-co-hexafluropropylene (PVDF-HFP) hollow fiber membranes were fabricated through a wet spinning process. In order to improve the membrane structure, composition of the polymer solution was adjusted by studying ternary phase diagrams of polymer/solvent/non-solvent. The prepared membranes were used for sweeping gas membrane distillation (SGMD) of 20 wt% ethylene glycol (EG) aqueous solution. The membranes were characterized by different tests such as N2 permeation, overall porosity, critical water entry pressure (CEPw), water contact angle and collapsing pressure. From FESEM examination, addition of 3 wt% glycerol in the PVDF-HFP solution, produced membranes with smaller finger-likes cavities, higher surface porosity and smaller pore sizes. Increasing the polymer concentration up to 21 wt% resulted in a dense spongy structure which could significantly reduce the N2 permeance. The membrane prepared by 3 wt% glycerol and 17 wt% polymer demonstrated an improved structure with mean pore size of 18 nm and a high surface porosity of 872 m-1. CEPw of 350 kPa and overall porosity of 84% were also obtained for the improved membrane. Collapsing pressure of the membranes relatively improved by increasing the polymer concentration. From the SGMD test, the developed membrane represented a maximum permeate flux of 28 kg·m-2·h-1 which is almost 19% higher than the flux of plain membrane. During 120 h of a long-term SGMD operation, a gradual flux reduction of 30% was noticed. In addition, EG rejection reduced from 100% to around 99.5% during 120 h of the operation. 相似文献
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Ju-Young Park Jae-Wook Lee Kyung Hee Park Tae-Young Kim Soon-Ho Yim Xing Guan Zhao Hal-Bon Gu En Mei Jin 《Polymer Bulletin》2013,70(2):507-515
Poly(vinylidenefluoride-co-hexafluoropropylene) (PVDF-HFP) nanofibers were prepared by the electrospinning method and used as polymer electrolytes in dye-sensitized solar cells (DSSCs). The electrolyte uptake and ionic conductivity of electrospun PVDF-HFP nanofibers with different diameters changed significantly, regardless of the nanofiber thickness. The PVDF-HFP nanofibers prepared from a 15 wt% spinning solution showed high ionic conductivity (1.295 S/cm) and electrolyte uptake (947 %). DSSCs based on the 15 wt% PVDF-HFP nanofiber electrolyte showed an electron transit time of 6.34 × 10?3 s, electronic recombination time of 5.88 × 10?2 s, and conversion efficiency of 3.13 %. Thus, we concluded that the electrospun PVDF-HFP nanofibers can be used as polymer electrolytes in flexible DSSCs as well. 相似文献
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Porous polyvinylidene fluoride-co-hexafluropropylene (PVDF-HFP) hollow fiber membranes were fabricated through a wet spinning process. In order to improve the membrane structure, composition of the polymer solution was adjusted by studying ternary phase diagrams of polymer/solvent/non-solvent. The prepared membranes were used for sweeping gas membrane distillation (SGMD) of 20 wt% ethylene glycol (EG) aqueous solution. The membranes were characterized by different tests such as N2 permeation, overall porosity, critical water entry pressure (CEPw), water contact angle and collapsing pressure. From FESEM examination, addition of 3 wt% glycerol in the PVDF-HFP solution, produced membranes with smaller finger-likes cavities, higher surface porosity and smaller pore sizes. Increasing the polymer concentration up to 21 wt% resulted in a dense spongy structure which could significantly reduce the N2 permeance. The membrane prepared by 3 wt% glycerol and 17 wt% polymer demonstrated an improved structure with mean pore size of 18 nm and a high surface porosity of 872 m−1. CEPw of 350 kPa and overall porosity of 84% were also obtained for the improved membrane. Collapsing pressure of the membranes relatively improved by increasing the polymer concentration. From the SGMD test, the developed membrane represented a maximum permeate flux of 28 kg·m−2·h−1 which is almost 19% higher than the flux of plain membrane. During 120 h of a long-term SGMD operation, a gradual flux reduction of 30% was noticed. In addition, EG rejection reduced from 100% to around 99.5% during 120 h of the operation. 相似文献
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Kaili Luo Dingsheng Shao Li Yang Lei Liu Xiaoyi Chen Changfei Zou Dong Wang Zhigao Luo Xianyou Wang 《应用聚合物科学杂志》2021,138(11):49993
Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)-based gel polymer electrolyte (GPE) is considered one of the promising candidate electrolytes in the polymer lithium ion battery (LIB) because of its free standing, shape versatility, security, flexibility, lightweight, reliability, and so on. However, the pristine PVDF-HFP GPE cannot still meet the requirement of large-scale LIBs and other electrochemical devices due to its relatively low ionic conductivity and deterioration of mechanical strength caused by the incorporation of organic liquid electrolyte into the polymer matrix as well as high cost. In order to overcome above deficiencies of PVDF-HFP based GPE, ultraviolet (UV)-curable semi-interpenetrating polymer network is designed and synthesized through UV-irradiation technique, and the as-prepared semi-interpenetrating matrix is constituted by pentaerythritol tetracrylate polymer network and PVDF-HFP. The ionic conductivity of the optimized GPE is as high as 5 × 10−4 S/cm and electrochemical window is up to 4.8 V at room temperature. Especially, the LIB prepared by GPE shows the high initial discharge specific capacity of 151 mAh/g at 0.5 C and good rate capability. Therefore, the semi-interpenetrating GPE based on PVDF-HFP exhibits a promising prospect for the application of rechargeable LIBs. 相似文献
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Anette Munch Elmér 《Polymer》2005,46(19):7896-7908
Polymer gel electrolyte membranes were prepared by first casting films of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt, and poly(ethylene glycol) (PEG) monomethacrylate and dimethacrylate macromonomers. Polymerization of the macromonomers initiated by UV-irradiation then generated solid films having phase-separated morphologies with a microporous PVDF-HFP phase embedded in PEG-grafted polymethacrylates. Gel electrolyte membranes were finally prepared by allowing the films to take up solutions of LiTFSI in γ-butyrolactone (γ-BL). The PEG-grafted polymethacrylate in the membranes was found to host the largest part of the liquid electrolyte, giving rise to a highly swollen ionic conductive phase. Results by FTIR spectroscopy showed that the Li+ ions preferentially interacted with the ether oxygens of the PEG chains. The properties of the membranes were studied as a function of the ratio of PVDF-HFP to PEG-grafted polymethacrylate, as well as the degree of crosslinking, LiTFSI concentration, and liquid electrolyte content. The self-supporting and elastic gel membranes had ionic conductivities of 10−3 S cm−1 and a mechanical storage modulus in the range of 2.5 MPa in the tension mode at room temperature. Variation of the salt concentration showed the greatest effect on the membrane properties. 相似文献
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Taehee Kim Ik Joong Kang Gyoujin Cho Kwon-pil Park 《Korean Journal of Chemical Engineering》2005,22(2):234-237
A novel solid polymer electrolyte (pore-gel SPE) has been found to provide superior SPE having a high conductivity, good mechanical
strength and low solution leakage. This pore-gel SPE was prepared from gelation in pores of polymer membrane with electrolyte
solution including solvent. The conductivity of pore-gel type PVDF-HFP/ TEABF4 (Tetraethylammomium tetrafluoroborate) membrane can reach 1.6×10-1 Scm-1. The tensile strength of this membrane was 4,000 kPa, which is about 23 times larger than that of gel-type SPE with the same
composition. Poregel SPE reduced solution leakage to 0%, compared with 2% of hybrid-type SPE after 2.0 hr leakage test in
PVDFHFP/ TEABF4 membrane. 相似文献