共查询到19条相似文献,搜索用时 62 毫秒
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碱处理法制备钛合金表面羟基磷灰石涂层 总被引:3,自引:2,他引:1
采用碱处理法制备钛基羟基磷灰石涂层,考察了碱液处理中有关钛合金表面活化参数对其诱导羟基磷灰石沉积速度的影响,采用X射线衍射和扫描电镜对样品的化学组成、结构和性能进行了表征,确定了钛合金表面活化处理的最优参数.结果表明,钛基体经10 mol/L氢氧化钠,饱和硝酸钙预钙化处理,模拟体液中培养后,羟基磷灰石沉积速度快,14 d就可形成致密﹑均匀﹑裂纹少的涂层;碱液处理后饱和硝酸钙溶液预钙化可得到片状的羟基磷灰石生物矿化层;且钛基体在600 ℃的热处理是HAP涂层沉积的重要条件之一.与相关研究相比较,该方法的优点在于可在形状复杂的植入体上形成均匀的涂层,工艺简单,并且涂层与基体结合牢固. 相似文献
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《浙江化工》2016,(9)
目的:为提高镁合金的耐蚀性与生物相容性。方法:利用溶胶-凝胶的方法制备羟基磷灰石并进行XRD物相分析,采用电沉积的方法在镁合金表面制备了一层透明质酸-羟基磷灰石复合层,利用扫描电子显微镜结合EDS能谱仪对膜层进行形貌表征与元素分析,对膜层进行Tafel极化曲线测量。结果:沉积物的含量随着沉积时间的延长而增大,并且沉积物的组分也随着透明质酸溶液中羟基磷灰石含量的变化而变化,羟基磷灰石均匀地分散到了透明质酸膜层中,Tafel极化曲线表明复合物涂层提高镁合金基体的耐蚀性。结论:常温下,采用电沉积的方法能使透明质酸与羟基磷灰石沉积到镁合金表面,并且能提高镁合金基体的耐蚀性。 相似文献
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钛金属表面生物陶瓷涂层研究的现状 总被引:6,自引:2,他引:6
骨替换材料与周围骨组织之间的生物活性结合是近10年来研究较多的一种结合方式,其关键是生物材料表面必须具备高的生物活性。利用物理沉积、溶胶—凝胶、电化学沉积以及生物仿生等技术在钛金属表面涂覆具备生物活性的生物陶瓷涂层,是提高钛金属生物活性的有效手段之一。另一类有效方法是用氢氧化钠或双氧水溶液对钛金属进行化学处理,在表面获得一层具备生物活性的二氧化钛.这层二氧化钛除必须富含Ti-OH功能性基团外,还应该是晶态的,这样才能有效地诱发羟基磷灰石晶核的生长,从而使钛金属表面具备高的生物活性。文中对这些表面生物活化处理技术及其生物活化机制作了简单评述。 相似文献
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先用10mol/L的NaOH溶液处理镍钛片,随后采用电沉积法制备羟基磷灰石涂层。电沉积工艺参数为:硝酸钙0.042mol/L,磷酸二氢铵0.025mol/L,EDTA-2Na1.5×10-4mol/L,温度65℃,pH4.5,电流密度1mA/cm2,时间1h。采用扫描电镜、红外光谱仪和能谱仪对所得涂层进行表征。NaOH溶液处理有利于羟基磷灰石的生长。溶液中EDTA-2Na的存在不影响羟基磷灰石的生成,只是促使羟基磷灰石末端聚拢,使羟基磷灰石之间的空隙扩大,并减少涂层的CO3-2含量,增加OH-,有效减少了涂层的镍含量。 相似文献
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电化学沉积-水热合成法制备羟基磷灰石生物涂层的工艺研究 总被引:27,自引:6,他引:21
采用电化学沉积法,在低温条件下从含钙、磷离子的电解水溶液中沉积磷酸钙涂层,经过水热合成获得羟基磷灰石(HA)涂层.用扫描电镜(SEM)、X射线衍射(XRD)和红外光谱(IR)对涂层的组织结构和化学组成进行分析.结果表明:电化学沉积涂层由CaHPO4·2H2O,经水热合成后转变为羟基磷灰石.随蒸气温度和压力的升高,羟基磷灰石的含量增加,在适当条件下可获得纯羟基磷灰石涂层.该方法重复性好,是制备羟基磷灰石生物涂层的理想方法之一. 相似文献
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T. Okada 《Electrochimica acta》1982,27(9):1273-1280
The surface of titanium was modified by depositing coatings of metals of Group VIII, Ib and IVb and heat treatment at 700°C in a vacuum. The polarization behavior of the modified specimens were different from that of unmodified titanium, depending upon the nature and quantity of the deposited metals, thus indicating the altered nature of the surface layer. The initial hydrogen absorption rate by the modified specimens during cathodic polarization in 0.5 M H2SO4 was measured and the results are discussed in relation to the hydrogen evolution reaction characteristic of the deposited metals, the surface layer composition, etc. Metals which inhibited the formation of the surface oxide layer of titanium increased the hydrogen absorption rate. The surface coverage of atomic hydrogen is suggested to the critical factor in determining the hydrogen absorption rate of titanium. Among the metals studied, Ni was the most significant in improving the hydrogen absorption rate of titanium, resulting in a current efficiency of 62% for hydrogen absorption (2.8 times that of titanium). Pt and Pb had an inhibiting effect on hydrogen absorption, with half the efficiency of untreated titanium. The present results suggest the possibility of controlling the hydrogen absorption rate of titanium during cathodic polarization by surface modification techniques. 相似文献
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The novelty of the present research consists in the possibility of obtaining cerium-doped hydroxyapatite/collagen coatings on the titanium support, to improve the performance of the bone implants. These coatings were deposited on the titanium surface by biomimetic method using a modified supersaturated calcification solution (SCS) additionally containing a cerium source and collagen. Prior to the deposition of the apatite layer, an alkali ÷ thermal oxidation pretreatment has been applied to ensure an increase in the bioactivity of the titanium surface. The coatings were examined by scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and Fourier transformed infrared (FTIR) spectroscopy. The EDX and XRD investigations of the coatings indicated that cerium was incorporated in the hydroxyapatite lattice. The collagen presence in the coatings was confirmed by FTIR analysis. The cerium-doped hydroxyapatite/collagen coatings showed good antibacterial efficacy against Escherichia coli and Staphylococcus aureus bacteria, being more effective against Escherichia coli. These coatings have a significant potential to be used in the dental and orthopedic implants, as the osseointegration depends on much more factors than simple formation of hydroxyapatite. 相似文献
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Valeria Cannillo Luca Lusvarghi Antonella Sola 《International Journal of Applied Ceramic Technology》2009,6(4):537-550
Titania–hydroxyapatite functionally graded coatings were deposited on titanium alloy substrates by plasma spraying. Because it was necessary to spray together the titania and the hydroxyapatite powders to obtain the graded system, the first target of the present study was to optimize the process parameters in order to obtain a high-quality coating. A 23 Design of Experiments was applied to define the optimal values of plasma torch power, hydrogen flux, and spraying distance. This defined set of parameters (38 kW, 5 SLPM, and 90 mm, respectively) was used to spray the most promising graded coating, which was characterized and postheat treated. 相似文献
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Bioactive Calcium Phosphate Coating on Sodium Hydroxide-Pretreated Titanium Substrate by Electrodeposition 总被引:1,自引:0,他引:1
Ji-Ho Park Doug-Youn Lee Keun-Taek Oh Yong-Keun Lee Kyoung-Nam Kim 《Journal of the American Ceramic Society》2004,87(9):1792-1794
This study examined the characteristics of calcium phosphate coatings deposited on a NaOH-pretreated titanium substrate by electrodeposition in a modified simulated body fluid (SBF) immediately after electrodeposition as well as after the coatings had been immersed in the SBF for 5 d in order to determine the effects of a NaOH pretreatment on the bioactive coating prior to electrodeposition. The results showed that a dense and uniform coating that consisted of brushite and hydroxyapatite had formed on the NaOH-pretreated titanium substrate by electrodeposition. This coating had transformed to a bonelike apatite during immersion in the SBF. This was attributed to the increased surface area of the modified titanium formed after the NaOH treatment as well as the Na+ ions released from that surface. Therefore, a NaOH pretreatment is recommended as an effective method for preparing a bioactive calcium phosphate coating by electrodeposition. 相似文献
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Biomimetic Hydroxyapatite Coating on Metal Implants 总被引:9,自引:0,他引:9
Pamela Habibovic Florence Barrère Clemens A. Van Blitterswijk Klaas de Groot Pierre Layrolle 《Journal of the American Ceramic Society》2002,85(3):517-522
The combination of the high mechanical strength of metals with the osteoconductive properties of calcium phosphates make hydroxyapatite coatings on titanium implants widely used in orthopedic surgery. However, the most popular coating method, plasma spraying, exhibits some important drawbacks: the inability to cover porous implants and to incorporate biologically active agents, delamination, and particle release. The aim of this study was to elaborate a dense, strong, and thick calcium-phosphate coating on titanium and porous-tantalum implants using a two-step biomimetic procedure. In the first step, the implants were soaked in a solution that was 5 times more concentrated than regular simulated body fluid (SBF-A solution). A thin but uniform amorphous calcium-phosphate coating was deposited on the metal. Then, the implants were immersed in the SBF-B solution, which had a similar composition as the SBF-A solution, but with decreased contents of crystal growth inhibitors (i.e., Mg2+ and HCO3 − ). This resulted in the fast precipitation of a 30 μm thick crystalline calcium-phosphate coating. The pH of the SBF-B solution and the thickness of the crystalline coating layer were studied as a function of time. The Fourier transform infrared spectra and X-ray diffraction patterns showed that this new coating closely resembles bone mineral. Our biomimetic coating should facilitate rapid bone formation around the implant, reducing therewith the patient's recovery time after surgery. 相似文献
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仿生法制备钛合金/羟基磷灰石复合涂层的研究 总被引:4,自引:0,他引:4
本研究了仿生溶液中钛合金表面沉积羟基磷灰石的技术路线。钛合金经抛磨、清洗.进行酸碱活化处理后,置于模拟体液(SBF)中,最终在钛合金基体上生成羟基磷灰石涂层。 相似文献
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《Journal of Adhesion Science and Technology》2013,27(2-3):221-231
We have developed a layered hydroxyapatite/diamondlike carbon/functionally gradient diamondlike carbon-silver/titanium carbide/titanium carbonitride/titanium nitride composite film using pulsed laser deposition. A diamondlike carbon interlayer between a hydroxyapatite coating and the Ti-6Al-4V alloy can serve several purposes, including preventing corrosion of Ti-6Al-4V alloy, overcoming poor adhesion between the hydroxyapatite coating and the titanium oxide surface, and reducing inflammation at the implant/tissue interface. Titanium nitride, titanium carbonitride (TiC x N y ), titanium carbide and functionally gradient diamondlike carbon-silver layers were used to improve the adhesion of diamondlike carbon films to Ti-6Al-4V alloy. We envision several potential medical applications for these multilayer materials, including use in orthopedic and dental devices. 相似文献
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基于表面生物学改性的多孔状二氧化钛/磷灰石复合薄膜的制备 总被引:26,自引:8,他引:26
在钛合金表面采用微孤氧化得到一层多孔状的具有生物活性的二氧化钛,经随后水热处理可形成羟基磷灰石薄膜,提高钛合金表面的生物学性能,用SEM、XRD、EDX分析了薄膜的组织、结构和化学组成,同时考察了微弧氧化得到的二氧化钛膜的生物活性,结果表明,在室温条件下从含钙、磷离子的电解液中在钛合金基体上微弧氧化得到一层二氧化钛薄膜,蒸汽处理后得到具有生物活性的二氧化钛/羟基磷灰石复合薄膜,该膜多孔均匀,且生物活性高,有利于骨组织的吸附和生长。 相似文献