Wcomet直接还原法渣铁分离影响因素研究

研究还原温度、渣相配料碱度和渣中CaF2、K2O、P2O5、S、FeO的含量等因素对2CaO·SiO2形成及其相变的影响规律。结果表明,在快速升温条件下,温度高于1300℃后2CaO·SiO2才大量生成;CaF2、S和FeO对2CaO·SiO2相变不产生影响,但K2O和P2O5对2CaO·SiO2相变具有明显抑制作用;渣相二元碱度R〈1．8时渣的自然粉化效果明显变差。     

高铝铁矿石球团在预还原过程中的热力学行为

应用物质吉布斯自由能函数法计算高铝铁矿石球团在预还原过程中所发生反应的ΔG,明确球团中物相在该过程中的热力学行为.热力学计算、分析结果表明:还原阶段产生的FeO最易与Al2O3反应生成FeO·Al2O3,其次与SiO2反应生成2FeO·SiO2,最后与SiO2反应生成FeO·SiO2·Al2O3置换2FeO·SiO2和FeO·SiO2中SiO2生成FeO·Al2O3的反应较之SiO2置换FeO·Al2O3中Al2O3的反应要容易得多.FeO.SiO2的还原反应趋势要强于FeO·Al2O3及2FeO.SiO2.     

球团矿回转窑内结圈物的特性研究

采用XRD、SEM和EDS等测试方法研究球团矿回转窑内结圈物的基本特性和显微结构及其对结圈形成的影响。结果表明,结圈物主要以赤铁矿为主,含有部分磁铁矿,其主要成分是铁的氧化物,其他少量成分以Al2O3、SiO2为主,还有极少量的CaO、K2O、Na2O等碱金属氧化物,它们主要以玻璃相的形式分布在晶界和气孔中。回转窑结圈的生长主要依靠铁氧化物的固相烧结反应,杂质形成的液相对固相烧结反应起到一定的促进作用。     

自蔓延高温合成法形成陶瓷涂层的研究

采用静态自蔓延高温合成法 (SHS)在钢件表面形成陶瓷涂层 .涂层的相组成主要是 Al2 O3 α Fe 少量 Fe3Al;涂层由两层组成 ,外层为近乎纯 Al2 O3陶瓷层 ,过渡层为 αFe Al2 O3金属 -陶瓷层 ,两层组织皆为长轴近似垂直于钢件表面的柱状晶 ;涂层与基体结合牢固     

转炉钢渣的物相及其冷却析出研究

利用X射线荧光光谱、X射线衍射、扫描电镜和能谱分析仪对转炉钢渣的物相组成及其形貌特征进行研究,并用热力学软件FactSage对钢渣冷却过程中各物相的析出情况进行模拟.结果表明,转炉钢渣中的主要物相为硅酸钙相、铁酸钙相以及RO 相,此外还有少量的游离氧化钙（f-CaO）等物相.从物相的形貌特征上来看,硅酸钙相多呈圆形或椭圆形,尺寸为10-20μm;铁酸钙相以延伸的状态分布在硅酸钙相和RO 相之间,无规则形状;RO 相为连续延伸的无定形状,尺寸大小不一;游离氧化钙呈堆积状态,无规则形状,尺寸在30-50μm 之间,且表面较为粗糙.转炉钢渣在缓慢冷却的过程中,最终会析出γ-Ca2SiO4、Ca2Fe2O5、（MnO）（Fe2O3）以及少量的MgO 等物相,且各物相的析出温度分别为175、1325、425、1550℃.     

自蔓延高温合成形成陶瓷涂层的研究

采用静态自蔓延高温合成法（SHS）在钢件表面形成陶瓷涂层。涂层的相组成主要是Al2O3 αFe 少量Fe3Al2;涂层由两层组成,外层为近乎纯Al2O3陶瓷层,过渡层为αFe Al2O3金属－陶瓷层,两层组织皆为长轴近似垂直于钢件表面的柱状晶;涂层与基体结合牢固。     

Na2SiO3含量对等离子体电解氧化Al2O3-ZrO2复合陶瓷层形成机制的影响

铸造Al-Si合金表面ZrO2陶瓷层可有效提高基体的隔热及抗高温氧化性能,采用等离子体电解氧化方法在Al-Si合金表面制备了氧化锆涂层.涂层的组成、结构通过SEM、XRD进行研究.结果表明:K2ZrF6体系成膜速度较快,30min膜厚可达92μm,膜层表面和截面没有明显的等离子体放电形成的微孔,大量聚集的Zr(OH)4在等离子体放电产生的热化学作用下分解为ZrO2,表面出现大量2μm～5μm的陶瓷颗粒.K2ZrF6复合Na2SiO3体系成膜速度较慢,30min膜厚仅为27μm,表面和截面存在较多喷射状孔洞,随着溶液浓度的增大,成膜速度均呈先增后减的趋势.K2ZrF6复合Na2SiO3体系中,陶瓷层主要由α-Al2O3、γ-Al2O3、Al2(OH)3F3和m-ZrO2组成,α-Al2O3为陶瓷层的主晶相.K2ZrF6体系中陶瓷层的主要成分为t-ZrO2、m-ZrO2、α-Al2O3和γ-Al2O3,t-ZrO2为涂层的主晶相.涂层中m-ZrO2较少,而t-ZrO2含量高,表明生成的α-Al2O3起到稳定高温相t-ZrO2的作用.     

挤压轮表面等离子喷涂Al_2O_3-13%TiO_2涂层组织和性能分析

在挤压轮表面,用等离子技术喷涂Al2O3-13%TiO2涂层。利用XRD、SEM和EDS等技术对Al2O3-13%TiO2涂层微观组织、形貌和物相成分进行表征,运用维氏显微硬度计对基体和涂层的显微硬度进行了测试,用高温摩擦磨损试验机对Al2O3-13%TiO2涂层的耐磨损性能进行了评价。结果表明,Al2O3-13%TiO2涂层中γ?Al2O3和α?Al2O3共存,以γ?Al2O3为主,涂层表面有Al2O3白色颗粒存在,涂层致密度较好,其表面显微硬度为975HV,耐磨损性能要明显优于H13钢,有效的提高了挤压轮的使用寿命。     

挤压轮表面等离子喷涂Al2O3-13％TiO2涂层组织和性能分析

在挤压轮表面,用等离子技术喷涂Al2O3-13％TiO2涂层.利用XRD、SEM和EDS等技术对Al2O3-13％TiO2涂层微观组织、形貌和物相成分进行表征,运用维氏显微硬度计对基体和涂层的显微硬度进行了测试,用高温摩擦磨损试验机对Al2O3-13％TiO2涂层的耐磨损性能进行了评价.结果表明,Al2O3-13％TiO2涂层中γ-Al2O3和α-Al2O3共存,以γ-Al2O3为主,涂层表面有Al2O3白色颗粒存在,涂层致密度较好,其表面显微硬度为975HV,耐磨损性能要明显优于H13钢,有效的提高了挤压轮的使用寿命.     

包渗法制备硅化物涂层的结构形貌及形成机理

采用包渗法在C-103铌合金基体上制备MoSi2涂层,通过X射线衍射、扫描电镜和能谱分析等手段研究涂层表面、截面形貌以及氧化后涂层结构变化,并分析硅化过程中涂层的形成机理。研究结果表明：包渗法制备硅化物涂层是通过反应扩散形成的,硅化过程服从抛物线规律;该涂层为复合结构：MoSi2相为主体层;以NbSi2相为主、并含少量Nb5Si3相的两相为过渡区;Nb5Si3相为扩散层。在高温氧化环境下,涂层表面生成致密的非晶氧化层,有效地阻止了氧向涂层内扩散。     

Fabrication and Microstructure of SiO_2-GeO_2 Sol-gel Glass Coatings

1　IntroductionSol gel derivedgermanosilicateglasscoatingshavebeenconsideredtohavepotentialapplicationsforplanaropticalwaveguides(POW ) .Generally ,inapplicationsthecontrolofthecontentofGeO2 andthesurfacequalityofthiscoatingwereveryimportant[1,2 ] .InrecentyearstherewerereportsaboutthestudiesonpreparingGeO2 basedgelglassbyusingtetraethylorthogermanate ,TEOGastheprecursor[3 -5] .However,TEOGisextremelyexpensiveandusuallyunavailable .Thusitiscostlyanddifficulttofabricatewaveguidescontaini…     

铸钢件用水基SG-GLY-I型复合涂料的研究

为了解低涂料及铸件成本,用高铝粉和锆英粉作耐火材料,用水作载体,通过正交复合耐火材料烧结试验以及流变特性的分析,研制出适用于铸钢件的优质涂料,该涂料成本低,生成浇注实践表明,所生产的铸钢件具有表面光洁,不粘砂及易清理等优点。     

含BaO,Na2O渣系渣钢间硫平衡研究

在钼丝炉上进行了含BaO,Na2O精炼渣系渣钢间流平衡实验。研究 结果表明,在传统精炼渣系中加入BaO,能够提高渣系的硫容量,Na2O对渣系的硫容量也有很大的影响,但稳定性不好。     

Corrosion mechanism of HVOF silicate glass coating in 5% NaCl solution

On the basis of good anticorrosion capability of silicate glass,silicate glass coating was sprayed by high velocity oxygen fuel (HVOF) and the corrosion mechanism in 5% NaCl solution was studied. Scanning electron microscope (SEM) ,energy dispersive X-ray analysis (EDX) ,X-ray diffraction (XRD) and potentiom- eter were used to study the coating composition and corrosion process. The result shows that silicate glass coating is entirely noncrystallizable. Silicate glass coating has very low incidence of hole with compact structure. Electric double-layer can form at coating/solution interface and corrosive solution performs as a lead connecting the coating surface and substrate after permeating through glass coating. The corrosion mechanism of silicate glass coating is similar to that of glass and the entire corrosion process can be divided into some states. The whole corrosion process happens in glass coating without substrate basically. The fluctuation of the self-corrosion potential about glass coating in corrosion solution can help to research the corrosion process.     

黑色金属铸件用铝矾土金属型涂料

本文研制了一种新型铝矾土水基水玻璃涂料,它具有良好的绝热性能和工艺性能与国外同类涂料相当,可用于铸钢、铸铁件的金属型生产.     

Structure and Oxidation Behavior of a Plasma Sprayed Yttrium Silicates Coated SiC-C/C with a Glass Outer Sealant from 1 573K to 1 873K

Different compositions of yttrium silicates coatings were deposited on SiC-C/C by plasma spraying and an outer borosilicate glass was applied on the yttrium silicates coatings surfaces.The structure of the multi-layer coatings was characterized by XRD and SEM analyses.High temperature oxidation behavior of the multi-layer coatings coated C/C composites was investigated.Results show that SiC/2SiO_2Y_2O_3/I.5SiO_2 Y_2O_3/SiO_2 Y_2O_3/glass multi-layer coating has better high temperature oxidation resistance,protecting carbon/ carbon composites from oxidation at 1 773 K in air for 164 h with the weight loss of 1.65%.The oxidation weight loss of the coated C/C with time accorded with parabolic rule in the temperature range 1 573 K-1 873 K; and the corresponding oxidation activation energy of the coated carbon/carbon composites is 132.2 kJ/mol.     

Structure and oxidation behavior of a plasma sprayed yttrium silicates coated SiC-C/C with a glass outer sealant from 1 573K to 1 873K

Different compositions of yttrium silicates coatings were deposited on SiC-C/C by plasma spraying and an outer borosilicate glass was applied on the yttrium silicates coatings surfaces. The structure of the multi-layer coatings was characterized by XRD and SEM analyses. High temperature oxidation behavior of the multi-layer coatings coated C/C composites was investigated. Results show that SiC/2SiO2 Y2O3/1.5SiO2 Y203/ SiO2 Y2O3/glass multi-layer coating has better high temperature oxidation resistance, protecting carbon/ carbon composites from oxidation at 1 773 K in air for 164 h with the weight loss of 1.65%. The oxidation weight loss of the coated C/C with time accorded with parabolic rule in the temperature range 1 573 K-1 873 K; and the corresponding oxidation activation energy of the coated carbon/carbon composites is 132.2 kJ/mol.     

高反射红外辐射涂料的制备与性能

选用Al2O3、ZnO和SiO2为耐火骨料,加入4种高反射率材料,分析高反射率材料的含量对反射红外辐射涂料反射率的影响.利用正交试验设计,确定涂料最佳配方.实验结果表明：当加入空心微珠30%、TiO27%、Cr2O311%和ZrO212%时,涂料的热反射率达到92%.     

Effectiveness of sodium silicate as gangue depressants in iron ore slimes flotation

The recovery of iron from the screw classifier overflow slimes by direct flotation was studied.The relative effectiveness of sodium silicates with different silica-to-soda mole ratios as depressants for silica and silicate bearing minerals was investigated.Silica-to-soda mole ratio and silicate dosage were found to have significant effect on the separation efficiency.The results show that an increase of Fe content in the concentrate is observed with concomitant reduction in SiO2 and Al2O3 levels when a particular type of sodium silicate at a proper dosage is used.The concentrate of 58.89wt％ Fe,4.68wt％ SiO2,and 5.28wt％ Al2O3 with the weight recovery of 38.74％ and the metal recovery of 41.13％ can be obtained from the iron ore slimes with 54.44wt％ Fe,6.72wt％ SiO2,and 6.80wt％ Al2O3,when Na2SiO3 with a silica-to-soda mole ratio of 2.19 is used as a depressant at a feed rate of 0.2 kg/t.     

SiO_2对烧结矿矿相组成的影响

采用化学试剂配成不同SiO2含量的原料,高温烧结,制成试样,对其进行观察,分析SiO2成份对烧结矿矿相组成的影响。实验结果表明,随着SiO2含量减少,碱度增加,铁酸钙和氧化亚铁的含量也随着增加,磁铁矿含量相应减少;烧结样的气孔率变小,气孔趋于不均匀分布。当SiO2的含量很高时,相应出现硅酸盐相。