Conductive behaviors of carbon nanofibers reinforced epoxy composites

By means of ultrasonic dispersion, carbon nanofibers reinforced epoxy resin composite was prepared in the lab, the electrical conductivity of composite with different carbon nanofibers loadings were studied, also the voltage-current relationship, resistance-temperature properties and mechano-electric effect were investigated. Results show that the resistivity of composite decreases in geometric progression with the increasing of carbon nanofibers, and the threshold ranges between 0.1 wt%-0.2 wt%. The voltage-current relationship is in good conformity with the Ohm＇s law, both positive temperature coefficient and negative temperature coefficient can be found at elevated temperature. In the course of stretching, the electrical resistance of the composites increases with the stress steadily and changes sharply near the breaking point, which is of importance for the safety monitor and structure health diagnosis.     

橡胶/粘土协同增韧环氧树脂的研究

采用橡胶/粘土协同增韧环氧树脂,通过扫描电镜(SEM)和X射线衍射仪(XRD)对环氧树脂/橡胶/粘土复合材料的结构进行了研究,同时还研究了其力学性能.结果表明:纳米粘土和橡胶之间存在明显的协同增韧效应.从冲击断面的SEM分析可知,改性后的复合材料呈现明显的韧性断裂.XRD结果表明,粘土结构以插层结构为主,粘土片层间距由2.3nm增加到3.5nm以上.复合体系解决了单纯橡胶增韧环氧树脂时带来的强度和耐热性差的问题,使复合材料的力学性能和热性能均有一定的改善.     

改性纳米碳酸钙填充PVC的机械性能研究

搅拌和超声条件下改性的纳米碳酸钙填充至聚氯乙烯(PVC),通过抗拉强度、断裂伸长率和冲击强度测试碳酸钙/PVC复合材料的机械性能.结果表明: PVC中纳米碳酸钙的最佳填充量是15 wt %,此时,纳米碳酸钙可均匀分散在PVC中,断裂伸长率和冲击强度明显增加,但抗拉强度略有下降;超声改性时,PVC/碳酸钙复合材料具有更好的抗冲击强度.     

镍铁氧体与聚苯胺的原位复合及电性能研究

采用超声场下原位聚合法制备了镍铁氧体/聚苯胺复合材料。其结构、形貌和导电性能分别采用X射线衍射仪(XRD)、扫描电镜(SEM)和四探针测试仪进行了研究。结果表明,十二烷基苯磺酸(DBSA)掺杂后的聚苯胺是部分结晶的。镍铁氧体/聚苯胺复合粉体近似球形,无严重团聚现象,粒径约为300 nm。镍铁氧体质量含量为15wt%的复合材料具有最大电导率0.845 5 S/cm.     

环氧树脂/粘土纳米复合材料的制备及其固化动力学的研究

通过离子交换反应十六胺对粘土进行改性处理,再用处理与环氧树脂（Ｅ－５１）进行纳米复合制备了环氧树脂／粘土纳米复合材料,讨论了影响材料形成的各种因素,并使用ＴＧＡ,ＸＲＤ、ＴＥＭ等手段对其结构和性进行了测试和表征;粘土的离子交换量采用ＴＧＡ测定;处理土的结构采用ＦＴ－０ＩＲ和ＸＲＤ进行表征;十六胺处理后粘土的晶面间距由原始粘土的１．２７ｎｍ扩展到１．７４ｎｍ;复合材料的微观结构采用ＴＥＭ进行了表征,     

凝固偏析对氧化铝/铝-铜合金复合材料性能的影响

利用挤压铸造技术制备氧化铝／铝-铜合金复合材料，研究了凝固偏析对复合材料机械性能的影响．结果表明：复合材料在凝固过程中由于选择结晶，基体中的溶质元素偏聚在纤维／基体界面或晶界上；纤维加速了复合材料的时效强化过程，随着纤维体积分数的增加，复合材料的硬度、强度、弹性模量增大，而塑性下降；随着预制件预热温度的升高，冷却速度减慢，凝固偏析加剧，复合材料的机械性能下降．     

玻璃纤维增强环氧树脂基复合材料的低温性能研究

对S玻璃纤维和E玻璃纤维增强环氧树脂基复合材料的常温和低温力学性能进行实验,结果表明：玻纤／环氧树脂单向复合材料力学性能随着纤维含量增加而增强,当纤维体积含量为50％时,复合材料具有较好的综合力学性能,且复合材料的强度随着温度的降低呈增加趋势。当温度降到76K时材料的强度达到最高值,S玻纤／环氧复合材料的拉伸强度最高值可达2．1GPa;E玻纤／环氧复合材料的最大拉伸强度也达到1．4GPa。其原因是由于低温下玻璃纤维的横向收缩比树脂基体小,界面摩擦力得到增强,从而获得高的界面粘接强度。     

Porosity and pore size distribution measurement of cement/carbon nanofiber composites by 1H low field nuclear magnetic resonance

The dispersion effect of carbon nanofibers （CNFs） in aqueous solution and the mechanical properties, porosity, pore size distribution and microstructure of CNFs reinforced cement-based composites were investigated in this paper. To achieve effective dispersion of CNFs, a method utilizing ultrasonic processing and a commercially surfactant were employed. CNFs were incorporated to cementitious materials with the addition of 0.1 wt% and 0.2 wt% of cement with a water/cement ratio of 0.35. The mechanical properties of CNFs/ cement composites were analyzed, the porosity and pore size distribution were characterized by ^1H low field nuclear magnetic resonance （NMR）, and the microstructure was observed by scanning electron microscopy （SEM）. The results indicate that the optimum concentration ratio of MC to CNFs is 2：1 for dispersing in aqueous solution. Moreover, in the field of mechanical properties, CNFs can improve the flexural strength and compressive strength. The increased mechanical properties and the decreased porosity of the matrices correspond to the increasing CNFs content and CNFs act as bridges and networks across cracks and voids.     

环氧树脂/粘土纳米复合材料的制备与表征

首先用己二胺对粘土通过离子交换反应进行改性,然后将改性后的粘土与双酚Ａ型环氧树脂在ＤＭＦ中搅拌混合,脱除溶剂后模浇铸,制备出环氧树脂／粘土纳米复合材料,利用元素分析,红外光谱、等手段表征了材料的结构和性能。     

Effect of nano-silica modification on the tensile property of SMA/GF/CF/epoxy super hybrid woven fabric composites

Tensile properties of epoxy casts together with shape memory alloy (SMA), glass (GF) and carbon (CF) woven fabric reinforced epoxy matrix super hybrid composites were investigated, respectively. In order to enhance the mechanical strength of this advanced material, two categories of modifications including matrix blending and fiber surface coating by nano-silica were studied. Scanning electron microscopy (SEM) and fiber pull-out tests were adopted to complement the experimental results, respectively. Experimental results reveal that the toughness of epoxy matrix is enhanced significantly by adding 2wt% nano-silica. The failure mechanism of SMA reinforced hybrid composites is different from that of GF/CF/epoxy composites. Compared with the matrix modification, the fibers modified by coating nano-silica on the surface have better tensile performances. Moreover, the fiber pull-out test results also indicate that composites with fiber surface modification have better interfacial performances. The modification method used in this paper can help to enhance the tensile performance of the mentioned composite materials in real engineering fields.     

Effect of N on microstructure and mechanical properties of as-cast Ti-6Al alloy

Duetotheirhighspecificstrength,goodcorrosionresistance,goodhightemperatureproperties,titanium andtitaniumalloysareconsideredidealmaterialsforspace,oil,chemicalandmedicalindustries[1-3].They alsohavepotentialapplicationintheautomobileindus try[4-7].Titaniu…     

一种非传统高分子粘结剂改良黏土的强度试验研究

通过室内无侧限抗压强度试验和直接剪切试验研究了不同浓度粘结剂对黏土强度的影响。试验结果表明,粘结剂的加入可以提高黏土体的强度。改良后,黏土的无侧限抗压强度和黏聚力随养护时间的增加均有提高;当养护时间一定时,随着粘结剂含量的增加,黏土的黏聚力和无侧限抗压强度也随之增加,当浓度增加至3%时,黏土的无侧限抗压强度相比2%浓度添加量出现下降。     

Fabrication and Mechanical Properties of TiC／TiAl Composites

TiC/ TiAl composites with different TiC content were fabricated by rapid heating technique of spark plasma sintering ( SPS ). The effect of TiC purticles on microstructure and mechanical properties of TiAl matrix was imestigated. The results indicate that grain sizes of TiAl matrix decrease and mechanical properties are improved because of the addition of TiC particles. The composites display a 26.8% increase in bending strength when 10wt% TiC is added and 43.8% improvement in fracture toughness when 5ut% TiC is added compared to values of TiC-free materials. Grain-refinement and dispersion-strengthening were the main strengthening mechanism. The improvement of fracture toughness was due to the deflexion of TiC particles to the crack.     

Curing behavior of epoxy asphalt

The curing process of epoxy asphalt was analyzed by Fourier transform infrared (FT-IR) spectroscopy. Effect of curing temperature on viscosity of epoxy asphalt, and changes of mechanical properties with curing time were investigated. The evolution of concentration of epoxy band was followed as a function of the applied curing process. The experimental results indicate that the curing reaction rate of epoxy asphalt is invariable before 70 min at 120 °C, and it decreases when curing time exceeds 70 min. The viscosity of epoxy asphalt increases slowly with curing time at initial curing stage. But it increases quickly after initial curing stage and the initial curing time decreases as the curing temperature increases. The tensile strength increases slowly at incipient curing stage and increases rapidly when curing time is form 20 min to 70 min. The elongation at break shows a decrease with curing time, but it exceeds 200% after cured.     

Damping properties of flexible epoxy resin

Amino-terminated polyethers and amino-terminated polyurethane were used as curing agent to cure the epoxy resin together and get a series of cured products. The damping properties of the composites were studied by DMA test at different measurement frequencies. Damping mechanical tests show that the flexible epoxy resin has higher loss factor than common epoxy. The highest loss factor reaches 1.57. Also the height and position of loss factor peak of the flexible epoxy resin varies by changing the content of amino-terminated polyethers. Results shows that the flexible epoxy resin can be used as damping polymer materials at room temperature or in common frequency range.     

温湿场交变环境下外加载荷对不同孔隙率CFRP弯曲力学性能影响

为探究不同孔隙率碳纤维/环氧树脂层合板在仿超音速飞行的高低温湿热老化环境及外加载荷作用对弯曲力学性能的影响规律,基于材料服役期间的吸湿状态和内应力状态,对T700CF/3234EP进行模拟超音速飞机服役环境的高低温交变加速湿热循环试验.通过控制模压压力,制备3种孔隙率分别为0.04、0.08和0.11的层合板,将3种孔隙率的层合板进行加载,加载载荷为层合板最大弯曲载荷的0、30%、40%和60%,然后将其置于高低温环境模拟试验箱中,分别测量不同循环周期复合材料层合板的弯曲强度变化,并采用ABAQUS软件对其弯曲力学性能进行有限元模拟.试验结果表明:温湿场交变环境下,外加载荷和孔隙率加速层合板弯曲强度的下降,在高低温湿热循环4~6周期时,随着载荷的增大,二次固化现象越明显,层合板的弯曲强度变化比较平缓.使用ABAQUS软件建立有限元模型,计算得到的弯曲力学强度变化趋势与试验结果相一致,说明高低温湿热老化环境和外加载荷对复合材料弯曲性能的影响,对不同孔隙率的碳纤维/环氧树脂层合板弯曲性能进行较为准确的预测.     

制备工艺对CNTs/EP复合材料性能的影响

采用溶液共混法制备碳纳米管(CNTs)/环氧树脂(EP)复合材料,主要研究丙酮用量、混合方式、超声时间、CNTs含量等制备工艺对复合材料的热性能和导电性能的影响.通过用SEM、DSC,TGA以及万用表对复合材料进行分析表征,结果表明,丙酮的加入量越多,超声时间越长,CNTs/EP的复合材料的导电性越好,CNTs在复合材料中分散性也好,而随着CNTs含量增加,复合材料的导电性按照逾渗理论的规律提高,且逾渗闶值出现在0.5 0A～1%范围内.利用超声处理伴随着搅拌这种混合方式所得复合材料的导电性最好,加入碳纳米管的复合材料玻璃转化温度Tg和热稳定性能较纯EP有显著提高.     

Modelling the Rheological Properties of Epoxy Asphalt Concrete

This paper presents an investigation into modelling the rheological properties of epoxy asphalt concrete （EAC） by using the Huet-Sayegh model.Complex modulus tests were conducted on EAC specimens at various temperature and loading frequency conditions.Dynamic modulus and phase angles obtained from the complex modulus tests were used in the construction of the Huet-Sayegh model.The dynamic modulus master curve was developed by the Huet-Sayegh model as well as the Burgers model for comparison purpose.The results showed that EAC exhibits typical rheological behavior whose dynamic modulus decreases with the increase of temperature while increases with the increase of frequency,and phase angles increase with the decrease of frequencies and the increase of temperatures.The Huet-Sayegh model predicts the dynamic modulus master curve of EAC very well and much better than the Burgers model over a wide range of frequencies.     

黄麻纤维/环氧树脂复合材料的力学性能

探讨了黄麻/环氧树脂复合材料板的制作方法,并对不同质量分数与长度的黄麻纤维增强的板材进行了拉伸及弯曲性能测试,采用扫描电镜观察了拉伸断面的微观形貌.讨论了纤维质量分数与长度对复合材料拉伸强度、拉伸模量、弯曲强度和弯曲模量的影响.实验结果表明,加入黄麻纤维有利于提升环氧树脂的拉伸和弯曲,纤维质量分数与长度对复合材料力学性...     

聚羧酸减水剂在水泥和泥土表面的吸附行为

采用有机碳测定仪研究了水泥、泥土和水体系中聚羧酸减水剂吸附量与吸附时间、减水剂浓度、体系温度的关系。同时,对减水剂吸附模型和吸附热进行了分析,探讨了聚羧酸减水剂在水泥、泥土颗粒表面的吸附特性。结果表明:水泥和泥土对聚羧酸减水剂的吸附量随时间延长不断增加,最后达到平衡,同时,泥土比水泥对减水剂的吸附量要大,泥土的掺入量为0.5%就会大大降低水泥净浆的流动度;聚羧酸减水剂的吸附基本符合Langmuir等温吸附模型,水泥和泥土对减水剂的饱和吸附量分别为3.7mg/g和10.1mg/g;水泥和泥土对聚羧酸减水剂的吸附量随温度的增大而减小,其吸附是一个放热过程。