共查询到19条相似文献,搜索用时 93 毫秒
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制备了14种膦酸缓蚀剂,其中7种为新报道的化合物。考查了膦酸浓度及溶液pH值对缓蚀性能的影响,分析了膦酸分子结构与缓蚀性能的关系,探讨了膦酸的缓蚀机理。结果表明,在膦酸的浓度低于100mg/L时,随着膦酸浓度的增大,对Q235钢的缓蚀能力明显加强;在高pH值条件下,膦酸的缓蚀效果较好。表面膜分析证实膦酸是一种吸附型的缓蚀剂,苯环上供电子基团有利于形成致密的保护膜。 相似文献
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Mannich碱是较普遍的酸化缓蚀剂之一,其分子结构对缓蚀性能影响较大。以苄叉丙酮为活泼氢化合物,与多聚甲醛、环己胺通过Mannich反应合成了一种新型Mannich碱缓蚀剂M1,采用失重法、极化曲线、交流阻抗、原子力显微镜等研究了其在18%HCl溶液中对Q235钢的缓蚀性能。结果表明:在90℃,18%HCl中,M1含量为0.3%时,缓蚀效率达97.71%;在60℃,18%HCl中,M1含量为0.2%时,缓蚀效率达93.29%;M1为抑制阳极为主的混合型缓蚀剂,在金属表面的吸附符合Langmiur等温吸附模型,缓蚀性能优异。 相似文献
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饱和CO2环境下噻唑衍生物的缓蚀性能和电化学特征 总被引:1,自引:1,他引:1
在油气田的CO2腐蚀控制中,添加缓蚀剂是一种简单、经济而又行之有效的办法.合成了一种噻唑衍生物缓蚀剂,利用腐蚀失重法和电化学方法对其在饱和CO2环境下的缓蚀效果进行了评价,对其电化学特征进行了表征,并初步探讨了其在饱和CO2环境下的缓蚀机理.结果表明,该噻唑衍生物对饱和CO,条件下N80钢的腐蚀有较好的抑制作用,在试验条件下,该缓蚀剂的加入量为500mg/L时,液相及气相缓蚀率分别为86.9%和89.6%;噻唑衍生物主要依靠分子中的S,N原子与N80钢表面直接发生吸附,从而起到缓蚀作用. 相似文献
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The inhibition effect of an excellent environmental-friendly corrosion inhibitor-berberine on hot-dip coated steels in the diluted HCl has been investigated by using quantum chemistry analysis, mass-loss tests, electrochemical measurements and scanning electron microscopy (SEM) observation. Calculation results show that berberine has a nearly planar structure with a number of active centers. The value of Mulliken charge, and the distribution of the highest occupied molecular orbital (HOMO) and the lower unoccupied molecular orbital (LUMO) imply that berberine has a good ability of electron exchange with metal surface. The test results indicate that inhibition efficiency (IE%) increases with the inhibitor concentration and the highest IE can reach 99%. Adsorption of berberine on the coating surface follows Langmuir adsorption isotherm with a single molecular layer by chemisorption. 相似文献
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桐油能自干成膜但水溶性差,在缓蚀剂中的应用有局限性。为此,以桐油为原料合成了桐油酸,将其与二乙烯三胺反应后,产物再与甲基丙烯酸甲酯反应制成桐油酸咪唑啉衍生物,利用红外光谱分析了合成产物的分子结构,利用失重法和动电位极化曲线考察了合成产物在盐酸溶液中对N80钢的缓蚀性能。结果表明:合成的桐油酸咪唑啉衍生物为以阴极抑制为主的混合型缓蚀剂,能有效抑制N80钢在盐酸介质中的腐蚀;随着桐油酸咪唑啉衍生物浓度的增大以及腐蚀介质温度和浓度的降低,N80钢的腐蚀速率下降,缓蚀效率上升。 相似文献
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Corrosion inhibition and adsorption behavior of 2-((dehydroabietylamine)methyl)-6-methoxyphenol on mild steel surface in seawater 总被引:1,自引:0,他引:1
The inhibition effect of a Dehydroabietylamine Schiff base derivative, namely 2-((dehydroabietylamine)methyl)-6-methoxyphenol (DMP) against mild steel corrosion in seawater was evaluated using weight loss and electrochemical techniques (potentiodynamic polarization and electrochemical impedance). The experimental results showed that DMP is a good corrosion inhibitor and the inhibition efficiency increased with the increase of DMP concentration, while the adsorption followed the Langmuir isotherm. X-ray photoelectron spectroscopy, scanning electron microscopy, theoretical calculation of electronic density, molecular electrostatic potential and molecular dynamics were carried out to establish mechanism of corrosion inhibition for mild steel with DMP in seawater medium. The inhibition action of the compound was assumed to occur via adsorption on the steel surface through the active centers in the molecule. The corrosion inhibition is due to the formation of a chemisorbed film on the steel surface. 相似文献
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The present study describes the inhibition of aluminium in 1N HNO3 with different concentrations of 1,2,4-triazole precursors ATD, BATD and DBATD using gravimetric method, potentiodynamic
polarization studies (Tafel), electrochemical impedance spectroscopy (EIS), adsorption studies, surface morphological studies
and quantum chemical calculations at 298 K. Polarization studies clearly showed that ATD, BATD and DBATD act as mixed type
inhibitors. As the electron density around the inhibitor molecule increases due to substitution, the inhibition efficiency
also increases correspondingly. Quantum chemical approach was used to calculate some electronic properties of the molecule
to ascertain the correlation between inhibitive effect and molecular structure of the inhibitor. The corrosion inhibition
efficiencies of these molecules and the global chemical reactivity relate to some parameters, such as E
HOMO
, E
LUMO
, gap energy (ΔE), electronegativity (χ), global hardness (η) and the fraction of electrons transferred from the inhibitor molecule to the metallic atom (DN\Delta \emph{N}). In addition, the local reactivity has been analysed through the Fukui function and condensed softness indices. Both the
experimental and theoretical studies agree well in this regard and confirm that DBATD is a better inhibitor than BATD and
ATD. The adsorption behaviours of molecules on the copper surface have been studied using molecular dynamics method and density
functional theory. The order of inhibitory action is DBATD > BATD > ATD. 相似文献
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1. IntroductionMany studies have been devoted to the inhibitionof steel i. acidic media by organic compounds[1-3],but indole and its derivatives have been relativelylittle studiedl4'5]. The chemical structure of the inhibitor molecules plays a significant role and often determines whether or not a compound will effectivelyinhibit a specific system.The present work has been carried out to investigate the inhibiting effect of indole and some of itsderivatives on the corrosion inhibition of C-ste… 相似文献
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目的 为解决单组分绿色气相缓蚀剂缓蚀性能差的问题,复配一种绿色复合气相缓蚀剂,探究其对碳钢和黄铜金属试样的缓蚀作用。方法 采用腐蚀质量损失、接触角、电化学等试验测试分析复合气相缓蚀剂对碳钢、黄铜的缓蚀效果与成膜耐久性。结果 复合气相缓蚀剂对10号钢、H62黄铜的缓蚀效率分别为84.71%、91.67%,缓蚀性能显著优于单组分气相缓蚀剂;复合气相缓蚀剂在10号钢、H62黄铜表面均形成了缓蚀膜,H62黄铜表面形成的缓蚀膜较10号钢的更具耐久性。结论 与单组分气相缓蚀剂相比,该复合气相缓蚀剂对碳钢、黄铜均具备良好的缓蚀作用,为绿色气相缓蚀剂的防锈包装应用提供支撑。 相似文献