碳织物／PEEK静电粉末预浸工艺树脂含量检测控制系统

介绍了一种由β射线检测仪、微机等组成的碳织物／ＰＥＥＫ（聚醚醚酮）静电粉末预浸过程树脂含量动态监控系统。该系统能够跟踪预浸过程，准确、灵敏地反映树脂含量的变化，并能根据要求及时调整工艺参数，保证预浸料树脂均匀分布，有利于工艺过程的连续化、自动化。本文介绍了这种监控系统的组成及工作原理，绘出了一些预浸料的工作曲线，考察了这种控制系统的性能，验证了其可行性。     

航空工业用热塑性树脂基复合材料研究进展EI

介绍了芳香族热塑性树脂的种类、性能，预浸料、复合材料的制备方法，复合材料的力学性能及其在飞机上的应用。     

纤维增强热塑性树脂预浸料的制备工艺及研究进展

热塑性复合材料因冲击韧性高、环境适应性强、可回收利用等优点,被广泛应用于汽车制造、航空航天、国防军工等领域。但因热塑性树脂加热熔融后较高的黏度使其很难与纤维充分浸渍。预浸料作为制造复合材料的中间材料,现阶段制备工艺已相对成熟,预浸料中纤维已被树脂浸润,因此通过预浸料制备的复合材料孔隙率较低。本文介绍了现阶段常用的热塑性预浸料制备方法及各自的优缺点,包括溶液浸渍法、熔融浸渍法、粉末浸渍法、薄膜叠层法、纤维混杂法以及反应链增长浸渍法。阐述了热塑性树脂熔体浸润纤维的浸渍机理,对浸渍机理的部分研究成果进行了概括。概述了浸渍温度、浸渍压力和牵引速率对预浸带性能的影响。最后指出了国内预浸料生产中存在的主要问题,未来可采用多学科结合、纤维树脂改性、对浸渍过程进行计算机模拟等方法促进热塑性预浸带的产业化发展。     

多功能微机(手动)调控预浸胶机的研制

一.前言 预浸料是制造纤维增强复合材料用的一种预制铺层材料,也是用作复合材料设计和制造的中间材料。目前,在预浸料这一领域里的新发展,就象采用新纤维一样具有重大意义。 单向纤维预浸料所用增强材料常为玻璃纤维、碳纤维和有机纤维,所用树脂一般为热固性树脂和热塑性树脂。 预浸料的制造方法有:溶液胶预浸,熔融树脂预浸、熔融树脂涂膜后传递预浸、胶膜热融后传递预浸、胶膜热融后传递预浸、热塑性树脂制成膜热融传递预浸、热塑性树脂纤维与增强纤维混合排列热融预浸(即双纤维预浸)、热塑性树脂直接熔融预浸等。 制造预浸料用设备如按功能分有单功能预浸机、多功能预浸机;按结构分有滚筒式定长预浸机、连续卷盘     

碳纤维增强热塑性复合材料的制备与性能研究进展

碳纤维增强热塑性复合材料(CRTP)因其具有众多优点而在航空航天、轨道交通、国防军工和风力发电等领域受到广泛的关注。本文总结了近年来国内外关于CRTP制备技术的研究进展，主要从预浸料制备工艺、碳纤维(CF)表面改性技术及CRTP成型工艺3个方面进行阐述，并详细介绍了不同预浸料制备工艺、CF表面改性技术和CRTP成型工艺的优缺点及对所制备CRTP性能的影响；最后对预浸料制备工艺、CF表面改性技术和CRTP成型工艺的发展方向进行了展望。     

复合材料用几种新型树脂研究进展

本文介绍了作为先进复合材料的几种新型树脂基体的进展,预浸料的制备方法,纤维增强复合材料的性能。本文所涉及的预浸方法具有如下优点:适于不同体系的树脂,预浸料树脂含量均匀,生产效率高等。     

热塑性纤维复合材料综述

本文简单综述热塑性纤维复合材料的发展，国内外简况，预浸料的制备方法，制品的成型工艺、性能和轻量化指数，以及应用和展望。     

中温固化3251树脂体系的研究

３２５１系促进剂Ｄ／取代双氰胺／ＣＴＢＮ－双酚Ａ环氧树脂体系，树脂体系各组份互溶性好且溶于丙酮。可制备优质均匀的预浸料，该体系能满足中温固化成型工艺要求，用Ｅ玻璃布增强的复合材料具有良好的力学性能及湿热老化性能。     

预浸料的制备工艺及应用

本文介绍了国内外热固性预浸料和热塑性预浸料的制备工艺和预浸料典型厂家、产品及应用。     

高性能热塑性树脂基复合材料复合方法及成型工艺简介

芳香族聚合物一类新型热塑性工程塑料的出现,有可能代替某些热固性树脂基体制作长纤维增强复合材料。国外对热塑性工程塑料树脂基复合材料进行了大量的研究,已经成功地应用于航空航天事业。保证这种材料取代某些热固性树脂基复合材料的前提是预浸带制造方法和成型工艺技术的实施。本文将对热塑性树脂基复合材料的预浸带制备及成型方法作一简单分析介绍。      

Mode I interlaminar fracture toughness of commingled carbon fibre/PEEK composites

Carbon fibre/poly (ether-ether-ketone) (PEEK) composites were fabricated from plain weave cloth using the commingled yarn of carbon fibres with PEEK filaments. The undirectional specimen was made from the warp of commingled yarn and the weft of PEEK yarn, while the two-dimensional specimen was made from commingled yarns both of the warp and the weft. During the hot-pressing process, PEEK filaments melt to form the matrix of the composite. The interlaminar fracture toughness of the commingled composite was measured and compared with that of the prepreg composite. The critical strain energy release rates,/'G _Ics, obtained for the commingled composites were higher than the prepreg composite. In particular, the two-dimensional composite exhibited higherG _Ic than the unidirectional commingled composite. Factors increasing the fracture toughness of commingled composites have also been investigated by SEM observation of the fractured surface.     

碳纤维/聚醚醚酮(PEEK)复合材料拉拔制管工艺设计和模拟

从太空制造角度出发,设计了一种碳纤维/聚醚醚酮(PEEK)预浸复合板料拉拔连续制管工艺.综合考虑了预浸复合板料的供料放卷过程、冲压、拉拔成形工步和超声焊接工序,并创造性的提出了卷曲拉挤成型方式.利用Johnson-Cook和Holzapfel-Gasser-Ogden模型构建了一种以PEEK为基体,以碳纤维编织布为增强体相互叠加的材料模型,通过实验数据确定材料参数.采用商业软件ABAQUS对各工序分步进行了地面条件下的有限元数值模拟,分析了预浸复合材料板材在供料放卷、冲压拉拔成形过程中的应力分布,并采用蔡-希尔最大变形能理论证明了本文设计的放卷模具和卷曲成形模具可以进行连续制管.在焊接过程中,分析了预浸料基体PEEK在焊接区域产生的Mises应力分布,证明了超声波焊接方案对管材表面质量的影响较小.模拟结果表明,所设计的连续拉拔制管工艺能够快速有效地生产出表面良好的管材.仿真结果可为后续复合材料在轨拉拔连续制管的工艺设计和制造提供借鉴.     

THE AUTOMATION OF THE LAY-UP AND CONSOLIDATION OF PEEK*GRAPHITE FIBER COMPOSITES*

The processing of PEEK/graphite fiber composites is characterized by an inordinate amount of hand labor. This greatly increases the cost, time, and inaccuracy involved in production. Automation of the lay-up and consolidation steps are a prerequisite for the widespread application and acceptance of these, as well as all, high performance materials. Automated techniques for the lay-up and consolidation of PEEK/graphite fiber composites have been developed and are presented in this paper. Discrete part lay-up schemes utilize robotic manipulators and specially constructed tables and allow any lay-up configuration to be automatically produced at high production rates. The size of the discrete parts was limited to 4 by 4 meters by design, not by any inherent difficulties. This size can be increased by enlarging the lay-up table. The length of a continuous sheet was limited by the length of the PEEK/graphite fiber prepreg material currently available. Its width was also restricted to 4 meters by design, but also can be increased to the desired width. Continuous consolidation methods were designed for both discrete and continuous parts. Heating is performed by quartz radiative heaters and consolidation pressure is produced by pressure rollers. These processes were designed taking into consideration     

Electron-beam irradiation effects on mechanical properties of PEEK/CF composite

Carbon fibre-reinforced composite (PEEK/CF) using polyarylether-ether-ketone (PEEK) as a matrix material was prepared and electron-beam irradiation effects on the mechanical properties at low and high temperatures were studied. The flexural strength and modulus of the unirradiated PEEK/CF were almost the same as those of carbon fibre-reinforced composites with epoxide resin. The mechanical properties at room temperature were little affected by irradiation up to 180 MGy, but in the test at 77 K the strength of the specimens irradiated over 100 MGy were slightly decreased. The mechanical properties of the unirradiated specimen decreased with increasing testing temperature, but the high-temperature properties were improved by irradiation, i.e. the strength measured at 413 K for the specimen irradiated with 120 MGy almost reached the value for the unirradiated specimen measured at room temperature. It was apparent from the viscoelastic measurement that the improvement of mechanical properties at high temperature resulted from the high-temperature shift of the glass transition of the matrix PEEK caused by radiation-induced cross-linking.     

Effect of carbon nanotubes on the mechanical properties and crystallization behavior of poly(ether ether ketone)

Pristine carbon nanotubes (CNTs) and noncovalently functionalized carbon nanotubes (f-CNTs) were used to prepare poly(ether ether ketone) (PEEK) composites (CNTs/PEEK and f-CNTs/PEEK) via melt blending. Noncovalently functionalized multiwalled nanotubes were synthesized using hydrogen-bonding interactions between sulfonic groups of sulfonated poly(ether ether ketone) (SPEEK) and carboxylic groups of nanotubes treated by acid (CNTs–COOH). The effects of these two kinds of nanotubes on the mechanical properties and crystallization behavior of PEEK were investigated. CNTs improved mechanical properties and promoted the crystallization rate of PEEK as a result of heterogeneous nucleation. Better enhancement of mechanical properties appeared in the f-CNTs/PEEK composites, which is ascribed to the good interaction between f-CNTs and PEEK. However, the strong interaction of f-CNTs and PEEK chains decreased the crystallization rate of PEEK for high content of f-CNTs.     

超薄预浸料对碳纤维/环氧树脂复合材料导电性能的影响

为了协同提高碳纤维/环氧树脂（CF/EP）复合材料的电性能和力学性能,采用碳纤维丝束展宽、浸润一体化的工艺方法,将12K CF展宽预浸制备成厚度分别为0.02 mm、0.03 mm、0.08 mm、0.10 mm的CF/EP预浸料及其单向层合板,分析测试了微观结构尺度对CF/EP复合材料层合板电阻率、电阻率随温度及在拉伸载荷作用下响应的影响机制。结果表明,随着CF/EP预浸料厚度从0.10 mm减小到0.02 mm,CF/EP复合材料单向层合板中大尺度树脂富集区所占比例明显减小,厚度方向的电阻率从151.3 Ω·cm减小到32.1 Ω·cm,导电性能提高了约5倍;随着温度升高,CF/EP复合材料层合板电阻率逐步下降,厚预浸料层合板沿厚度方向电阻率的下降速率高于薄预浸料层合板;在载荷作用下由CF/EP薄预浸料制成的CF/EP复合材料层合板的电阻率具有较高的稳定性,表明预浸料薄层化有助于提高CF/EP复合材料抵抗载荷作用的能力,从而获得较高的力学性能和电性能。实验结果为CF/EP复合材料结构-功能一体化设计提供了基础。      

羟基磷灰石的表面改性对羟基磷灰石/聚醚醚酮复合材料力学和摩擦性能的影响

采用共沉淀法制备纳米羟基磷灰石（HA）,并用硅烷偶联剂KH560对其进行表面改性;然后,以聚醚醚酮（PEEK）为基体,通过热压成型工艺制备原始HA/PEEK与改性HA/PEEK复合材料。考察两种HA的引入对复合材料结构、力学性能和摩擦性能的影响。利用XRD、FTIR、FESEM、拉伸测试、DMA和摩擦测试对两种HA/PEEK复合材料的结构和性能进行了表征。结果表明：HA表面引入了硅烷偶联剂KH560;改性前后HA的晶型结构没有明显改变;两种HA对PEEK基体的结晶结构也没有产生影响;改性HA在PEEK基体中分散均匀;与纯PEEK相比,10wt%改性HA/PEEK复合材料的储能模量增加了55.56%,玻璃化温度增加了3.6℃,磨痕深度降低了31.1%,有效改善了复合材料的热力学性能和摩擦性能;改性HA/PEEK拉伸强度为68.33 MPa,能够满足人骨的强度要求。     

Influence of prepreg conditions on the void occurrence and tensile properties of woven glass fiber-reinforced polyimide composites

The influence of prepreg solvent content on void occurrence in woven glass fiber-reinforced polyimide composites and their tensile properties was studied. A precursor solution of SKYBOND 703 was diluted in an additional solvent (n-methyl pyrrolidone) and the glass woven fabric was immersed in about 40 wt.% polyamic acid, in solvent. Prepregs were dried at 373 K for different time intervals, ranging from 2 to 24 h. Prepregs with varying residual solvent content under each condition were laid up, and their [(0/90)]₄ composite laminates were formed by autoclaving at a hydrostatic pressure of 0.7 MPa. The relationship of drying time with the amount of residual prepreg solvent, as well as with the volume fractions of fiber and voids was investigated. The void geography and content for each composite laminate, and the tensile strength and modulus at room temperature were also evaluated. The results clearly indicated that, depending on the altering residual solvent content in the prepreg, the void geometry and location influenced reduction of the tensile properties of woven fabric composite laminate. An appropriate prepreg resin viscosity during curing, which avoids reduction of the tensile properties, was revealed.     

A simulation study on the effects of particle size on the consolidation of polymer powder impregnated tapes

The powder prepreg technique offers a low-cost, high-speed method of manufacture of composites. Consolidation of the prepreg tows is a key step in the manufacture of a final `useful' part. The efficiency of the consolidation for any polymer powder prepreg tape produced from powder prepreg processes would conceivably depend on the material properties of the polymer, particle size, temperature, consolidation pressure and volume fraction of the tape. A mathematical process model that identifies and describes a set of parameters to predict the consolidation conditions of a given polymer powder prepreg tape has been developed. A simulation study that identifies the different parameters and compares the advantages and limitations of polymer physical properties and particle size has been performed. An integrated Flow Resistance (FR) index has been developed to mathematically describe the consolidation process. The results show that small powder particle sizes are beneficial to the process.     

Mechanical and thermal expansion properties of glass fibers reinforced PEEK composites at cryogenic temperatures

Polyetheretherketone (PEEK) has been widely used as matrix material for high performance composites. In this work, 30% chopped glass fibers reinforced PEEK composites were prepared by injection molding, and then the tensile, flexural and impact properties were tested at different temperatures. The modulus, strength and specific elongation of glass fibers reinforced PEEK at room temperature, 77 K and 20 K have been compared. And the fracture morphologies of different samples were investigated by scanning electron microscopy (SEM). The results showed a dependence of mechanical properties of glass fibers reinforced PEEK composites on temperature. The coefficient of thermal expansion of unfilled PEEK and glass fibers reinforced PEEK were also investigated from 77 K to room temperature. The results indicated that the thermal expansion coefficient (CTE) of PEEK matrix was nearly a constant in this temperature region, and it can be significantly decreased by adding glass fibers.