Solution-sol-gel processing of superconductors

Bulk materials and thin films of pure and homogeneous YBa₂Cu₃O_7−x and Bi₂Sr₂CaCu₂O_8+x compounds were prepared by a nanocomposite solution-sol-gel (SSG) method. The superconducting oxides of YBa₂Cu₃O_7−x and Bi₂Sr₂CaCu₂O_8+x were prepared at very low temperatures i.e. 750°C and 850°C, respectively by SSG method. Pellets sintered from these nanophasic sol powders showed sharp resistivity drops atT _c ∼ 90°K for YBa₂Cu₃O_7−x andT _c∼67°K for Bi₂Sr₂CaCu₂O_8+x . Thin films were prepared using triphasic sol of Y, Ba, Cu and tetraphasic sol of Bi, Sr, Ca and Cu on MgO and SrTiO₃ substrates. The triphasic sol coated on SrTiO₃ substrates and calcined at 800°C for 12h showed the formation of superconducting phase, YBa₂Cu₃O_7−x with preferred orientation along theC-axis. X-ray diffraction patterns of the Bi₂Sr₂CaCu₂O_8+x films on MgO substrate showed the formation of the superconducting phase with preferential orientation along the C-axis and the microwave absorption data as a function of temperature of this film revealed the onset temperature to be 90°K.     

Growth and characterization of laser-deposited Ag-doped YBa2Cu3O7−x thin films on bare sapphire

Microstructural and superconducting properties of YBa₂Cu₃O_7−x thin films grownin situ on bare sapphire by pulsed laser deposition using YBa₂Cu₃O_7−x targets doped with 7 and 10 wt% Ag have been studied. Ag-doped films grown at 730°C on sapphire have shown very significant improvement over the undoped YBa₂Cu₃O_7−x films grown under identical condition. A zero resistance temperature of 90 K and a critical current density of 1·2×10⁶ A/cm² at 77 K have been achieved on bare sapphire for the first time. Improved connectivity among grains and reduced reaction rate between the substrate and the film caused due to Ag in the film are suggested to be responsible for this greatly improved transport properties.     

Magnetic Fieid-lnduced Recovery of Superconductivity in Epitaxial YBa2Cu3O7-x Films at Microwave Frequencies

An anomalous magnetic field-effect has been observed in the microwave surface impedance of epitaxial YBa₂Cu₃O_7−x films on LaAlo₃ substrates. The application of dc and microwave magnetic fields up to 20 mT caused a significant decrease of microwave surface reactanceX _s (≤3%) and resistanceR _s (≤20%) at 8.5 GHz, 77 K and at 87 GHz, 4.2 K. The field effects onX _s andR _s s were found to correlate within the framework of the two-fluid model. The observed effect is attributed to the presence of magnetic impurities in the superconducting films, giving rise to pair breaking. Alignment of the impurity spins suppresses the spin-flip scattering rate and, as a result, leads to a recovery of microwave superconductivity.     

Investigation of high temperature superconductivity through microwave absorption method

The field dependence and near zero magnetic field microwave absorption as a function of rf power in YBa₂Cu₃O_7−δ and Bi-Ca-Sr-Cu-O has been studied using a varian ESR spectrometer. A model of microwave absorption built on diamagnetic tensor susceptibility has been proposed which explains the observed results satisfactorily.     

Intermittent Flux Penetration at Different Temperatures in?YBa2Cu3O7?x on NdGaO3 Substrates

In type-II superconductors, increasing applied magnetic field penetrates gradually in the form of magnetic vortices. It is of great interest to understand the dynamics of magnetic flux in different superconducting materials, as this phenomenon can severely limit the performance of superconductors in applications. YBa₂Cu₃O_7?x (YBCO) is an important high-temperature superconductor, but until recently, it has been hard to make wires from it due to misalignment of superconducting grains. A solution to this problem is to deposit YBCO on vicinal substrates to better align the grains. Some of these samples show a strongly intermittent flux penetration at low temperatures. In this work, we have studied flux penetration in YBCO deposited on a 14° vicinal substrate of NdGaO₃ (NGO) at different temperatures.     

Two-gap superconductivity and microwave properties of YBCO

The YBa₂Cu₃O_7–x compound contains two conductive subsystem and as a result displays a two-gap structure. The Cu-O₂ planes are characterized by intrinsic pairing, whereas the superconducting state of the Cu-O chains is induced by two different charge-transfer channels (intrinsic proximity effect and phonon-mediated transfer). Oxygen ordering affects the value of the induced energy gap. Such spectrum along with a short coherence length lead to peculiar microwave properties of YBCO thin films. The large residual microwave losses are explained in the framework of the two-gap model.     

Irreversible change of surface impedance of high-Tc thin films due to D.C. magnetic field commutation

The magnetic field dependence of the surface impedance (resistance and reactance) of high-T _c thin films is found employing measurements of the quality factor and the frequency of the parallel plate resonator in a dc magnetic field up to 500 Oe at 10 GHz.c-Oriented YBa₂Cu₃O₇ thin films are examined. Enhancement of surface resistance and inductance with increase of magnetic field is observed. The effect of irreversible increase of surface impedance as compared to its initial values after a cycle of magnetic field commutation is found. A qualitative explanation of the observed effects based on the picture of magnetic vortex penetration and accumulation in the film due to strong pinning is presented.     

High-temperature superconducting dual-mode resonator on (100) MgO substrate

We report, for the first time to our knowledge, a clear resonant peak split in the range of 7.7–9.7 GHz in a perturbed dual-mode disk-type resonator (DMDR) made of YBa₂Cu₃O_7–x (YBCO) superconducting thin film on MgO substrate. Epitaxial YBCO superconducting thin films were grown on (100) MgO substrates by pulsed laser deposition technique. The critical temperature of superconducting thin film on MgO substrate was 85 K. Superconducting dualmode disk resonators were designed by microwave design software, EEsof, and patterned by photolithography and a wet-etch process. The unloaded quality factor (Q_UL) of the superconducting DMDR was found to be 1,312 at 77 K. We believe this type of DMDR can be utilized for dual-mode resonator-based filters for satellite communications.     

Microstructural study of YBa2Cu3O7/SrTiO3/YBa2Cu3O7 heteroepitaxial trilayer films grown on (100) SrTiO3 substrates

Detailed transmission electron microscopic study has been carried out on heteroepitaxial YBa₂Cu₃O₇/SrTiO₃/YBa₂Cu₃O₇ trilayer thin films grown on (100)SrTiO₃ substrates prepared by DC and RF magnetron sputtering. The microstructural results showed the existence of somea-axis-oriented YBCO grains 20–90 nm wide in thec-axis-oriented YBCO matrix. Some of thea-axis grains in the lower YBCO thin film layer have protruded into the above SrTiO₃ layer, which may cause short circuit between the two YBCO superconducting layers. This is unsuitable for the application of trilayer thin films for microelectronic devices. The defects on the surface of the substrates would also influence the growth quality of the YBCO thin films.     

Effect of additives on the morphology and superconductivity of YBa2Cu3O6+x ceramic materials

The effect of the addition of 0–15 wt.% alumina powder on the grain size, morphology and superconducting properties of sintered YBa₂Cu₃O_6+x was investigated as a function of alumina concentration in the composites. The results suggest that the grain size of YBa₂Cu₃O_6+x decreases with an increase in the additive concentration. Some surface erosion of the YBa₂Cu₃O_6+x grains was also noticeable in Al₂O₃/YBa₂Cu₃O_6+x composites. The results also indicate that the additive tends to stabilize the nonsuperconducting tetragonal phase of the YBa₂Cu₃O_6+x at the expense of the superconducting orthorhombic crystal phase.     

Effect of PrBa2Cu3O7?x buffer layer thickness on the properties of YBa2Cu3O7?x thin films grown on sapphire by laser ablation

Superconducting YBa₂Cu₃O_7–x (YBCO) thin films were deposited onr-plane A1₂O₃ substrates with PrBa₂Cu₃O_7–x (PBCO) buffer layer by XeCl excimer laser ablation. The thickness of PBCO buffer layer was systematically changed to investigate the superconducting properties of YBCO thin films on sapphire. The structure and surface morphology of the films were characterized by X-ray diffraction and scanning electron microscopy (SEM). Superconducting transition temperatures were varied depending on the buffer layer thickness. Interdiffusion between laser-ablated YBCO thin films and A1₂O₃ substrates had been studied by Auger electron spectroscopy (AES). The results of this study show that diffusion does not occur between the YBCO thin film and the substrate even with 20 Å thick PBCO buffer layer.     

Estimation of intragrain magnetic flux motion viscosity in high-temperature superconductors

A simple method for evaluation of the lower limit of intragrain magnetic flux motion viscosity is presented. We have also shown that in our experiment the energy loss in an alternating magnetic field in a granular YBa₂Cu₃O_7–x superconductor prepared by the standard sintering method is determined by thermally assisted magnetic flux flow into superconducting grains and does not depend on the intergrain space.     

DC SQUIDs based on YBCO step edge junctions

We describe the fabrication and testing of dc SQUIDs (Superconducting QUantum Interference Devices) obtained by photolithographic patterning of YBa₂Cu₃O_7–x thin films deposited both on SrTiO₃ and MgO substrates. The Josephson junctions in the superconducting loop are of the step-edge type, where the weak link is obtained through the growth of grains with different orientations across suitably prepared steps previously etched on the substrate surface. TheI–V characteristics of the devices tested show multiple branches and instabilities having a weak dependence on the external magnetic field, probably due to formation of junction clusters on the substrate step. The SQUID devices showed quantum interference behavior and an easily detectable voltage modulation with the applied magnetic field at a temperature of 77 K.     

Critical current in YBa2Cu3O7 ceramics

Measurements of critical currents using a four-point direct current (dc) method and an alternating magnetic field method have been performed on several superconducting YBa₂Cu₃O₇ ceramics at 77 K. In the presence of a constant magnetic field, the critical currents obtained with the alternating field method are several orders of magnitude larger than the critical currents measured by the dc method. Also, we observed a minimum in the dc critical current as a function of applied transverse magnetic field. Several authors have suggested that these ceramics behave as individual superconducting grains coupled by Josephson junctions. In this paper, we explain the two observations above using that model.     

Effect of bismuth replacement at barium site in Y-Ba-Cu-O system

X-ray diffraction, electron paramagnetic resonance, microwave absorption and resistivity measurements were carried out on YBa_2−x Bi _x Cu₃O₇ (0≤x≤0·5) superconductors in order to study the effect of bismuth on the structural and superconducting properties. A decrease in sintering temperature increased the amount of impurity phase. Transition from an orthorhombic (superconducting) phase to tetragonal structure produced no significant change in EPR zero-field signal at liquid nitrogen temperature (LNT). The non-resonance signal height decreased on higher concentration of bismuth. Sintered YBa_2−x Bi _x Cu₃O₇ superconductor had a strong EPR zero-field signal at LNT. We have evaluated particle size from XRD and EPR studies. The average particle size was about 0·4μm.     

Generation of microwave oscillations in a superconducting tunnel mesa-structure with a ferromagnetic insulator interlayer

Spin-polarized current in thin-film tunnel mesa-structures formed by epitaxial cuprate superconducting (YBa₂Cu₃O_7–δ) and manganite (LaMnO₃) films and an upper superconducting Au–Nb bilayer is studied experimentally. Intrinsic narrow-band generation in the microwave range is reported. Its frequency is tuned by the bias voltage and an external magnetic field.     

Comparison of high-pressure dc-sputtering and pulsed laser deposition of superconducting YBa2Cu3O x thin films

Superconducting YBa₂Cu₃O_x thin films were deposited on NdGaO₃ (110) substrates using two different techniques: dc sputtering at high oxygen pressure and pulsed laser deposition. The structure, electrical properties, and surface morphology of the obtained films were compared. The superior crystal quality of dc-sputtered films fabricated at the same temperature and at oxygen pressure of the same range as for laser-deposited films can be explained by a lower deposition rate providing time for recrystallization processes. The re-evaporation becomes significant for dc sputtering at high deposition temperatures and results in Badeficient films. The high mobility of atoms on the surface of the growing film during laser deposition helps in the formation of smoothc-oriented areas of the film.     

Interaction between the Ferromagnetic Dots and Vortices: Numerical Calculation and Experimental Results

Enhancing the pinning force in high-T _c superconductors can be achieved by externally introduced periodic magnetic dots. We numerically calculate the interaction between ferromagnetic dots and vortices in high-T _c superconductors. The London equation is used to generate two-dimensional vortex lattice. In the matching condition, we calculate the attraction force between magnetic dots and vortices. It is found that in an ideal condition, the pinning force of the magnetic dot reaches 2.5×10⁻¹¹ N that is more than one order magnitude stronger than the intrinsic pinning force in YBa₂Cu₃O₇ thin films. In the experimental side, we use a novel nano-technique to deposit periodic submicron Ni dots on YBa₂Cu₃O₇ thin films. The current versus voltage characteristics of an YBa₂Cu₃O₇ thin film strip with uniform Ni dots are measured at various temperatures and magnetic fields. They are compared with the current versus voltage characteristics of a bare YBa₂Cu₃O₇ thin film strip without magnetic dots. It is found the critical current value of the strip with Ni dots reduces with a much slower pace as the magnetic field strength increases in comparison with the value of the bare sample.     

High-temperature superconducting microwave devices: Fundamental issues in materials, physics, and engineering

High-T _c superconductivity has generated a great deal of interest because of the challenges it presents in the fields of material science, condensed matter physics, and electrical engineering, and because of the potential applications which may result from these research efforts. Thin-film passive microwave components may become the first high-temperature superconducting (HTS) devices available for widespread use and commercialization. In this article, we review aspects of material science, physics, and engineering which directly impact high-T _c superconducting microwave devices and discuss issues which determine the performance of these devices. Methods of growing HTS thin films on large-area substrates, techniques for fabricating single-level HTS passive microwave components, and the relevant properties of high-T _c superconducting films are discussed, with a focus on thin films of the HTS material YBa₂Cu₃O_7–. Several known mechanisms for microwave loss in both the superconductor and the dielectric substrate are presented. An overview of the general classes of superconducting passive microwave devices is given, and representative microwave devices which have been recently demonstrated are described in detail. Examples of a select few HTS active microwave components are also presented. Potential microwave applications are illustrated with comparisons to current technology.     

Superconductive YBa2Cu3O7−x fibres from an extrudable dispersion of a particulate precursor

A particulate precursor of YBa₂Cu₃O_7–x was dispersed in a concentrated acetic/formic acid solution of yttrium, barium and copper acetates to form an extensible, viscous mixture. This dispersion was stable, unlike one prepared from superconductive YBa₂Cu₃O_7–x itself. Fibres extruded from the viscous dispersion were fired at 935 °C in the presence of oxygen.Although the fired fibres were not fully densified, they had a sharp Meissner transition temperature at 90 K and an apparent critical current density (J _c) of 900 A cm^–2 (1800 A cm^–2 corrected for porosity) at 77 K. The superconducting fibre was sensitive to magnetic field, which is evidence of weak coupling between the superconducting grains.