烧结温度对稀土永磁Sm(Co0.72Fe0.15Cu0.1Zr0.03)7.5的磁性能的影响

采用粉末冶金法制备稀土永磁Sm(Co0.72Fe0.15Cu0.1Zr0.03)7.5,研究烧结温度对磁体的磁性能的影响.结果表明:随着烧结温度的提高,剩磁Br、内禀矫顽力Hci及最大磁能积(BH)max都先增加后降低.虽然Br在烧结温度为1220℃时获得最大值0.95T,但磁体的综合磁性能在烧结温度为1215℃时最优,Br、Hci和(BH)max分别达到0.94T、2276.6kA·m-1和171.9kJ·m-3.1215℃烧结的磁体的温度稳定性较好,有望应用到550℃环境中.     

烧结温度对(Nd_(0.947)Dy_(0.053))_(15)(Fe_(0.83)Co_(0.17))77B_8永磁体剩磁的影响

本文用磁测量和差热分析等技术,研究了(Nd_(0.947)Dy_(0.053))_(15)(Fe_(0.83)Co_(0.17))_(77)B_8合金的剩磁(Br)和最大磁能积(BH)_(max)与烧结温度(T)的关系。合金的Br主要取决于烧结温度,而时效处理对Br的影响甚小。(BH)_(max)与Br~2成正比关系。对于所研究的磁体,最佳烧结温度为1100℃,最佳剩磁Br=1.250T,(BH)_(max)=286.1KJ/m~3。     

稀土Dy掺杂SrFe_(12)O_(19)永磁铁氧体的结构与性能

研究了掺杂稀土Dy对锶铁氧体制备工艺、结构与性能的影响关系。研究表明,取向磁场对铁氧体磁性能的影响十分显著:随着取向磁场强度的增加,锶铁氧体晶粒发生的晶面择优取向度也增大,剩磁Br、最大磁能积(BH)max和矫顽力Hc均有上升趋势。烧结温度的影响则较复杂:随着烧结温度的增加,剩磁Br和最大磁能积(BH)max均有上升趋势,而矫顽力Hc则呈下降之势。通过在Y30牌号SrFe12O19预烧料基础上掺杂0.2%Dy2O3,经700kA/m磁场、4414N/cm2压力湿法成型的样品在1230℃温度下烧结1h后的磁性能达到了Br=398mT、Hcj=254kA/m和(BH)max=29.1kJ/m3,它与不掺杂Dy2O3的样品相比分别提高了12mT、31kA/m和0.7kJ/m3。     

钇掺杂M型锶铁氧体的结构与磁性能研究

采用固相烧结法于1150℃保温烧结3h制备了钇掺杂的M型锶铁氧体SrYxFe(12-x)O19(x=0,0.25,0.5,0.75,1.0)预烧料,再将预烧料在取向磁场下压制成型后于1295℃保温3h烧结成磁体。用X射线衍射仪对烧结磁体的相结构进行分析,用扫描电子显微镜对烧结磁体的表面形貌进行分析,用磁性能测试仪测试烧结磁体的磁性能。结果表明,随着钇掺杂量的增加,晶格常数a呈现非常微小的变化,c缓慢增大,a/c先增大后减小,晶体X射线密度dX-ray近似呈线性增加。SEM分析表明制备的磁体具备典型的六方晶系结构的形貌特征。磁性能研究表明随着钇掺杂量的增加,剩磁Br单调增加,内禀矫顽力Hcj、最大磁能积(BH)max与磁感矫顽力Hcb的变化规律均为先增大后减小;当x=1.0时,剩磁Br达到最大值420.7mT,但内禀矫顽力Hcj随之变为最小值;当x=0.75时Hcj达到最大值323.7kA·m-1,同时剩磁Br达到了410.4mT。     

纳米晶复合Nd9.5Fe76Co5Zr3-xNbxB6.5（x=0～3.0）粘结磁体的磁性能和温度系数的研究

采用熔体快淬法及真空退火工艺制备了Nd9.5Fe76Co5Zr3-xNbxB6.5(x=0～3.0)粘结磁体,研究了其磁性能及温度系数。结果表明,随着Nb含量的增加,合金剩磁逐渐提高,磁能积和矫顽力呈现先增大后减小的趋势。Zr元素与Nb元素复合添加,能够有效地改善矫顽力温度系数β。经最佳条件退火处理后制备的Nd9.5Fe76Co5Zr1.5Nb1.5B6.5的粘结磁体,具有最优的综合磁性能:Br=0.717T,Hcj=773kA/m,(BH)max=82kJ/m3,α20～150℃=-0.111%/℃,β20～150℃=-0.356%/℃。     

流动温压成型黏结钕铁硼/锶铁氧体复合磁体的研究EI北大核心CSCD

采用流动温压成型工艺制备黏结钕铁硼/锶铁氧体复合磁体,研究温压工艺参数对钕铁硼/锶铁氧体复合磁体磁性能的影响。结果表明:随着温压温度、压制时间以及保压压力的提高,黏结复合磁体的磁性能呈现先增大后减小的趋势。流动温压成型参数的选择与黏结剂有关,采用酚醛环氧树脂BPANE8200为黏结剂时,流动温压成型的最佳工艺参数:77℃加载900MPa并保压8min,复合磁体的剩磁B_r、内禀矫顽力H_(cj)以及最大磁能积(BH)max均获得最大值,即Br=522mT,Hcj=740.48kA/m,(BH)max=39.82kJ/m^3。     

2:17型Sm-Co整体辐向永磁环烧结工艺的研究

针对2:17型Sm-Co整体辐向永磁环在烧结过程中出现的问题进行了研究,并通过SEM、EDS等分析了真空预烧和烧结温度对磁体性能的影响原因.结果表明:调整合适的烧结工艺过程能有效地减少永磁环的开裂和变形;在1190℃进行真空预烧,明显改善了永磁体的性能,预烧时间在20min时,磁性能最好.烧结温度对永磁体性能有着非常重要的影响,合适的烧结温度为1220℃,烧结时间为70min.永磁体的磁性能:Br=1.08T,Hcj＞2100kA/m,(BH)max=212kJ/m3.     

Nd2Fe14B/α-Fe纳米复合永磁的制备和性能

用超声化学法制备纳米Fe颗粒包覆的Nd2Fe14B复合粉体,将其在Ar气保护下经放电等离子烧结(SPS),得到Nd2Fe14B/α-Fe纳米晶复合磁体.Fe名义质量分数为5%的烧结磁体具有较高的磁性能:Br=0.86 T,Hci=683.8 kA/m,(BH)max=95.92 kJ/m3.烧结前对复合粉末进行适当的高能球磨,能促进显微组织进一步细化,增强软磁相与硬磁相之间的交换耦合,使相同Fe含量和烧结工艺的磁体Br和(BH)max分别提高到0.94 T和113.6 kJ/m3.     

放电等离子烧结温度对热压/热变形NdFeB纳米晶永磁体磁性能的影响

采用放电等离子烧结技术制备了热压/热变形NdFeB磁体。研究了不同烧结温度对热压磁体、热变形磁体微观结构及磁性能的影响。结果表明,随烧结温度的升高,磁体密度上升,680℃时已达理论密度的99.7%;另一方面,晶粒则随温度的增加发生长大。剩磁和最大磁能积受密度和晶粒大小的交互作用,在650℃时达最大:(BH)m=129kJ/m3,Br=0.87T,Hci=914kA/m。热变形后,磁体主相晶粒的c轴逐渐转向与压力平行的方向,形成磁晶各向异性,使磁体的剩磁和最大磁能积大幅增加。热压烧结温度对热变形磁体的磁性能有着极大影响,其剩磁和最大磁能积随热压温度的升高先升高后降低,620℃热压后,热变形磁体磁性能达最大:(BH)m=339kJ/m3,Br=1.49T,Hci=576kA/m。     

含Ti和C的纳米复合Nd2Fe14B／α—Fe磁体研究

研究Ti和C添加对Nd9.4Fe79.6B11合金磁性能的影响规律。结果表明:Ti和C联合添加能够在不降低合金剩磁的情况下显著提高合金的矫顽力,最佳工艺条件下制备出的Nd9.4Fe75.6Ti4B10.5C0.5合金薄带的剩磁Br=0.91T,矫顽力Hcj=975.6kA/m,磁能积(BH)max=135.4kJ/m3。在磁体密度为6.1g/cm3时,黏结Nd9.4Fe75.6Ti4B10.5C0.5磁体剩磁Br=0.68T,内禀矫顽力Hcj=975kA/m,最大磁能积(BH)max=76 kJ/m3,性能和MQ-D磁粉制备的黏结磁体性能相当,具有低价位高性能的特点。     

Irreversible Colossal Magnetoresistance in La0.58Dy0.09Ca0.33MnO3

The representative sample La0.58Dy0.09Ca0.33MnO3 of Dy doped La0.67Ca0.33MnO3 rare-earth manganites was investigated.The most important effect of Dy doping is to introducethe magnetoimpurity and form the spin clusters which induce dramatically large CMR in Lao.58Dyo.09Cao.33MnO3. The fitting results of field-induced resistivity decrease to the Brillouin function indicate that the CMR is caused by the spin dependent hopping between spin clusters. It is the magnetic field that reduces the size of spin clusters and induces a field-induced irreversible CMR behaviour.     

The Rockwell C hardness of quenched high-purity iron-carbon alloys containing 0.09 to 1.91% carbon

The Rockwell C hardnesses of thirteen high-purity iron-carbon alloy specimens that had been brine-quenched from temperatures in the austenite region to room temperature were measured. The hardness versus wt % C curve exhibits a maximum value of 65.5 R_c near 0.9% C. The decrease in hardness at carbon concentrations >0.9% is the result of a rapid increase in the volume fraction of retained austenite. Attention is called to the desirability of using these or similar data in materials texts to illustrate this structure-property relationship.     

The Particle Size Effect on the Irreversible Magnetization and Critical Current Density in Low Fields for Polycrystalline SmFeAsO0.91F0.09 Superconductors

Journal of Superconductivity and Novel Magnetism - The particle size dependence of the isothermal magnetization loops, critical current density, and the irreversibility field were determined for a...     

Effects of high-temperature annealing on magnetic properties of (Zn0.91Mn0.09)O thin films grown by RF magnetron sputtering

The (Zn_0.91Mn_0.09)O thin film annealed at 1000 °C for 60 min in N₂ atmosphere showed two kinds of Curie temperature (T_C) values of T_C1 around 130 K and T_C2 above 300 K while the as-grown (Zn_0.91Mn_0.09)O thin film showed typical ferromagnetism with the T_C of 108 K. It is expected that the increase of T_C up to T_C1 might be attributed to the enhancement of crystal magnetic anisotropy because the increases of (0 0 0 l) peak for X-ray diffraction patterns and Mn²⁺-related emission for photoluminescence spectra were observed for annealed (Zn_0.91Mn_0.09)O thin films. The increase of T_C above T_C2 might be originated from the formation of nano-sized (Zn_0.91Mn_0.09)O islands because it was confirmed that the nano-sized (Zn_0.91Mn_0.09)O islands were formed after annealing treatment and that they revealed clearly the magnetic domains at 300 K for the measurements of atomic force microscopy and magnetic force microscopy, respectively. The room temperature ferromagnetism in the nano-sized (Zn_0.91Mn_0.09)O islands is considered to be originated from the inhomogeneous distribution of Mn ions.     

Structural and dielectric properties of Pb0.91(La,K)0.09(Zr0.65Ti0.35)0.9775O3 ceramics

Potassium-modified polycrystalline samples of PLZT, Pb_0.91(La_{1 – z/3}K_z)_0.09(Zr_0.65Ti_0.35)_0.9775O₃ [z = 0.0, 0.1, 0.3, 0.5, 0.7], were prepared using sol-gel technique. X-ray diffraction (XRD) of these compounds show that they can be formed in single phase at 800 °C. Pellets prepared from the above powders were sintered at 1100 °C. Detailed studies of the dielectric constant () and loss tangent (tan ) of the compounds at different frequencies (400 Hz to 10 kHz) at room temperature (RT) and temperature (RT to 350 °C) suggest that the compounds undergo ferroelectric phase transition of diffuse-type on increasing K-concentration. Analysis of diffuseness of these compounds gives a value close to 2, which indicates the presence of higher degree of disorder in PLZT substituted by K. The dielectric constant () is found to increase initially and then to decrease with increasing K concentration.     

High-temperature thermoelectric properties of Na(Co0.91, Ni0.09)2O4 fabricated by solution combustion method for power generation

High-quality nano-sized Na(Co0.91Ni0.09)2O4 powders, i.e., 27 nm in average size, were synthesized by the solution combustion route. The magnitude of the electrical conductivity, the Seebeck coefficient, and the power factor for Na(Co0.91Ni0.09)2O4 depended strongly on the fuel used and followed the order of aspartic acid > glutamic acid > alanine > glycine. The order of the thermoelectric characteristics was consistent with that of the density of Na(Co0.91Ni0.09)2O4. The maximal power factor (1.06 x 10(-3) Wm(-1) K(-2)) was achieved for aspartic acid-processed Na(Co0.91 Ni0.09)2O4 twice-sintered at 800 degrees C. We believe that the solution combustion route was highly effective for fabricating high-efficiency thermoelectric materials.     

Spectroscopic properties and high-power laser operation of Yb0.14:Y0.77Gd0.09Ca4O(BO3)3 mixed crystal

We report, for the first time to our knowledge, on the spectroscopic properties and continuous-wave laser performance of Yb_0.14:Y_0.77Gd_0.09Ca₄O(BO₃)₃, a mixed rare earth calcium oxyborate Yb-ion crystal. Under simple end-pumping conditions with a 976-nm diode, efficient CW laser operation was demonstrated at room temperature, producing an output power of 14.1 W at 1084.4 nm with an optical-to-optical efficiency of 48%; while operating around 1045 nm, the laser could generate an output power as high as 23.0 W, with optical-to-optical and slope efficiencies amounting, respectively, to 57% and 70% with respect to incident pump power. The polarized absorption and emission cross sections are also presented. The impressive results demonstrated reveal the great potential of these mixed oxyborates in developing new promising Yb-ion laser crystals.     

Thermophysical Properties of Solid Solutions of Bi1 –xNdxFe1 –xMnxO3 (x = 0.03, 0.09) Multiferroics at High Temperatures

High Temperature - The thermal diffusivity, thermal conductivity, and specific heat of solid solutions of Bi1–xNdxFe1 –xMnxO3 (x = 0.03, 0.09) multiferroics have been studied in a wide...