钢结硬质合金覆层材料的磨损性能研究

首次用液相烧结法成功地制备出钢结硬质合金钢硬质覆层材料 FC- 和 FC- ,并对其磨损性能进行了研究。液相烧结使得钢结硬质合金与钢基体形成良好的结合界面。抗磨损实验表明 :覆层材料获得了接近于钢结硬质合金的抗磨损性能 ,与钢基体相比抗磨损性能得到显著提高 ,FC- 的抗磨损能力好于 FC- 。     

多元硬质合金覆层材料力学性能的研究

为提高钢材表面的耐磨损和耐腐蚀能力,以Mo粉、Fe-B合金粉和Fe粉为基本原料,加入WC、Cr3C2、TiC等碳化物硬质相和C、Ni、Cr等合金元素,采用真空液相烧结工艺,在Q235钢基体上制备多元硬质合金覆层材料.对覆层材料进行了洛氏硬度测试及弯曲强度测试,结果表明:CW系覆层材料的硬度达到HRA84.8,是Q235钢基体硬度的2.3倍;CW系覆层材料的弯曲强度值达到1175.52MPa,是Q235钢基体弯曲强度的1.4倍;掺加碳化物硬质相显著提高了Mo2FeB2硬质合金覆层材料的硬度和弯曲强度.利用扫描电镜观察了硬质合金覆层以及覆层-钢基体界面的微观组织结构,发现硬质合金覆层内部组织结构致密,覆层与钢基体之间形成了具有一定厚度的过渡层.     

铸造烧结三元硼化物硬质合金-钢覆层材料

运用铸造烧结技术,在铸钢件表面制备生成了厚度约为3 mm~4 mm的Mo2FeB2硬质合金表面覆层材料。研究分析表明,硬质合金覆层中生成了大量弥散分布的三元硼化物陶瓷硬质相。利用SEM-EDS研究了硬质合金覆层的微观结构和元素分布,并研究了覆层-钢基体界面微观结构和界面区元素分布,发现硬质合金覆层与钢基体之间形成了一个具有一定厚度的过渡层,并且两相之间形成了良好的冶金结合。讨论了硬质合金覆层-钢基体之间界面层形成的机理。     

热处理对TLMW50烧结覆层组织及磨粒磨损性能的影响

利用液相烧结工艺成功制得以钢为基、以TLMW50钢结硬质合金为耐磨覆层的复合材料。利用SEM、XRD对经1050℃～1100℃淬火、150℃～250℃回火的TLMW50覆层材料的组织进行分析研究,在ML-10磨粒磨损试验机上对TLMW50覆层的磨粒磨损性能进行测试,结果表明:经过淬火、回火处理的由珠光体+碳化物转变为马氏体+碳化物覆层组织得以不同程度的改善;覆层硬度相由烧结态的45.5HRC上升到60HRC以上。其中,1050℃淬火、150℃回火工艺最优,覆层的磨粒磨损量最少,耐磨性最好,所对应的覆层组织粘结相中除马氏体外还有Hagg碳化物形成,复式碳化物会演变为WC和Fe-WO4等形式。     

钢结硬质合金覆层的微观结构分析

采用液相烧结法将爆炸压实后的钢结硬质合金粉末复合在碳钢表面,成功获得覆层材料。利用扫描电子显微镜、透射电子显微镜对覆层及界面的微观结构进行了研究,结果表明:在烧结温度1282℃￣1350℃时,界面组织为珠光体;在1350℃时,扩散层厚度可达30μm,而且钢结硬质合金/碳钢的界面为扩散型,界面结合良好。     

铸造法制备金属陶瓷/钢基覆层材料的组织及性能

以FeB、Mo等粉末为主要原材料,采用先烧结陶瓷后铸造复合的方式制备金属陶瓷/钢基覆层材料,并对覆层材料的界面组织、覆层硬度、覆层耐磨性进行了研究。结果表明,金属陶瓷/钢基覆层材料由表及里分别为金属陶瓷表层、过渡区及钢基体,过渡区由3层过渡层构成梯度组织结构。金属陶瓷与钢基体形成冶金结合,界面组织致密无缺陷。金属陶瓷覆层的硬度(HV)为1 098,远高于45钢,其耐磨性与硬质合金YG8相当。     

热处理后钢结硬质合金覆层中粘结相组织转变分析

采用液相烧结技术成功制得碳钢/钢结硬质合金TLMW50覆层复合材料。为了提高覆层材料的耐磨性等性能,将烧结复合成功的碳钢/TLMW50覆层复合材料进行淬火和回火热处理。利用XRD、SEM和TEM对热处理后的试样覆层粘结相组织进行分析。结果表明:在1050℃淬火、150℃￣250℃回火热处理后钢结硬质合金TLMW50覆层中粘结相组织发生明显转变,由烧结态下的片状珠光体组织转变为针状马氏体,1050℃淬火、200℃回火后TLMW50覆层中粘结相回火马氏体组织较其它回火温度处理后的覆层粘结相组织更细密。     

铸造烧结法制备WC-钢覆层材料的力学性能研究

采用铸造烧结技术在铸钢件表面制备了WC-钢覆层材料,并对其力学性能进行了研究。结果表明,在WC覆层与钢基体界面处,存在一个覆层高硬度向基体低硬度渐变的过渡区。随着覆层中WC含量的增加,无论在压应力还是张应力条件下试样的弯曲强度均不断提高,并且较大的载荷主要由具有更高弹性模量的WC硬质合金层承载。     

热处理对钢结硬质合金TLMW50覆层微观组织的影响

利用液相烧结工艺成功制得以碳钢为基材，以TLMW50钢结硬质合金为耐磨覆层的复合材料。利用SEM、XRD等手段研究了1050℃淬火，150℃、200℃和250℃回火以及1100℃淬火，150℃、200℃和250℃回火6种不同热处理工艺对覆层材料的组织及微观形貌的影响。结果表明，上述6种热处理工艺均可以使钢结硬质合金TLMW50覆层中粘结相组织由珠光体转变为回火马氏体，硬质相结构会发生改变。其中1050℃淬火，150℃回火工艺较其它5种工艺优越，覆层粘结相中有Hagg碳化物形成，复式碳化物会演变为WC和FeWO4形式。     

感应熔覆Ni基合金／碳化物熔覆层的组织与冲蚀磨损性能

在Ni60A粉末中添加不同含量的Cr3C2-NiCr材料,采用感应熔覆方法在45号钢基体上制备熔覆层,研究Cr3C2-NiCr含量对熔覆层的成型性、显微组织、硬度与冲蚀磨损性能的影响规律.结果表明:当Cr3C2-NiCr含量小于70%时成型性较好;熔覆层与基体可形成良好结合,熔覆层组织呈现树枝晶的形貌特征;当Cr3C2-NiCr含量为40%时,熔覆层的硬度值最大(达580 HV)、冲蚀速率最低(为2.62 mg/mm2.min).     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

Information for Contributors

正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis     

Preface

<正>We are pleased to present this Special Issue of Transactions of Nonferrous Metals Society of China containing selected papers from the First Asian Conference on Aluminum Alloys(ACAA-2013),held in Beijing,China,13–17 October 2013.This conference has been initiated,with approval of     

Information for Contributors

The Transactions of Nonferrous Metals Society of China, founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, 1NSPEC, CA, METADEX, AJ and JICST.     

INTRODUCTION TO PATENTS

The invention provides a method of making a mold which can reduce SOx generation rate while preventing decrease in hardening rate in the case of using sulfuric acid for a hardener composition. The method has a mixture step in which fire-resistant particles, a hardener composition and a binder composition are mixed to obtain a composition for a mold. The hardener composition contains sulfuric acid. In the mixture step, sodium carbonate is added. A molar ratio of the sulfuric acid to the sodium carbonate is 0.5 or more and 4.0 or less.     

China Foundry Week 2014

China Foundry Week, hosted by the Foundry Institution of Chinese Mechanical Engineering Society （FICMES） each year, is a large academic event in China. It is one of the ten high-impact activities sponsored by the Chinese Mechanical Engineering Society.     

17th Conference of Hydrodynamic and Electromechanical Control Engineering Call for papers

正1.Contents In order to promote the academic exchanges and technical communication of the research in the field of fluid power transmission and control,fluid control engineering specialized committee of the Chinese Society of Theoretical and Applied Mechanics will hold the 17th Conference of Hydrodynamic and Electromechanical Control Engineering on July 27-29,2014 in Tibet,Lhasa city.     

Formulas of Tension of Continuous Rolling Process

The development of computer controlled continuous rolling process calls for a mathematical expression that can express the inequality condition of "constant flow". Tension is the link of the continuous rolling process. From the condition of dynamic equilibrium, a differential equation of tension is given out. On the basis of the physical rules established from the industrial practice and experimental studies, the law of volume constancy, the linear relation of forward slip and tension, the state equation of continuous rolling, the formula of dynamic tension, and the formula of static tension have been obtained. These formulae reflect the functional relations between tensions, thickness, roll velocity, and time in the continuous rolling process. It is implied that the continuous rolling process is a gradually steady, controllable, and measurable dynamic system. An assumption of predicting the thickness of a steel plate using these tension formulae is also put forward.