Zur Kenntnis eines gemischtvalenten Lanthanoxovanadats: La11VV3O26

Single crystals of La₁₁V⁴⁺V₃⁵⁺O₂₆ were prepared by high temperature reactions in an N₂/H₂ mixture above the melting point of the initial oxides V₂O₅–La₂O₃. X-ray investigations of the dark blue crystals reveal triclinic symmetry, space group with = 7.088 Å, β = 10.213 Å, χ = 10.250 Å, = 89.59°, β = 71.10°, τ = 70.00°, Z = 1. The lanthanum-rich compound exhibits a new structure type characterized by a complicated La₁₁O₂₆^19- network with incorporated V⁴⁺/V⁵⁺ ions. The VO₄ tetrahedra are isolated from each other and occupied with V⁴⁺ and V⁵⁺ in a statistical manner.

Résumé

Einkristalle von La₁₁V⁴⁺V₃⁵⁺O₂₆ wurden durch Hochtemperaturreaktionen unter N₂/H₂-Mischungen oberhalb des Schmelzpunktes von V₂O₅-La₂O₃ dargestellt. Die röntgenographische Untersuchung der tiefblauen Kristalle führte zu trikliner Symmetrie, Raumgruppe mit = 7,088 Å, β = 10,213 Å, χ = 10,250 Å = 89,59°, β = 71,10°, τ=70,00°, Z = 1. Die lanthanreiche Verbindung bildet einen neuen Strukturtyp und zeichnet sich durch ein kompliziertes La₁₁O₂₆^19- Gerüst aus, in welches V⁴⁺/V⁵⁺-Ionen eingelagert sind. Die gebildeten VO₄-Tetraeder treten zueinander isoliert auf und sind statistisch mit V⁴⁺ und V⁵⁺ besetzt.     

超快变换高频变极性方波TIG电弧行为

基于一种新型电路变换拓扑实现频率达超音频段且具有超快速电流上升沿和下降沿变化速率的高频变极性方波电流输出,将其用于铝合金TIG焊接过程,研究分析高频变极性TIG电弧行为.结果表明,变极性电流频率和变化速率具有对电弧形态、稳定性及电弧力的控制能力,提高电流极性变换频率,电弧清除氧化膜的能力增强,电弧表现出明显的收缩效应,电弧电压和电弧等效电阻增大,但电弧偏吹作用加剧.在一定频率范围内,增加变极性电流频率,减小负极性电流幅值及其持续时间,可增大焊缝熔透率,有利于提高焊接效率和质量.     

TIG welding-brazing joint of aluminum to stainless steel with hot wire

TIG welding-brazing process with high frequency induction hot wire technology was presented to create joints between 5A06 aluminum alloy and SUS32! stainless steel using ER1100 filler wire with different temperature. The joints were evaluated by mechanical test and microstructural analyses. The welding procedure using hot fiUer wire （400 ℃ ） significantly increases strength stability by 71% and average value of tensile strength by 30. 8 % of the joints, compared with cold wire. The research of microstructures in interfaces and welded seams reveals that using 400 ℃ hot filler wire can decrease the thickness of intermetallic compounds （ IMCs ） from 6 to 3.5 txm approximately, which is the main reason of mechanical property improvement.     

Research on welding simulation methods and software development

To develop highly efficient and useful software, we need to understand the essential feature of the welding phenomenon. From the mechanical point view, welding is a transient nonlinear problem in which small but strongly nonlinear region is moving with the welding torch. Noting this characteristic, ISM （Iterative Substructure Method） was developed for the thermal-elastic-plastic analysis of large scale structures. It is also known that the welding distortion and the residual stress are produced by inherent strain. The inherent strain is the sum of irreversible strains such as plastic strain due to welding thermal cycles or phase transformation and creep strain. In addition to the inherent strain, the mismatch produced by cutting error and fitting is also an important cause of the welding distortions and residual stresses. Based on this understanding, an elastic FEM introducing the inherent strain and mismatch is developed. The potential capabilities of these methods are demonstrated through some examples.     

Effects of rare earth elements on sulphur and phosphorus impurities in deposited metal

In order to reduce sulphur （ S ） and phosphorus （ P ） impurities in deposited metal, a small amount of rare earth （RE） lanthanum （ La） and yttrium （Y） were added into the coating ofE4303 electrode, a low carbon steel electrode. The microstructures of deposited metal were analyzed with metalloscope, and then the content of S and P was examined by energy dispenive X-ray spectrometer （ EDXS ）, and by wavelength dispersive X-ray fluorescence （XRF） spectrometer for further examination. The results show that the proper addition of La and Y can be beneficial to the desulfurization and dephosphorization of the deposited metal. Certainly, difference in the addition amount of La and Y could lead to various desulfurization and dephosphorization efficiency, in which the former is more obvious than the latter. With the proper amount of La attd Y, there is finer microstructure in deposited metal, and mechanical properties are improved as well. The S content in deposited metal with added La and Y decreases by 44. 44 wt. % , while the P content 6. 67 wt. %, compared with that in deposited metal without La and II.     

Gas dynamic control of properties of welded joints from high strength alloyed steels

Gas dynamic control in welding with consumable electrode in conditions of two-jet gas shielding and its impact on the processes in the welding area and properties of the welded joints from high strength alloyed steel 30HGSA is considered in the paper. The results of a comparative experimental study of controlling the properties of welded joints by changing the gas dynamics of the active shielding gas are given. The impact force of a shielding gas jet on the drop of the electrode metal is 12 times higher in conditions of two-jet gas shielding than in those of single jet shielding. It is found that gas dynamics of the active shielding gas jet determines the formation of the welded joints, their chemical properties and the properties of the welded joints from high strength alloyed steels. The consumable electrode welding method with two-jet gas shielding provides controlled dynamics in the welding area and allows controlling the transfer of the electrode metal, chemical composition of the weld, stabilizing the welding process, it ensures higher mechanical properties of the welded joints.     

Microstructure characteristics of dissimilar metal weld between aluminum alloy and brass

Dissimilar metal joining between 5A02 aluminum alloy and H62 brass sheets was conducted by gas tungsten arc welding with Zn-15% Al and Al-12% Si flux-cored filler wires. The microstructure in the weld and distribution of major alloying elements in the intelfacial layer were examined, and the tensile strength of the resultant joints was measured. Pores appeared in the weld made with Zn-15% Al flax-cored filler wire, the interracial layer mainly consisted of AlCu phase, and the specimens fractured through the weld with tensile strength of 129 MPa. When Al-12% Si flux-cored filler wire was used, Cu diffused into the weld and Al2 Cu phase formed, and the specimens fractured along the interfacial layer with tensile strength of 122 MPa.     

Neural network prediction of the shunt current in resistance spot welding

An error back propagation （BP） neural network prediction model was established for the shunt current compensation in series resistance spot welding. The input variables for the neural network consist of the resistivity of the material, the thickness of workpiece and the spot spacing, and the shunt rate is outputted. A simplified calculation for the shunt rate was presented based on the feature of the constant-current resistance spot welding and the variation of the resistance in resistance spot welding process, and then the data generated by simplified calculation were used to train and adjust the neural network model. The neural network model proposed was used to predict the shunt rate in the spot welding of 20# mlid steel （in Chinese classification） （in 2. 0 mm thickness） and 10# mild steel （in 1.5 mm and 1.0 mm thickness）. The maximum relative prediction errors are, respectively, 2. 83%, 1.77% and 3.67%. Shunt current compensation experiments were peoCormed based on the neural network prediction model proposed to check the diameter difference of nuggets. Experimental results show that maximum nugget diameter deviation is less than 4% for both 10# and 20# mlid steels with spot spacing of 30 mm and 50 mm.     

Numerical analysis of temperature profile and weld dimensions in laser ＋ GMAW hybrid welding of aluminum alloy T-joint

The temperature fields in the transient state and weld dimensions in laser ＋ gas metal arc welding （GMAW） hybrid welding of aluminum alloy T-joint for different welding conditions were calculated using the developed heat source model, and the effect of welding speed on them was analyzed. The results show that the temperature field for the first weld pass only shows the feature of GMAW and the one for the second weld pass has the characteristics of both laser welding and GMAW. Welding speed can affect greatly weld dimensions and temperature distribution. When welding speed reaches 3.5 m/min, the fusion zones of two weld passes are separated and the maximum peak temperature of thermal cycle on the workpiece surface decreases largely.     

Comparative study on the flow fields of three atomization nozzles

In this paper, the flow fields of three types of nozzles （ Hartmann, Laval and Laminar nozzles ） under the same conditions are simulated, and the corresponding to pressure, temperature, velocity and turbulence intensity are obtained. The results suggest that two crushing presents in the atomization process using Hartmann nozzle, but only one crushing presents in the atomization process using the other nozzles, through the comparative research on the flow field features of three types of nozzle. Furthermore, the shockwave plays a more important role in crushing of liquid metal than velocity.     

Investigation on diffusion bonding of TiAl intermetallic to Ti3AlC2 ceramic with Ni interlayer

In this study, vacuum atmosphere. The diffusion bonding of TiAI alloy and Ti3AlC2 ceramic was carried out using Ni foil as interlayer in a interfacial microstructures and the mechanical properties of the diffusion bonded joints were evaluated. Result showed that the interfacial microstructure of the joint from TiAl to Ti3AlC2 side could be divided into Al3NiTi2 , AlNi2 Ti , Ni3 （ Al, Ti） , Ni , Ni3 （ Al , Ti） , Ni （ Al , Ti ） , Ni3Al ＋ TiC~ ＋ Ti3AlC2 , respectively. The shear strength test showed that an average value of 45.9 MPa was achieved. The crack propagated along the interface between TiAl intermetallic and Ni interlayer during the shear test. The mechanisms f or formation of those compound layers during bonding process and the determinant of the fracture location were also discussed.     

Study of microstructures and of domestic X70 properties for girth welding pipeline steels

With the development of domestic pipeline steels, it is necessary to develop suitable welding technology which can improve the properties of the welded pipeline. In this paper, the microstructures and mechanical properties of domestic XTO pipeline steels and welded joints are discussed. The welding consumables of BOHLER E6010 and HOBART 81N1 are matched for girth welding. The following characteristics in heat-affected zone（ HAZ） are indicated that microstructures of intercritical HAZ（ ICHAZ） is finer and more uniform, the grain sizes of fine-grain HAZ （ FGHAZ） and subcritical HAZ （ SCHAZ） are smaller than that of coarse-grain HAZ（ CGHAZ）. The hardness, tensile strength and toughness of welded joints come up to the standard. The micrographs of impact specimens in welded joints are cleavage, quasi-cleavage and dimple which shows there is typical ductile rupture.     

Formation mechanism of the porous zone at the bonded Si3 N4/Ni interface

Diffusion bonding of Si3N4 ceramic to itself was performed using Ni interlayer. A flat Si3N4/Ni interface was found at a lower temperature （ 1 273 K）. Whereas at a higher temperature （ 1 473 K）, a porous zone located at the Si3N4/Ni interface and some petal-like Ni3 Si compounds precipitated in the Ni interlayer were observed. The formation mechanism of the porous zone was investigated based on a fracture analysis. An additional stress （O＇add ） generated at the Si3NJNi interface played an important role in the formation of the porous zone, which was resulted from the aggregation of nitrogen during the bonding process. A calculation equation of the O＇aaj was derived to analyze its effects. The results indicated that %~ was directly in dependent with diffusion bonding temperature and dwell time.     

Microstructure and mechanical properties of laser welded joints of pure copper and 304 stainless steels

A continuous wave diode laser with an output power of 2.8 kW was used to join pure copper and 304 stainless steel with a thickness of 1 mm. The focused laser beam with a diameter of O. 8 mm was irradiated on the copper side of the butt joints. In process of laser welding, effects of processing primary parameters on tensile strength of the joints were investigated. The interfacial characterizations of the joints were investigated by metallographic microscope, scanning electron microscope （SEM） and energy dispersive X-ray spectroscope （EDS）. The results showed that the element diffusion and solution occur and metallurgical bonding was achieved between pure copper and 304 stainless steel. The maximum tensile strength of the joints was 209 MPa when the laser power of welding was 2. 4 kW and welding speed was 12 mm/s.     

Ultrasonic C-scan inspection of brazed joint in thin panel honeycomb structure

The non-destructive testing of brazed joint in honeycomb structure with thin panel （ thickness ： 0. 2 mm） was studied by ultrasonic C-scan method. Samples with different types of artificial defect were designed; the characteristic signal and the main parameters of the test were determined by the pre-experiment, and then parameters were optimized by orthogonal design, finally the optimum process was verified by a single panel sample. The multiple reflection echoes were chosen as the characteristic signal. The optimal C-scan results were achieved when the 20 MHz focus probe was used, and the pass band range for received signal were selected as 8 - 17. 5 MHz. The defects such as incomplete penetration and core damage can be detected with ultrasonic C-scan, and the detection accuracy can reach to 1 ram.     

Effect of Zr-Ti combined deoxidation on impact toughness of coarse-grained heat-affected zone with high heat input welding

In this study, the effects of Zr-Ti combined deoxidation and AI deoxidation on the impact toughness of coarse- grained heat-affected zone in high-strength low-alloy steels were investigated. More fine oxides were formed in the Zr-Ti-killed steel than in Al-killed steel. It was also found that more acicular ferrite grains were formed in the coarse-grained heat-affected zone in the Zr-Ti-killed steel than in Al-killed steel. The impact toughness of coarse-grained heat-affected zone of Zr-Ti-kiUed steel was higher than that of Al-killed steel. The good impact toughness was attributable to the pinning effect of fine oxides and the formation of acicular ferrite grains on fine oxides.     

Influence of post-weld heat treatment on microstructure and properties in heat-affected zone of KMN steel joint

The influence of temperature during post-weld heat treatment on the microstructure and properties of KMN steel joints was investigated. The results reveal that after heat treatment, the martensite transformed to tempered sorbite, causing the softening of the resultant joints. XRD test shows that the residual austenite content decreased obviously when the joint was heattreated at 550 ℃ and 580 ℃, which degraded the impact toughness of heat-affected zone （ HAZ）. When the heat treatment temperature increased further, the dispersion strengthening from the precipitation of alloying elements improved the impact toughness of HAZ. The aggregation and coarsening of carbide also contributed to the improvement of impact toughness of HAZ.     

Microstructure and properties of SAF2507 superduplex stainless steel welded joints

SAF2507 plates （ 12 mm thickness ） were welded using shield metal arc welding （SMAW） process with E2594 electrode. The microstructure, o-phase, and impact fraetograph of the welded joints were analyzed using optical microscope and scanning electron mieroseope. The results show that the fusion zone consists of ferrite, chromium nitride, and secondary aastenite precipitation when welding is performed at low heat input （0. 5 kJ/mm）. However, the increase in heat input causes precipitation of brittle o＂ phase at the y/c~ interface in weld metal and heat-affected zone, as well as a brittle fracture along the grain boundary. Heat input in the range of O. 5 kJ/mm to 1.5 kJ/mm is suitable for joining SAF2507 plates.     

Effect of groove angle and preheating temperature on temperature profile and fluid velocity in weld pool

The three dimensiotud transient weld pool dynamics are numerically analyzed ,for Forcearc welding, which is a new gas metal arc welding technology to get deep fusion penetration with smaller angle sf V groove to enhance welding efficiency significantly. The influence of groove angle and preheatin,g temperature on heat and .fluid .flow is studied and compared to get an optimal welding parameter. Good agreement is shown between the predicted and experimental results, such as weld bead cross-section and thermal cycles. It can he seen that an apprpriate groove angle could be used to replace high preheating temperature to get inproced penetration and thermal cycles.     

Prediction of welding residual stress in multipass narrow gap welded pipes with large thickness

The objective of this study is to investigate the influence of post weld heat treatment （PWHT） on the distribution of residual stress in welded pipes with large thickness. The detailed pass-by-pass finite element simulation was developed to study the residual stress in narrow gap multipass welding of pipes with a wall thickness of 150 mm and 89 weld beads. The effect of PWHT on welding residual stress was also investigated by means of numerical analysis. The simulated results show that the hoop stress is tensile stress in the weld region and compressive stress in the parent metal areas adjacent to weld seam. After heat treatment, the residual stresses decrease substantially, and the simulated residual stress is validated by the experimental one. The distribution of the through-wall axial residual stress along the weld center line is a self-equilibrating type.