Synthesis and characterization of poly acrylic acid/graphite oxide nanocomposite

1　INTRODUCTIONOrganic intercalatedlayeredsolidshavebeenstudiedbyscientistsindifferentfieldsformanyyearsbecauseoftheirnew physicalandchemicalpropertiessuchaselectricalproperties[1] ,mechanicalproper ties ,thermalbehavior[2 ] ,surfaceandinterfacialproperties[3] .Graphiteoxide (GO)hasbeenstudiedformany years ,itsstructuralmodel[4 6 ] ,formationprocessandkinetics[7,8] havebeenstudiedindetail.IthasbeenreportedthatGOpossessesC OHande poxidefunctionalgroups[9] whichmakegraphiteox ideeasilyabs…     

Development of cube texture in multistage annealing of high purity aluminum foils

1　INTRODUCTIONThecubetextureisimportanttohighpurityalu minumfoilsforhighvoltagecapacitorsbecauseitcanenlargeeffectivesurfaceofaluminumfoilsandin creasecapacitancethroughchanneletching .Inordertoincreasethevolumefractionofthecubecompo nent ,a greatdealofresearchesontheformationmechanismofcubetexturehavebeendone ,andmanymethodswere proposed ,suchasimpuritycontrol ling[1,2 ] ,directionalsolidification[3] ,preheating[4 ] ,inhomogeneousrolling[5] ,vacuumannealing[6 ] andsoon .Inthispaperamulti…     

Improving fatigue property of Al-Li alloy by thermo-mechanical treatment

1　INTRODUCTIONAl Lialloyhasbeenusedwidelyasakindofnewstructuralspaceflightmaterialdependingonitshighstrengthandlowdensity[1,2 ] .ManyresearchworkshavebeendoneonAl Lialloy[36 ] ,butfewofthemareaboutfatiguefaliure .Becausemorethan 80 %ofstructuralmaterials failuresarecausedbythefatiguefailuresdirectlyorindirectly[7,8] ,itisnecessarytostudythefatiguepropertyofAl Lialloy[911] .ThereisobviousageingstrengtheningeffectwhenAl Lialloyisagedbelowthesolubilitycurveoftransientphaseδ′ .However,t…     

Effect of heat-treatment on fatigue property of Al-Li alloy

1　INTRODUCTIONMorethan 80 %ofstructuralmaterials failuresarecausedbyfatiguefailuredirectlyorindirectly [1,2 ] .Al Lialloyhasbeenusedasakindofnewstructuralspaceflightmaterialbecauseofitshighstrengthandlowdensity[3,4 ] .AlthoughalotofresearchesaboutAl Lialloy[58] havebeendoneinthepastfew years ,thede tailedstudyonthefatigueproperty[910 ] hasnotbeendonesomuch .Especially ,therewaslittleresearchonthefatiguecrackinitiatingandpropagatingbehavior.Be causethestrengthofAl Lialloycouldbeaffected…     

ORTHOGONAL POLYNOMIAL EXPANSIONS OF THERMODYNAMIC PROPERTIES OF BINARY AND TERNARY SYSTEMS

1.IntroductionThereareseveralkindsofpolynomialexpansionsofthermodynamicproperties.FOrbinarysystemsthereareMargUlespolynomial[1],Redlich-Kisterpolynomial[2]andLegen-drepolynomialexpansions[3--5]etc..ForternaryandquaternarysystemsonlyMargulespolynomialexpansions[6'7]areawilable.Legendrepolynomialexpansionisbelievedtohavethead~agesofcoefficientsindependence[3--518]etc..ButwecanseethecoefficientsofLegendreexpansionsarenotcompletelyindependent,especiallywhentheinputdataarefleded.ThatisbecauseL…     

Measurement of surface crystallinity of PAA and PAANa coatings and its effect on hydrophilicity of coatings

1　INTRODUCTIONAsanimportantwater solublemacromoleculecompound,poly (acrylicacid) (PAA)anditssaltshavebeenwidelyused[1] .Utilizingitsfinefilm form ingcapacityandhydrophilicity ,Okoroaforetal[2 ] ,andPanetal[3] developedanewhydrophilicpaintforaluminiumfin[2 ,3] .Hydrophilic paintforheat ex changerofairconditioningdemandslittlesurfacecon tactangle ,sothatcontinuoushomogeneouswaterfilmcanformeasily ,andcandrainoffcondensedwa teronthesurfaceoffintimely[4 6 ] .Hydrophilicityofcoatingsisaffec…     

Dry sliding wear of Ti-6Al-4V alloy in air and vacuum

1　INTRODUCTIONTitaniumanditsalloysareidealmaterialsforaerospaceandspaceindustriesbecauseoftheirhighspecificstrengthandexcellentcorrosionresistance[1] .Thevacuumenvironmentmustbeconsideredinspaceapplicationswherewearresistanceisrequired .Theabsorption ,stainsandoxidesmaybetotallyorpar tiallyremovedfromthesolidsurfaceinvacuum[2 ] .Thus ,arelativelyclearsurfacecanbeformed ,whichmightresultinanadhesionorevencoldweldingduetothestrongattractiveforcesbetweenmoleculesofthecontactingsurfaces[3] .…     

Synthesis and characterization of metastable Ag-B solid solutions

1　INTRODUCTIONMechanicalalloying (MA) [1] hasbecomeawide lyusedtechniquetosynthesizeavarietyofmaterials ,suchasamorphousalloys ,nanocrystallinematerials ,compounds ,solidsolutionsandsoforth .Especially ,theformationofnonequilibriummaterialscomposedofimmiscibleelementsbyMAhasreceivedincreasedattention .Anumberofbinarysystemshavebeenin vestigated ,includingAg Cu[2 4 ] ,Ag Fe[5] ,Fe Cu[6 ] ,Ag Ni[7] andothers .Comparisonwithothersynthesismethods ,suchasrapidlyquenching ,MAhasadvantages…     

Electrochemical hydrogen storage properties of La0.95Mg2.05Ni9 alloy prepared by mechanical alloying

1　INTRODUCTIONTheMg basedhydrogenstoragealloysastheac tivematerialsofmetalhydrideelectrodeshaveattract edattentionbecauseofhighertheoreticalcapacitiesforhydrogenabsorption/desorption ,andthelowerpricecomparedwiththeotherhydrides[17] .Recent ly ,thecharge dischargepropertiesofMg basedalloysatroomtemperaturehavebeengreatlyimprovedbysomeresearchers[813] .Inparticular ,theMg Ni REsystemalloyisoneofthemost promisinghydrides[14 16 ] .Tanakaetal[15] reportedthatthenanocrystallineMg Ni RE(R…     

Electrochemical characteristic of chemical-mechanical polishing of copper with oxide passive film

1　INTRODUCTIONThankstoitslowresistivityandhighelectromi grationresistance ,copperappearstobeaverypromisingsubstituteforaluminumininterconnec tions[1] .However ,copperisverydifficulttopattern ,andonlychemical mechanicalpolishing (CMP)tech nologycanresolvethisproblem[2 ] .CMPwasinitiallyinvestigatedandopenedoutfrom 1980soverseas[3] ,anditisthebestandonlyglobalplanarizationtech nologyatpresent ,butkeepsholdofbusinesssecretsallthetime .Fayolleetal[2 ] researchedCMPprocessofcopperwhereFe(…     

AZ31镁合金热变形流动应力预测模型

采用近等温单轴压缩实验获得了AZ3l镁合金变形温度为523 723 K,应变速率为0.01—10 s^-1条件下的流动应力,分析了变形温度和应变速率对流动应力的影响规律.结果表明,AZ31镁合金变形过程中发生了动态再结晶,523 K时形成细小组织;而723 K时动态再结晶和长大的晶粒沿径向拉长.考虑实验过程塑性变形功和摩擦功引起的温度升高,在高应变速率条件下采用温度补偿修正了流动应力.在此基础上,建立了基于双曲正弦模型的峰值流动应力和统一本构关系,该模型利用材料参数耦合应变来描述流动应力的应变敏感性,进一步获得了合金热变形过程中流动应力与变形温度、应变速率和应变的定量关系.采用该本构关系模型预测流动应力具有较高的精度,预测值与实测值相关系数为0.976,平均相对误差为5.07%,实验条件范围内预测的流动应力与实验值几乎能保持一致.     

AZ61B镁合金热变形动力学的研究

采用等温压缩试验，测定了AZ61B镁合金材料在热变形条件下的流变应力，分析变形条件对流变应力的影响规律，借助于经验公式描述高温变形动力学，计算了合金的热变形激活参数，探明了AZ61B合金试验变形条件下主要的软化机制为动态再结晶。     

Analysis on flow stress of magnesium alloys during high temperature deformation

The flow stress of magnesium alloys during hot compression at different temperatures and strain rates was studied by experiments.Materials used were AZ91D alloys in as-cast,homogeneous treatment states,AZ31 and ZK60 alloys in as-cast state. The results show that the thermal simulation curves of different alloys differ from one another at the same deforming condition.The general curves of AZ31 and AZ91D alloys have the character of dynamic recrystallization.There are increase of true stress,drastic fallin...     

应变影响的AZ31B镁合金流动应力预测模型研究

本文采用热压缩试验获得了铸态AZ31B镁合金高温变形时的流变曲线,分析了变形温度和应变速率对流动应力的影响。结果表明：峰值应变随着应变速率增加和温度减小而增大,减小应变速率、适当提高变形温度对材料的动态回复和再结晶是有利的。利用多元回归分析建立了流动应力预测模型,该模型可以描述流动应力的应变敏感性,经验证发现使用其预测流动应力具有较高精度,相关系数高达0.9926,能较好地描述铸态AZ31B镁合金在热变形过程的流动行为。     

AZ31镁合金挤压板材的中温变形机理及软化机制(英文)

研究AZ31镁合金挤压板材在473～523K的温度范围内。应变速率0.001～1.0s-1压缩时的流变应力行为,计算板材沿挤压方向压缩时的激活能,并结合光学显微镜和透射电子显微镜探讨合金软化机制和变形机理之间的联系。结果表明,在中温下沿挤压方向压缩时,AZ31挤压态镁合金的变形激活能为174.18kJ/mol。这说明,由热激活位错交滑移所控制的动态再结晶是合金中温变形的主要软化机制。位错滑移是中温变形的主要变形机理,而孪生的作用则不大。其主要的动态再结晶机制为持续动态再结晶,并伴随少量的孪生动态再结晶。     

AZ31B镁合金塑性变形动态再结晶的实验研究

通过不同应变速率和不同温度下的轴对称压缩试验,研究了AZ31B镁合金塑性变形与动态再结晶的相互依赖关系。研究证实,温度T在200℃～400℃区间、变形程度ε约0.2左右时,开始出现动态再结晶(DRX)现象。随变形程度的增加,DRX晶粒不断增多,材料呈现明显的软化趋势,流动应力下降。当DRX过程完成以后,继续变形,材料又出现硬化行为。为镁合金塑性变形组织演变的定量研究打下了基础。     

A FLOW STRESS MODEL FOR AZ61 MAGNESIUM ALLOY

The flow stress behaviors of AZ61 alloy has been investigated at temperature range from 523 to 67314 with the strain rates of 0.001-1s^-1.It is found that the average activation energy, strain rate sensitive exponent and stress exponent are different at various deformation conditions changing from 143.6 to 176.3kJ/mol,0.125 to 0.167 and 6 to 8 respectively. A flow stress model for AZ61 alloy is derived by analyzing the stress data based on hot compression test.It is demonstrated that the flow stress model including strain hardening exponent and strain softening exponent is suitable to predicate the flow stress. The prediction of the flow stress of AZ61 alloy has shown to be good agreement with the test data.The maximum differences of the peak stresses calculated by the model and obtained by experiment is less than 8%.     

Simulation of strain-softening behaviors in an AZ31 Mg alloy showing distinct twin-induced reorientation before a peak stress

To investigate strain-softening behavior during plastic deformation of an AZ31 Mg alloy, cylindrical specimens were compressed in a rolling direction at 300 °C. Experimental evidence revealed that an inhomogeneous microstructure evolved due to the softening behavior associated with deformation at elevated temperatures. The large grains that reoriented as a result of deformation twinning were free of dynamic recrystallization (DRX). Fine grains nucleated at grain boundaries of grains were deformed by a slip-dominated mechanism, which accommodated the external strain. A visco-plastic self-consistent (VPSC) polycrystal model was used to simulate softening of the flow stress curve and texture evolution during uniaxial compression. A softening scheme was implemented in the polycrystal model to predict the softening phenomenon and texture evolution after the peak stress. The original VPSC model was modified to simulate texture evolution in an AZ31 Mg alloy that exhibited twin-dominated deformation before the peak stress.     

Dynamic recrystallization behavior of AZ61 magnesium alloy

An AZ61 alloy was subjected to hot compression at temperatures ranging from 523 K to 673 K, with strain rates of 0. 001 - 1 s^-1. Flow softening occurs at all temperatures and strain rates. There are peak and plateau stresses on flow curves. The initiation and evolution of dynamic recrystallization（DRX） were studied by the flow softening mechanism based on the flow curves and microstructural observations. A linear relationship was established between the logarithmic value of the critical strain for DRX initiation（lnεc） and the logarithmic value of the Zener-Hollomon parameter （lnZ）. The volume fraction of DRX grain （φd） is formulated as a function of the process parameters including strain rate, temperature, and strain. The calculated values of φd agree well with the values extracted from the flow curves. The size of DRX grain（d） was also formulated as a function of the Zener- Hollomon parameter. This study suggests that DRX behavior of AZ61 can be predicated from plastic process parameters.     

Hot deformation behavior of a spray-deposited AZ31 magnesium alloy

The flow stress behavior of an as-spray-deposited AZ31 magnesium alloy with fine grains was investigated by means of compression tests with a Gleeble 1500 thermal mechanical simulator at isothermal constant strain rates of 0.01, 0.1, 1.0, and 10 s-1; the testing temperatures ranged from 623 to 723 K. It is demonstrated that a linear equation can be fitted between the Zemer-Hollomon parameter Z and stress in a double-log scale. The effect of deformation parameters on the behavior of recrystallization was analyzed. Dynamic recrystallization (DRX) generally occurs at a higher temperature and at a lower strain rate. The constitutive equation of the spray-deposited AZ31 magnesium alloy is elevated temperatures due to the fine grain, which provides a large amount of nucleation sites and a high-diffnsivity path for the atom.