SIMA法制备LC4半固态合金的流变行为研究

半固态坯的流动性能是获得优质、复杂制件的基础和关键。通过对两种状态合金在相同载荷作用下进行半固态压缩试验，结果表明：挤压态合金的流动性最差，挤压后冷变形态合金Ⅱ（压缩方向垂直于冷变形方向）的流动性最好。这主要有两方面的原因：一是晶粒形状上的差异；二是与半固态坯料的制备历史及其后续加工有关。     

半固态金属成形技术的研究概况

在合金凝固过程中加以搅拌或通过其它处理,可得到非枝晶结构合金,其凝固组织为球状的等轴晶,这种合金在固相含量６０％以下时流动性好,变形抗力很小。半固态金属成形是将具有上述特殊组织的、固液相共存的半固态坯料加工成所需形状、性能制品的技术,包括半固态锻造、半固态挤压、半固态轧制、半固态压铸等类型。它是７０年代出现的新兴技术,优点显著,前景良好,有望成为２１世纪金属制造关键技术之一。     

半固态ZA27合金等温挤压

通过采用电磁搅拌的方法获得等温挤压所需要的半固态ZA27合金试样,从而对试样进行等温挤压,通过分析等温挤压前后ZA27合金显微组织及所需的单位挤压力得出:等温挤压后,挤压件组织都得到了细化,半固态合金挤压件组织比常规铸造合金组织更细小均匀,在本实验条件下,半固态合金的单位挤压力比常规铸造合金减少了1/4~1/5。     

半固态挤压Al-Si-Fe合金磨损行为的研究

采用半固态挤压成形技术制备了Al-Si-Fe耐磨铝合金，分析了合金的微观组织，利用磨损试验研究了合金的耐磨性和磨损失效形式。研究结果表明：半固态挤压成形合金具有细小、均匀的微观组织和良好的耐磨性，磨损失效形式以滑动和磨粒磨损为主。半固态挤压成形的挤压比越高，耐磨性越好；干摩擦条件下半固态合金的磨损质量损失是铸态合金的49．2％，润滑条件下是铸态合金的40．0％。     

半固态冷却方式对二次挤压Mg-3.88Zn-1.56Gd(wt. %)合金组织和力学性能的影响

本文研究了半固态(淬火或者空冷)以及热挤压对Mg-3.88Zn-1.56Gd(wt. %)合金显微组织和力学性能的影响。结果表明半固态后淬火,第二相在合金中呈现纳米级共晶层片组织,而半固态后空冷,第二相在合金中呈三叉岛、块状和微米层片状。经过二次挤压,由于不完全再结晶,半固态+挤压后的合金均呈现典型的双峰组织。与未半固态直接二次挤压合金相比,半固态+挤压的合金均具有较高的强度。合金性能增强主要原因是由于双峰组织的形成,细小晶粒提供了晶界强化,未再结晶的粗晶粒则是通过抑制基面滑移,从而产生增强效果。其次要原因是准晶相的细化及其在基体中的弥散分布。     

喷射沉积Al-27%Si合金的半固态挤压成形

研究喷射沉积Al-27%Si合金的半固态挤压成形工艺及其对合金组织与性能的影响。结果表明:喷射沉积Al-27%Si合金在600℃下二次加热10~12 min后,合金液相体积分数适中,Si相尺寸相对细小,形貌为近球形,适合于半固态成形。经600℃二次加热10~12 min后,进行半固态挤压能消除喷射沉积合金中的孔隙,Si相比挤压前更加均匀细小,挤压棒材具有良好的表面质量和均匀的微观组织。经600℃二次加热12 min后,半固态挤压的合金可达到最高的相对密度(99.5%)、抗拉强度(195 MPa)和伸长率(6.7%)。     

ZL101铝合金半固态微挤压流动性实验研究

从微塑性成形技术入手,结合半固态金属良好的成形性能,对半固态金属ZL101铝合金进行正挤压成形实验研究,探讨了半固态金属微成形流动性性能,分析比较了温度、挤出直径、工作带对金属流动性的影响.实验结果表明:微成形条件下,半固态成形可以大大降低挤压载荷;半固态微成形出现了类似尺度效应的现象;工作带越小,挤出长度越长.     

挤压态Mg–Dy–Zn合金板材的压缩各向异性（英文）

研究挤压态Mg-2Dy-0.5Zn(摩尔分数,%)合金板材的压缩各向异性。合金主要由α-Mg、(Mg,Zn)xDy相和大量沿挤压方向分布的长周期有序堆垛(LPSO)结构相组成。压缩实验测试结果表明,合金呈明显的压缩各向异性。平行于挤压方向(ED)合金试样的压缩强度显著高于板材横向(TD)及与挤压方向成45°角的合金试样的压缩强度。ED方向合金试样的压缩屈服强度(CYS)、最大压缩强度(UCS)和压缩应变分别为274.65 MPa,518.94 MPa和12.93%。合金压缩各向异性主要与LPSO相的分布以及变形晶粒中1 010//ED类型织构的形成有关。     

7A04合金半固态模锻工艺的实验研究

以两种状态的7A04合金为例,简要分析了二次加热工艺参数、模具预热温度等工艺参数对半固态模锻成形的影响,并重点研究了半固态模锻前后的显微组织变化及不同加热温度下的力学性能.结果表明:半固态模锻件的显微组织与合金的初始状态及其二次加热后的半固态组织密切相关;在同样变形条件下,经半固态模锻后,挤压后冷变形态合金的力学性能好于挤压态合金,其最佳变形温度分别为600℃和605℃.     

半固态AlSi7Mg合金在封闭竖直圆柱空间中触变变形和流动的研究

兰固态合金挤压工艺的关键是控制半固态合金坯料的流动和变形。在实际工程应用中,半固态合金坯料的挤压铸造成形主要是通过在二维和三维约束空间中的变形和流动而实现的。本文论述了半固态ＡｌＳｉ７Ｍｇ合金坯料在三维封闭圆柱空间中触变变形和流动的规律。     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Rheology Feature of Simple Metal Melt

The rheology feature of Sb, Bi melt and alloys was studied using coaxial cylinder high-temperature viscometer. The results showed that the curve of torsion-rotational speed for Sb melt presents a linear relation in all measured temperature ranges, whereas for the Bi melt, the curve presents obvious non-Newtonian feature within the low temperature range and at relative high shear stress. The rheology feature of Sb80Bi20 and Sb20Bi80 alloy melts was well correlated with that of Sb and Bi, respectively. It is considered that the rheology behavior of Sb melt plays a crucial role in Sb80Bi20 alloy and that of Bi melt plays a crucial role in Sb20Bi80 alloy.     

Microstructures and Mechanical Properties of a Newly Developed Austenitic Heat Resistant Steel

The effect of heat treatment on the microstructures and mechanical properties of a newly developed austenitic heat resistant steel(named as T8 alloy) for ultra-supercritical applications have been studied. Results show that the main phases in the alloy after solution treatment are γ and primary MX. Subsequent aging treatment causes the precipitation of M_(23)C_6 carbides along the grain boundaries and a small number of nanoscale MX inside the grains. In addition, with increasing the aging temperature and time, the morphology of M_(23)C_6 carbides changes from semi-continuous chain to continuous network.Compared with a commercial HR3C alloy, T8 alloy has comparable tensile strength, but higher stress rupture strength. The dominant cracking mechanism of the alloy during tensile test at room temperature is transgranular, while at high temperature, intergranular cracking becomes the main cracking mode, which may be caused by the precipitation of continuous M_(23)C_6 carbides along the grain boundaries. Typical intergranular cracking is the dominant cracking mode of the alloy at all stress rupture tests.     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

The 15th Global Foundry Sourcing Conference 2014held in Qingdao China

Organized by Suppliers China Co., Ltd and co-organized by the National Technical Committee 54 on Foundry of Standardization Administration of China, the 15th Global Foundry Sourcing Conference 2014 （hereinafter referred to as FSC 2014） was successfully held on Sep. 23rd in Grand Regency Hotel, Qingdao. More than 500 delegates from home and abroad attended this conference, including over 130 purchasers from 20 countries and 380 domestic and foreign suppliers.     

Secondary Recrystallization Behaviors of Grain-Oriented 6.5 wt% Silicon Steel Sheets Produced by Rolling and Nitriding Processes

By rolling and nitriding processes, 0.23- to 0.3-mm-thick grain-oriented 6.5 wt% silicon steel sheets were produced. The core losses of grain-oriented 6.5 wt% silicon steel at frequencies ranging from 400 Hz to 20 k Hz were lower than that of the grain-oriented 3 wt% silicon steel with the same thickness by 16.6–35.8%. The secondary recrystallization behavior was investigated by scanning electron microscopy, energy-dispersive spectroscopy, and electron backscattered diffraction. The results show that the secondary recrystallization in high-silicon steel sheets develops more completely as the nitrogen content increases after nitriding, secondary recrystallized grain sizes become larger, and the sharpness of Goss texture increases. Because more {110}116 grains in the subsurface and the central layer of the sheets have a lot of 20°–45° high-energy boundaries in addition to Goss grains, {110}116 can be the main component through selective growth during secondary recrystallization when the inhibitor quantity is not enough and inhibitor intensity is weaker. The increases in nitrogen content can increase the inhibitor intensity and hinder abnormal growth of a mount of {110}116 grains and therefore enhance the sharpness of Goss texture.     

Laser Cladded TiCN Coatings on the Surface of Titanium

Laser cladded coatings of TiCN were produced on the surface of titanium. To obtain the optimal techniques, several conditions were tested by varying the laser scanning rate. The choice of shielding gas was also studied. The cladded coatings were then evaluated from the surface mechanics point of view based on their microhardness. The microstructure of some interesting samples was investigated by optical micrographs (OM). The results showed that under the condition of fixed pulse frequency and pulse width, the laser scanning rate and the shielding gas are the main factors influencing the components of coatings. TiCN coatings were decompounded and oxidized during the cladding process in the condition of no shielding gas of N2. X-ray diffraction results indicated that the composite coatings composed of TiCN, TiC, Ti2N, and TiO2 were produced using appropriate techniques. The results indicated that the best condition in terms of the surface microhardness is obtained when the scanning rate is 1.5mm / s, the pulse frequency is 15Hz, the pulse width is 3.0ms, and N2 is chosen as the shielding gas. The microhardness of the composite coatings is about 1331kg · mm - 2, which is about 4 times that of the substrate. The optical micrographs indicated that the cladding zone is made up of TiCN, TiO2, and some interdendritic Ti, but the diffusion zone mainly consists of the dendrites phase, and the cladded depth is about 80?滋m, which is more than 2 times that of the laser nitrided sample. There were no microcracks or air bubbles in the cladded sample, which was cladded using the above optimal techniques.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

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正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis