热处理对AZ91D镁合金腐蚀性能的影响

对经过不同热处理工艺处理后的AZ91D镁合金进行腐蚀试验,并测定其腐蚀参数.对腐蚀数据及金相显微组织分析、观察表明:时效处理后的AZ91D镁合金腐蚀率最低为2.128mm/a,为铸态和固溶加时效处理的AZ91D镁合金(3.081mm/a、3.209mm/a)的69.1%和66.3%;比仅进行固溶处理的AZ91D镁合金7.400mm/a的腐蚀率减少了71.2%,耐蚀性能提高2.48倍.合金组织中β相的形态和数量对合金腐蚀率起着重要作用.     

AZ91D镁合金微等离子体氧化陶瓷层的耐腐蚀性研究

采用微等离子体氧化方法在AZ91D镁合金表面制备陶瓷层.利用扫描电镜、X射线分析陶瓷层微观组织结构,通过盐雾试验方法测试处理过的AZ91D镁合金耐腐蚀性能.结果表明,AZ91D镁合金经过微等离子体表面氧化处理后,陶瓷层由表面的疏松层和内部致密层所组成,疏松层里有较多的孔隙;致密层孔隙较少且与基体结合牢固;微等离子体氧化陶瓷膜的相结构主要由MgAl2Si3O12,β-Mg2SiO4,(Mg4Al14)(Al4Si2)O20等含硅的尖晶石型氧化物和δ-MgAl28O4等Mg,Al复合氧化物构成.AZ91D镁合金经微等离子体氧化处理后,基体被氧化膜覆盖,使其抗腐蚀性能显著提高,试样表面有陶瓷膜的AZ91D镁合金在盐雾试验中的腐蚀速率是AZ91D镁合金腐蚀速率的1/8.61.     

碳纳米管/镁基复合材料在NaCl溶液中的抗腐蚀性能研究

研究了不同碳纳米管(CNTs)含量以及不同球磨时间对铸造AZ91D、AZ31合金在3.5%NaCl溶液中抗腐蚀性能和pH值的影响.结果表明,随着CNTs含量的增加,AZ91D合金试样的抗腐蚀性明显提高,碳纳米管含量在3%时,其平均腐蚀速率与未加CNTs的铸态试样相比,提高了10.3倍.随着预制块配料球磨时间的增加.加入该碳纳米管预制块的AZ31镁合金的抗腐蚀性能也明显提高,当预制块配料球磨16 h,AZ31合金铸态试样的平均腐蚀速率比球磨0.5 h的试样提高了2.3倍.随腐蚀时间的延长,溶液的pH值增加,其腐蚀速率先增加后趋近于平缓.     

T6热处理对消失模铸造AZ91D与AZ91D-1.5%Y镁合金组织与性能的影响

以消失模铸造AZ91D和AZ91D-1.5%Y镁合金作为研究对象,利用光学显微镜(OM)、扫描电子显微镜(SEM)、X射线衍射(XRD)、X射线能谱仪(EDS)、及金属拉伸和硬度试验等系统研究了消失模铸造AZ91D和AZ91D-1.5%Y镁合金在T6热处理过程中β-Mg17Al12相的溶解与析出对组织及力学性能的影响。结果表明,T6(420℃固溶20 h,250℃时效)处理工艺中,随时效时间的延长,AZ91D与AZ91D-1.5%Y镁合金的硬度和抗拉强度不断提高,当时效时间为15 h时,硬度和抗拉强度达到最大值,AZ91D-1.5%Y镁合金固溶处理后硬度及抗拉强度均高于AZ91D镁合金。     

二十面体Zn_6Mg_3Y_1对AZ91D镁合金性能的影响

通过普通凝固技术获得5种含有二十面体准晶相Zn6Mg3Y1的Mg-Zn-Y合金,按质量比2∶5与AZ91D熔合制备实验合金。利用金相显微镜(OM)、扫描电镜(SEM)观察合金微观组织形貌;用扫描电镜附带的能谱分析仪(EDS)分析其微区化学成分;采用维氏硬度测试仪测试合金硬度;用热膨胀分析仪测定合金的热膨胀系数;模拟海洋环境下,测试合金的电化学腐蚀性能。结果表明:二十面体准晶相Zn6Mg3Y1的添加提高了AZ91D镁合金的硬度;降低了AZ91D镁合金的热膨胀系数,并表现出良好的高温热稳定性;AZ91D镁合金的抗腐蚀性能得到显著改善,腐蚀电流密度较AZ91D合金有1～2个数量级的提高。     

热处理工艺对AZ91镁合金组织与性能的影响

通过对AZ91镁合金进行不同工艺的固溶处理和时效处理,研究了热处理工艺对AZ91镁合金显微组织、力学性能和耐腐蚀性能的影响。结果表明,固溶和时效处理可以明显提高AZ91镁合金的力学性能和耐腐蚀性能。分级固溶处理可使AZ91镁合金的抗拉强度提高27 MPa,-20℃冲击吸收功增加10 J,腐蚀电位正移196 mV。     

钇添加量和固溶处理对AZ91D镁合金组织的影响

添加适量稀土元素钇的AZ91D镁合金采用真空熔炼、金属型铸造的方法获得,并对之进行了固溶处理;研究了钇的添加量及固溶处理时间对AZ91D合金组织的影响.结果表明,经350℃固溶处理16h、钇含量约为0.6％的AZ91D镁合金具有均匀、细小的组织和最佳的力学性能和.     

稀土元素Gd对AZ91镁合金摩擦磨损及腐蚀性能的影响

研究了Gd含量对AZ91镁合金摩擦磨损及腐蚀性能的影响。结果表明,稀土元素Gd的添加能显著提高AZ91镁合金的摩擦磨损及腐蚀性能。当Gd含量为0.8%时,组织和成分较均匀,合金的抗摩擦磨损及腐蚀性能最好。添加过量的Gd元素将使合金摩擦磨损和腐蚀性能下降。     

纯镁和镁合金强流脉冲电子束表面合金化性能

利用强流脉冲电子束对纯镁及镁合金AZ31和AZ91HP进行表面合金化处理。用光学显微镜和扫描电镜对表面处理层形貌和组织进行了分析,腐蚀性能和摩擦磨损测试表明:纯镁表面合金化铝后,样品抗5%NaCl溶液腐蚀性能得到显著提高,维钝电流降低2个数量级以上;而镁合金AZ31以及AZ91HP表面合金化Cr、TiN后,耐磨性均得到提高。     

AZ91D镁合金微等离子体氧化陶瓷层的耐腐蚀性研究

采用微等离子体氧化方法在AZ91D镁合金表面制备陶瓷层。利用扫描电镜、X射线分析陶瓷层微观组织结构，通过盐雾试验方法测试处理过的AZ91D镁合金耐腐蚀性能。结果表明，AZ91D镁合金经过微等离子体表面氧化处理后，陶瓷层由表面的疏松层和内部致密层所组成，疏松层里有较多的孔隙；致密层孔隙较少且与基体结合牢固；微等离子体氧化陶瓷膜的相结构主要由MgAl2Si3O12，β-Mg2SiO4，（Mg4A114）（Al4Si2）O20等含硅的尖晶石型氧化物和δ-MgAl28O4等Mg，Al复合氧化物构成。AZ91D镁合金经微等离子体氧化处理后，基体被氧化膜覆盖，使其抗腐蚀性能显著提高，试样表面有陶瓷膜的AZ91D镁合金在盐雾试验中的腐蚀速率是AZ91D镁合金腐蚀速率的1／8．61。     

Corrosion resistance of WE43 and AZ91D magnesium alloys with phosphate PEO coatings

The corrosion performance of WE43-T6 and AZ91D magnesium alloys with and without treatment by plasma electrolytic oxidation (PEO) was investigated by electrochemical measurements in 3.5 wt.% NaCl solution. For untreated WE43-T6 alloy, formation of a uniform corrosion layer (Mg(OH)₂) was accompanied by initial pits around magnesium-rare earth intermetallic compounds. The AZ91D alloy disclosed increased corrosion susceptibility, with localized corrosion around the β-phase, though the β-phase network phase acted as a barrier for corrosion progression. PEO treatment in alkaline phosphate electrolyte improved the corrosion resistance of WE43-T6 alloy only at the initial stages of immersion in the test solution. However, PEO-treated AZ91D alloy revealed a relatively high corrosion resistance for much increased immersion times, contrary to the relative corrosion resistances of the untreated alloys. The improved performance of the PEO-treated AZ91D alloy appears to be related to the formation of a more compact coating.     

Electrodeposition and corrosion resistance of Ni–P–TiN composite coating on AZ91D magnesium alloy

In order to improve the corrosion resistance and microhardness of AZ91D magnesium alloy, TiN nanoparticles were added to fabricate Ni–P–TiN composite coating by electrodeposition. The surface, cross-section morphology and composition were examined using SEM, EDS and XRD, and the corrosion resistance was checked by electrochemical technology. The results indicate that TiN nanoparticles were doped successfully in the Ni–P matrix after a series of complex pretreatments including activation, zinc immersion and pre-electroplating, which enhances the stability of magnesium alloy in electrolyte and the adhesion between magnesium alloy and composite coating. The microhardness of the Ni–P coating increases dramatically by adding TiN nanoparticles and subsequent heat treatment. The corrosion experimental results indicate that the corrosion resistance of Ni–P–TiN composite coating is much higher than that of uncoated AZ91D magnesium alloy and similar with Ni–P coating in short immersion time. However, TiN nanoparticles play a significant role in long-term corrosion resistance of composite coatings.     

Electrodeposition of zinc on AZ91D magnesium alloy pre‐treated by stannate conversion coatings

A stannate chemical conversion process followed by an activation procedure was employed as the pre‐treatment process for AZ91D magnesium alloy substrate. Zn was electroplated onto the pre‐treated AZ91D magnesium alloy surface from pyrophosphate bath to improve the corrosion resistance and the solderability. The surface morphologies of conversion coating and zinc coating were examined with scanning electron microscope (SEM). The phase composition of conversion coating was investigated by X‐ray diffraction (XRD). The electrochemical corrosion behavior of the coatings in the corrosive solution was investigated by potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS). The experimental results showed that the activated stannate chemical conversion coating provided a suitable interface between zinc coating and the AZ91D magnesium alloy substrate. The corrosion resistance of the AZ91D substrate was improved by the zinc coating.     

表面纳米化对AZ91D镁合金渗铝行为的影响

镁合金表面渗铝是提高耐蚀性的一种有效方法。本研究将表面纳米化作为渗铝的预处理过程。采用高能喷丸对AZ91D镁合金进行表面纳米化处理,然后进行真空铝扩散得到渗铝层。用透射电镜(TEM)和扫描电镜(SEM)观察了渗铝层的形貌。结果表明,在对AZ91D镁合金表面高能喷丸后获得了100 nm的晶粒尺寸。在高能喷丸之后,渗铝层的深度比未高能喷丸的渗铝层厚。在440℃下扩散12 h后,渗铝层的深度增加到70μm。采用电化学方法对AZ91D镁合金的耐腐蚀性能进行了表征。结果表明,渗铝层明显降低了AZ91D镁合金的腐蚀速率。因此,高能喷丸强化有利于镁合金表面渗铝,提高镁合金的耐蚀性。     

Wear and corrosion properties of laser cladded Cu47Ti34Zr11Ni8/SiC amorphous composite coatings on AZ91D magnesium alloy

To improve the wear and corrosion properties of AZ91D magnesium alloys, Cu-based amorphous composite coatings were fabricated on AZ91D magnesium alloy by laser cladding using mixed powders of Cu47Ti34Zr11Ni8 and SiC. The wear and corrosion behaviours of the coatings were investigated. The wear resistance of the coatings was evaluated under dry sliding wear condition at room temperature. The corrosion resistance of the coatings was tested in 3.5% （mass fraction） NaCl solution. The coatings exhibit excellent wear resistance due to the recombined action of amorphous phase and different intermetallic compounds. The main wear mechanisms of the coatings and the AZ91D sample are different. The former is abrasive wear and the latter is adhesive wear. The coatings compared with AZ91D magnesium alloy also exhibit good corrosion resistance because of the presence of the amorphous phase in the coatings.     

汽车发动机用AZ91D合金的表面喷涂与性能

采用热喷涂工艺在压铸态AZ91D合金表面制备了Al涂层,研究了热处理温度和保温时间对AZ91/Al涂层界面组织形貌的影响,并对比分析了扩散层的耐腐蚀性能和耐磨性能。结果表明,热处理前Al涂层与基材为机械结合,热处理后Al涂层与AZ91合金基材的界面处可形成冶金结合扩散层,且随着保温时间延长,扩散层厚度不断增加;热处理温度在375 ℃以下时扩散层主要由β-Mg₁₇Al₁₂相构成,375 ℃×8 h热处理后为α-Mg+β-Mg₁₇Al₁₂相,425 ℃×1 h热处理后为γ-Mg₂Al₃和β-Mg₁₇Al₁₂相。AZ91合金基材和扩散层腐蚀电位从高至低顺序为γ>β>α+β>AZ91合金基材,扩散层的腐蚀电流密度均低于AZ91合金基材,阻抗谱图中容抗弧半径从大至小顺序为γ>β>α+β>AZ91合金基材,扩散层的耐腐蚀性能均优于AZ91合金基材;γ、β和α+β扩散层的摩擦稳定性系数都高于AZ91合金基材,而磨损速率和磨痕宽度都要小于AZ91合金基材,其中β扩散层的磨损速率和磨痕宽度最小,具有最佳的抵抗磨损的能力。     

Influence of chemical composition on corrosion resistanceof AZ91D magnesium alloy ingots

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EFFECTS OF Ce ON CORROSION RESISTANCE OF AZ91D MAGNESIUM ALLOY

1. IntroductionM agnesium alloysare w idely used in autom otive, com m unicated, electronic and aerialindustriesand predicted to be one ofthe m ostim portantlow -density and high-strength m aterialsin the 21th centu-ry ow ing to theirlow density,high spec…     

Corrosion resistance of Mg–8·8Li alloy compared with AZ91

Abstract

The superlight Mg–Li alloys exhibit good formability but poor corrosion resistance due to the alloying of lithium. In this paper, the corrosion behaviour of Mg–8·8Li alloy was investigated by electrochemical measurements, corrosion morphology observations and weight loss determination. The results indicate that Mg–8·8Li alloy displays worse corrosion resistance than AZ91D alloy in the early stages of corrosion. However, the corrosion resistance of AZ91D alloy declines and becomes worse than Mg–8·8Li alloy with increasing exposure time. In addition, it is found that a 250°C annealing treatment has a detrimental effect on the corrosion resistance of Mg–8·8Li alloy.