触变成形AZ91D镁合金在NaCl水溶液中腐蚀特征

通过SEM观察及采用EPMA测定和失重法，对3．5％NaCl水溶液中金属型铸造和触变成型镁合金AZ91D腐蚀行为及腐蚀后微观组织特征进行分析，表明触变成形镁合金的腐蚀速率小于金属型铸造合金的腐蚀速率，原因是微观组织的差异导致其耐蚀性不同；镁合金腐蚀电偶对是以α相和共晶α相作为阳极，β相作为阴极。阳极是被腐蚀相，腐蚀是分阶段分层次进行的，α相是腐蚀初期的被腐蚀相，共晶α相是后期被腐蚀的主要相，β相和共晶α相的相对位置和结构决定着后期腐蚀速率；触变成型中β相的偏析提高了合金的耐蚀性。     

pH值对触变成形和金属型铸造AZ91D镁合金试样应力腐蚀行为的影响

采用静载荷实验和扫描电镜,研究了pH值对触变成形和金属型AZ91D镁合金应力腐蚀行为的影响。通过对试验现象、试样断裂时间及断口形貌的对比分析,结果表明:触变成形AZ91D镁合金的抗应力腐蚀敏感性明显高于金属型AZ91D镁合金的。主要是由于触变成形工艺的优良性,使得镁合金的组织在二次加热等温处理的过程中具有了球状的组织结构,而并非像金属型那样的树枝晶状的组织。同时这种成形工艺也降低了铸件的缩松、气孔和氧化夹杂等缺陷。     

AZ91D镁合金电偶腐蚀的研究

在自来水和3.5%NaCl溶液中测试了铸造AZ91D镁合金与铝合金、锌合金、Q235碳钢和Cu偶合后的电偶腐蚀行为,研究了腐蚀环境、偶接材料和阴阳极面积比(CAAR)对铸造AZ91D镁合金电偶腐蚀行为的影响。在电偶腐蚀过程中测量溶液的pH值以及电偶腐蚀电流;用失重法计算了铸造AZ91D镁合金的电偶腐蚀速率,利用SEM观察了AZ91D镁合金的腐蚀形貌,并对腐蚀产物进行XRD分析。结果表明,AZ91D镁合金在电偶腐蚀过程中会使溶液的pH值升高,并伴有以Mg(OH)₂为主的腐蚀产物的生成;溶液中Cl^-的存在会加速AZ91D镁合金的电偶腐蚀速率;低氢过电位金属Q235碳钢和Cu对AZ91D镁合金的电偶腐蚀加速效果明显高于中氢过电位金属铝合金和锌合金,偶接材料的极化性能对AZ91D镁合金的电偶腐蚀速率有较大影响。同时,大的阴阳极面积比会加速AZ91D镁合金的电偶腐蚀速率,且AZ91D镁合金的电偶腐蚀电流随阴阳极面积比的增大而呈线性增长趋势。     

热处理对半固态触变成形镁合金组织与力学性能的影响

研究了固溶处理对金属型铸造成形及半固态触变成形镁合金AZ91D组织与性能的影响。半固态触变成形使镁合金组织中的α-Mg固溶体由树枝状转变为球状，其抗拉强度和伸长率得到大幅度的提高；同时，由于固溶强化作用使镁合金的抗拉强度、伸长率与普通金属型铸造成形相比提高幅度达51．6％和248．11％。     

热处理对半固态触变成形镁合金组织与力学性能的影响

研究了固溶处理对金属型铸造成形及半固态触变成形镁合金AZ91D组织与性能的影响。半固态触变成形使镁合金组织中的α-Mg固溶体由树枝状转变为球状,其抗拉强度和伸长率得到大幅度的提高;同时,由于固溶强化作用使镁合金的抗拉强度、伸长率与普通金属型铸造成形相比提高幅度达51.6%和248.11%。     

AZ91D镁合金的触变成形及其磨损性能的研究

研究了加热时间和模具预热温度对AZ91D镁合金触变成形性、组织和磨损性能的影响。结果表明，适合AZ91D镁合金触变成形的最佳加热时间为90min(在585℃)，模具预热温度为350℃；在此工艺条件下，初生相颗粒较圆整、粒度较小，组织最致密，相应地，其耐磨性也最好；与金属型铸造相比，触变成形显著地减少了缩松，因而，也明显地提高了耐磨性。     

消失模铸造AZ91镁合金组织及耐蚀性研究

通过采用金相分析、能谱分析、电子万能材料试验机、腐蚀失重法、极化测试及交流阻抗分析等手段,研究了消失模铸造AZ91镁合金的组织、力学性能及腐蚀行为,并与普通砂型铸造及金属型铸造方法进行了比较.研究结果表明,消失模铸造镁合金组织除了粗大的α相与β相外,还出现了球状的Al-Mn-Fe三元相,造成消失铸造镁合金的力学性能及耐蚀性能低于砂型铸造及金属型铸造.本试验条件下,消失模铸造AZ91合金的抗拉强度及伸长率分别为135.6MPa与1.4%.失重法测得的消失模铸造AZ91镁合金的腐蚀速率为0.64 mg/(cm2·d),为金属型铸造的2.2倍.极化曲线及交流阻抗等电化学研究表明,铸造工艺对镁合金的腐蚀行为有明显影响,消失模铸造镁合金的自腐蚀电位较低,但自腐蚀电流密度较大,分别为-1.577V与1.39×10-5Amp/cm2.     

触变成型镁合金AZ91D在兰州城市大气中的腐蚀行为研究

研究了兰州大气中触变成型镁合金AZ91D的腐蚀行为.结果表明:发生的腐蚀是与降水有关的电偶腐蚀，湿度是影响腐蚀过程的主要因素之一;腐蚀发生在原固相区的α相和液相区的共晶α相，β相作为腐蚀的阴极区;α相表面形成的表面膜和龟裂是α相腐蚀加剧的主要控制因素.腐蚀产物与大气中的腐蚀性气体CO2，SO2有关.     

触变成形AZ91D合金的组织及磨损性能的研究

研究了触变成形AZ91D镁合金的组织和磨损性能.结果表明,触变成形AZ91D合金长方体零件的组织并不均匀:在纵向远离内浇道的区域和在横向远离中心的部位初生相颗粒分数略有减小;在往复式磨损实验中,随着往复次数的增加,磨损率先急剧增加,最后趋于常数,随着载荷和往复频率的增加,磨损率则一直呈增大趋势;与金属型铸造相比,触变成形能显著提高耐磨性.     

挤压铸造AZ91D镁合金的显微组织与力学性能

研究了挤压铸造AZ91D镁合金在不同热处理状态下的显微组织、力学性能以及厚度对镁合金试样力学性能的影响。结果表明,挤压铸造AZ91D镁合金铸态显微组织主要由基体α-Mg和在晶内及晶界上分布的β-Mg17Al12相组成,经固溶处理后得到单相α-Mg固溶体组织,而且在α-Mg晶粒内部也出现了少量颗粒状析出物,经固溶时效处理后β-Mg17Al12相再一次在α-Mg晶内和晶界析出,且晶粒变得更加细小;挤压铸造AZ91D镁合金的硬度、屈服强度、抗拉强度随着试样厚度的增加而减小,而伸长率随着试样厚度的增加而增加。     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

INTRODUCTION TO PATENTS

The invention provides a method of making a mold which can reduce SOx generation rate while preventing decrease in hardening rate in the case of using sulfuric acid for a hardener composition. The method has a mixture step in which fire-resistant particles, a hardener composition and a binder composition are mixed to obtain a composition for a mold. The hardener composition contains sulfuric acid. In the mixture step, sodium carbonate is added. A molar ratio of the sulfuric acid to the sodium carbonate is 0.5 or more and 4.0 or less.     

China Foundry Week 2014

China Foundry Week, hosted by the Foundry Institution of Chinese Mechanical Engineering Society （FICMES） each year, is a large academic event in China. It is one of the ten high-impact activities sponsored by the Chinese Mechanical Engineering Society.     

17th Conference of Hydrodynamic and Electromechanical Control Engineering Call for papers

正1.Contents In order to promote the academic exchanges and technical communication of the research in the field of fluid power transmission and control,fluid control engineering specialized committee of the Chinese Society of Theoretical and Applied Mechanics will hold the 17th Conference of Hydrodynamic and Electromechanical Control Engineering on July 27-29,2014 in Tibet,Lhasa city.     

Information for Contributors

正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis     

Preface

<正>We are pleased to present this Special Issue of Transactions of Nonferrous Metals Society of China containing selected papers from the First Asian Conference on Aluminum Alloys(ACAA-2013),held in Beijing,China,13–17 October 2013.This conference has been initiated,with approval of     

Information for Contributors

The Transactions of Nonferrous Metals Society of China, founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, 1NSPEC, CA, METADEX, AJ and JICST.     

Formulas of Tension of Continuous Rolling Process

The development of computer controlled continuous rolling process calls for a mathematical expression that can express the inequality condition of "constant flow". Tension is the link of the continuous rolling process. From the condition of dynamic equilibrium, a differential equation of tension is given out. On the basis of the physical rules established from the industrial practice and experimental studies, the law of volume constancy, the linear relation of forward slip and tension, the state equation of continuous rolling, the formula of dynamic tension, and the formula of static tension have been obtained. These formulae reflect the functional relations between tensions, thickness, roll velocity, and time in the continuous rolling process. It is implied that the continuous rolling process is a gradually steady, controllable, and measurable dynamic system. An assumption of predicting the thickness of a steel plate using these tension formulae is also put forward.