Hydrogen production characteristics of a bioethanol solar reforming system with solar insolation fluctuations

The development of a bioethanol steam reforming system (FBSR) is considered as a means of distributing energy using PEM fuel cells. Small-scale solar collectors (collection areas on the order of several m²) are installed in a house as a method for applying the FBSR. However, the temperature distribution of a reforming catalyst fluctuates under conditions of unstable solar insolation. Therefore, heat transfer analysis applied in reforming the catalyst layer of the reactor and the temperature distribution and transient response characteristics of the gas composition of the process were investigated. As a case study, meteorological data for representative days in March and August in Sapporo, Japan were recorded, and the hydrogen production speed, power generation output and amount of electricity purchased were analyzed. The results showed that although fluctuations in solar insolation affected the efficiency of the FBSR, the average efficiency of each representative day exceeded 40%. By installing two solar collectors, each with a collection area of 1 m², 21–25% of the average power demand of an individual house can be supplied.     

Global solar radiation estimation from measurements of visibility and air temperature extremes

Solar radiation is the main source of energy for the survival of life and its associated activities. It is important to know accurate solar radiation value in areas such as agricultural activities, solar energy systems, heating, and meteorology. In this study, we present a model for the estimation of solar radiation value with other meteorological parameters in cases where solar radiation cannot be measured or not available. This model is based on the relationship between solar radiation and measured air temperature and visibility extremes. As is known, the incident global solar radiation is attenuated by clouds, aerosols, ozone layer, water vapor, etc.. In the model, the attenuation of the solar radiation is expressed by dew point temperature, visibility, and the maximum and minimum air temperatures. Dew-point temperature refers to the effect of water vapor on solar radiation, air temperature extremes are used to signify cloudiness. Visibility also gives the effect on the attenuation of solar radiation by air pollutants and aerosols in the model. The model was applied to the data taken from meteorological stations in Turkey. Error analysis was performed and compared with the models in the literature and satisfactory results were obtained.

Abbreviations H: Daily total global solar radiation, units of MJ ? m^?2 ? day^?1; H₀: Extraterrestrial solar radiation, units of MJ ? m^?2 ? day^?1; H_m: Measured daily total global solar radiation, units of MJ ? m^?2 ? day^?1; H_c: Calculated daily total global solar radiation, units of MJ ? m^?2 ? day^?1; T_min: Daily minimum temperature, units of °C; T_max: Daily maximum temperature, units of °C; RH: T_dew: Relative humidity, units of %rh; Dew-point temperature, units of °C     

Some aspects of solar radiation climatology of Iraq

Study of the climatology of global solar radiation is considered very useful for assessing the potential efficiency of systems designed for solar energy utilization. This paper explores some aspects of solar radiation climatology in Iraq. Analysis of the monthly averages global solar radiation and the general atmospheric transparency for the period 1971–1985 for three different climatological zones (Mosul, Baghdad, Nasiriyah) are discussed. The frequency distribution of daily clearness index for each station is determined using histograms of frequencies. The percentage number of days with solar radiation and sunshine duration values below a certain value is analyzed and discussed. The period of successive days having radiation less than 5 MJ/m² · day⁻¹ and 10 MJ/m² · day⁻¹ is examined and presented graphically.     

Energy and exergy analyses of an integrated solar‐based desalination quadruple effect absorption system for freshwater and cooling production

In this paper, a novel integrated solar photovoltaic thermal absorption desalination system for freshwater and cooling production is proposed and analyzed thermodynamically. Ammonia–water pair is considered as a working fluid for the absorption system. Effect of average solar radiation for different months, time period of solar radiation availability in Abu Dhabi, salinity of seawater, and temperature of the seawater on energetic and exergetic COPs, production rate of freshwater, and overall performance of the system are investigated under different operating conditions. It is found that energetic and exergetic COPs, production rate of freshwater, energetic and exergetic utilization factors, and performance ratios vary greatly from one month to another because of the dynamic variation in solar radiation and its time of availability. The highest amount of freshwater is produced in the month of July as calculated to be 152 kg/h for a collector area of 100 m² and solar power of 4.8 kW. The highest energetic and exergetic COPs and utilization factors are also obtained for the month of July. Moreover, the highest performance ratio is found to be 0.056 as obtained in the month of July when solar radiation intensity is highest as available for more than half of a day. Copyright © 2012 John Wiley & Sons, Ltd.     

Performance of a dual-purpose solar continuous adsorption system

A conceptual design and performance of a dual-purpose solar continuous adsorption system for domestic refrigeration and water heating is described. Malaysian activated carbon and methanol are used as the adsorbent–adsorbate pair. The heat rejected by the adsorber beds and condensers during the cooling process of the refrigeration part is recovered and used to heat water for the purpose of domestic consumption. In a continuous 24-h cycle, 16.9 MJ/day of heat can be recovered for heating of water in the storage tanks. In the single-purpose intermittent solar adsorption system, this heat is wasted. The total energy input to the dual-purpose system during a 24-h operation is 61.2 MJ/day and the total energy output is 50 MJ/day. The latter is made up of 44.7 MJ/day for water heating and 5.3 MJ/day for ice making. The amount of ice that can be produced is 12 kg/day. Using typical value for the efficiency of evacuated tube collector of water heating system of 65%, the following coefficient of performances (COP's) are obtained: 44% for adsorption refrigeration cycle, 73% for dual-purpose solar water heater, 9.1% for dual-purpose solar adsorption refrigeration and 82.1% for dual-purpose of both solar water heater and refrigerator.     

基于太阳能热驱动甲烷重整制氢的燃料电池发电系统性能研究

该文采用Aspen Plus软件建立膜反应器重整制氢及燃料电池模型,根据拉萨某日太阳能直接辐射强度（DNI）变化计算太阳能可供使用的能量,作为外热源输入重整系统,并分析反应温度、水碳比（S/C）及DNI对该系统各性能指标的影响,性能指标包括甲烷转化率、H₂收率、电池功率及电压、太阳能转换为氢能的效率。结果表明：反应温度为500 ℃,S/C为2.5时有利于太阳能甲烷湿重整反应;系统日性能结果显示在某日10:00—20:00时,电池输出功率120 kW,太阳能-化学能转化效率0.368,系统发电效率0.225。     

Operating schedule of a combined energy network system with fuel cell

The chromosome model showing system operation pattern is applied to GA (genetic algorithm), and the method of optimization operation planning of energy system is developed. The optimization method of this operation planning was applied to the compound system of methanol‐steam‐reforming‐type fuel cell, geothermal heat pump and the electrolysis tank of water. The operation planning was performed for the energy system using the energy demand pattern of the individual residence of Sapporo city. From analysis results, the amount of outputs of a solar module and the relation of the operation cost of the system, which are changed by the weather were clarified. The representation day in February of the ratio of the operation cost in case of (0% of output rates) the rainy weather to the time of fine weather (100% of output rates) is 1.12. And the representation day in July is 1.71. Furthermore, the optimal capacity of accumulation of electricity and thermal storage was estimated, and they are 308 and 23 MJ, respectively. Copyright © 2006 John Wiley & Sons, Ltd.     

The integration of parabolic trough solar collectors and evacuated tube collectors to geothermal resource for electricity and hydrogen production

In this study, electricity and hydrogen production of an integrated system with energy and exergy analyses are investigated. The system also produces clean water for the water electrolysis system. The proposed system comprises evacuated tube solar collectors (ETSCs), parabolic trough solar collectors (PTSCs), flash turbine, organic Rankine cycles (ORC), a reverse osmosis unit (RO), a water electrolysis unit (PEM), a greenhouse and a medium temperature level geothermal resource. The surface area of each collector is 500 m². The thermodynamics analysis of the integrated system is carried out under daily solar radiation for a day in August. The fluid temperature of the medium temperature level geothermal resource is upgraded by ETSCs and PTSCs to operate the flash turbine and the ORCs. The temperature of the geothermal fluid is upgraded from 130 °C to 323.6 °C by the ETSCs and PTSCs. As a result, it is found that the integrated system generates 162 kg clean water, 1215.63 g hydrogen, and total electrical energy of 2111.04 MJ. The maximum energy and exergy efficiencies of the overall system are found as 10.43% and 9.35%, respectively.     

Estimating monthly mean valuesof daily total solar radiation for Australia

Monthly mean values of daily total solar radiation were obtained for the widest possible network acrossAustralia. Bureau of Meteorology sources yielded 11 stations with long term records of both measured daily total solar radiation and sunshine hour values. Monthly modified Angstrom equations were developed from these data and used to estimate radiation values for a further 90 stations in the Bureau of Meteorology network that had sunshine hour data. Measured daily total solar radiation data were obtained from a variety of sources mostly outside the Bureau of Meteorology network for an additional 33 stations. Finally, estimates of solar radiation from detailed cloud cover data were used for a further 12 stations, selected because they filled in significant gaps in coverage. These various sources yielded a total of 146 sets of monthly mean values of daily total solar radiation. For each month optimal surfaces, which were functions of position only, were fitted to this network of values using Laplacian smoothing splines with generalized cross validation. Residuals from the fitted surfaces at the data points were acceptably low. Fitted surfaces which included, in addition to position variables, a cloudiness index based on a transform of mean monthly precipitation further reduced these residuals. The latter fitted surfaces permit estimation of monthly mean values of total daily solar radiation at any point on the continent with a root mean square predictive error of no more than 1.25 MJ m⁻² day⁻¹ (5.2 per cent of the network mean) in summer and 0.74 MJ m⁻² day⁻¹ (5.5 per cent of the network mean) in winter.     

Performance assessment of an integrated PV/T and triple effect cooling system for hydrogen and cooling production

In this paper we study an integrated PV/T absorption system for cooling and hydrogen production based on U.A.E weather data. Effect of average solar radiation for different months, operating time of the electrolyzer, air inlet temperature and area of the PV module on power and rate of heat production, energy and exergy efficiencies, hydrogen production and energetic and exergetic COPs are studied. It is found that the overall energy and exergy efficiency varies greatly from month to month because of the variation of solar radiation and the time for which it is available. The highest energy and exergy efficiencies are obtained for the month of March and their value is 15.6% and 7.9%, respectively. However, the hydrogen production is maximum for the month of August and its value is 9.7 kg because in august, the solar radiation is high and is available for almost 13 h daily. The maximum energetic and exergetic COPs are calculated to be 2.28 and 2.145, respectively and they are obtained in the month of June when solar radiation is high for the specified cooling load of 15 kW.     

Performance assessment of a magnesium chloride saturated solar pond

This paper deals with the experimental investigation of a magnesium chloride saturated solar pond and its performance evaluation through energy and exergy efficiencies. The solar pond system is filled with magnesium chloride containing water to form layers with varying densities. A solar pond generally consists of three zones, and the densities of these zones increase from the top convective zone to the bottom storage zone. The incoming solar radiation is absorbed by salty water (with magnesium chloride) which eventually increases the temperature of the storage zone. The high-temperature salty water at the bottom of the solar pond remains much denser than the salty water in the upper layers. Thus, the convective heat losses are prevented by gradient layers. The experimental temperature changes of the solar pond are measured by using thermocouples from August to November. The densities of the layers are also measured and analysed by taking samples from at the same point of the temperature sensors. The energy and exergy content distributions are determined for the heat storage zone and the non-convective zone. The maximum exergy destructions and losses appear to be 79.05 MJ for the heat storage zone and 175.01 MJ for the non-convective zone in August. The energy and exergy efficiencies of the solar pond are defined as a function of solar radiation and temperatures. As a result, the maximum energy and exergy efficiencies are found to be 27.41% and 26.04% for the heat storage zone, 19.71% and 17.45% for the non-convective zone in August, respectively.     

Monthly mean solar radiation statistics for Australia

Tables of monthly mean solar radiation parameters are computed from detailed cloud cover information. The parameters include direct and global daily total energy inputs to horizontal, inclined and “sun-tracking” surfaces. Comparison with measured global radiation at 12 stations reveals virtually no systematic error in the computation scheme, and an error of 2MJ m⁻² day⁻¹ in the worst case month of any station.     

Development of an economical model to determine an appropriate feed-in tariff for grid-connected solar PV electricity in all states of Australia

Australia is a country with a vast amount of natural resources including sun and wind. Australia lies between latitude of 10–45°S and longitude of 112–152°E, with a daily solar exposure of between less than 3 MJ/(m² day) in winter and more than 30 MJ/(m² day) in summer.Global solar radiation in Australia varies between minimum of 3285 MJ/(m² year) in Hobart to 8760 MJ/(m² year) in Northern Territory. As a result of this wide range of radiation level there will be a big difference between costs of solar PV electricity in different locations.A study we have recently conducted on the solar PV electricity price in all states of Australia. For this purpose we have developed an economical model and a computer simulation to determine the accurate unit price of grid-connected roof-top solar photovoltaic (PV) electricity in A$/kWh for all state of Australia. The benefit of this computer simulation is that we can accurately determine the most appropriate feed-in tariff of grid-connected solar PV energy system. The main objective of this paper is to present the results of this study.A further objective of this paper is to present the details of the unit price of solar PV electricity in the state of Victoria in each month and then to compare with electricity price from conventional power systems, which is currently applied to this state. The state Victoria is located south of Australia and in terms of sun radiation is second lowest compared with the other Australian states.The computer simulation developed for this study makes it possible to determine the cost of grid-connected solar PV electricity at any location in any country based on availability of average daily solar exposure of each month as well as economical factors of the country.     

A grey‐box model of next‐day building thermal load prediction for energy‐efficient control

Accurate building thermal load prediction is essential to many building energy control strategies. To get reliable prediction of the hourly building load of the next day, air temperature/relative humidity and solar radiation prediction modules are integrated with a grey‐box model. The regressive solar radiation module predicts the solar radiation using the forecasted cloud amount, sky condition and extreme temperatures from on‐line weather stations, while the forecasted sky condition is used to correct the cloud amount forecast. The temperature/relative humidity prediction module uses a dynamic grey model (GM), which is specialized in the grey system with incomplete information. Both weather prediction modules are integrated into a building thermal load model for the on‐line prediction of the building thermal load in the next day. The validation of both weather prediction modules and the on‐line building thermal load prediction model are presented. Copyright © 2008 John Wiley & Sons, Ltd.     

Battery control for leveling the amount of electricity purchase in smart‐energy houses

An optimal operation method in smart‐energy houses with photovoltaics (PV) and a storage battery was investigated in a trial production system. In this method, the inverse current of the PV output is not conveyed to the commercial electricity system as operation conditions. Instead, the excess of the consumed PV power is applied to leveling the electricity purchase by appropriately charging and discharging the storage battery. To validate the proposed system, a lithium battery (4 kWh) and PV cell (3 kW) used in average individual houses was installed in a smart‐energy house in a local city (Kitami) in Japan. Another example was introduced into a wider area (Hokkaido, Japan). Accounting for the error between the weather forecast and actual solar radiation, the trial production system reduced the range in the electricity purchase amount by 75.0%, 77.0%, and 73.0% on a representative day in January, April, and July, respectively. The accuracy of the reduction effect in the trial production system, obtained in the proposed optimization analysis, ranged from 1.9% to 7.2%. Moreover, the CO₂ emissions were reduced by 1.990 kg‐CO₂/(Day‐House) in January, 2.910 kg‐CO₂/(Day‐House) in April, and 2.210 kg‐CO₂/(Day‐House) in July.     

Efficiency assessment of solar redox reforming in comparison to conventional reforming

Solar redox reforming is a process that uses solar radiation to drive the production of syngas from natural gas. This approach caught attention in recent years, because of substantially lower reduction temperatures compared to other redox cycles. However, a detailed and profound comparison to conventional solar reforming has yet to be performed. We investigate a two-step redox cycle with iron oxide and ceria as candidates for redox materials. Process simulations were performed to study both steam and dry methane reforming. Conventional solar reforming of methane without a redox cycle, i.e. on an established catalyst was used as reference. We found the highest efficiency of a redox cycle to be that of steam methane reforming with iron oxide. Here the solar-to-fuel efficiency is 43.5% at an oxidation temperature of 873 K, a reduction temperature of 1190 K, a pressure of 3 MPa and a solar heat flux of 1000 kW/m². In terms of efficiency, this process appears to be competitive with the reference process. In addition, production of high purity H₂ or CO is a benefit, which redox reforming has over the conventional approach.     

Experimental investigation and simulation analysis of the thermal performance of a balcony wall integrated solar water heating unit

A balcony wall type solar water heater system was designed and constructed in a high-rise building. The U-type evacuated glass tube solar collector is fixed vertically on the balcony wall. The water, heated in the solar collector, flows through the exchanger coil in the water tank and then flows back to the solar collector. With regard to the hot water supply system, the cold water, heated by the heat exchanger, is sent to the point of use. Considering storeys and water consumption pattern, four apartments are selected for testing. Meanwhile, the theoretical analysis with TRNSYS was presented. According to the experimental results, mean daily collector efficiency is about 40%. Solar fraction is high in summer and autumn for the relative high radiation and high ambient temperature. Under given conditions, the annual energy extracted from tank is 2805.3 MJ/m², and the annual solar fraction is 40.5%. When the tank volume-to-collector area ratio is decreased to 37.5 L/m², the solar fraction can be increased to 50%. The results show that the family to use water all day round gets higher solar fraction than the family using hot water mostly in the morning and night.     

An investigation of the solar powered absorption refrigeration system with advanced energy storage technology

This paper presented a new solar powered absorption refrigeration (SPAR) system with advanced energy storage technology. The advanced energy storage technology referred to the Variable Mass Energy Transformation and Storage (VMETS) technology. The VMETS technology helped to balance the inconsistency between the solar radiation and the air conditioning (AC) load. The aqueous lithium bromide (H₂O-LiBr) was used as the working fluid in the system. The energy collected from the solar radiation was first transformed into the chemical potential of the working fluid and stored in the system. Then the chemical potential was transformed into thermal energy by absorption refrigeration when AC was demanded. In the paper, the working principle and the flow of the SPAR system were explained and the dynamic models for numerical simulation were developed. The numerical simulation results can be used to investigate the behavior of the system, including the temperature and concentration of the working fluid, the mass and energy in the storage tanks, the heat loads of heat exchanger devices and so on. An example was given in the paper. In the example, the system was used in a subtropical city like Shanghai in China and its operating conditions were set as a typical summer day: the outdoor temperature varied between 29.5 °C and 38 °C, the maximum AC load was 15.1 kW and the total AC capacity was 166.1 kW h (598.0 MJ). The simulation results indicated that the coefficient of performance (COP) of the system was 0.7525 or 0.7555 when the condenser was cooled by cooling air or by cooling water respectively and the storage density (SD) was about 368.5 MJ/m³. As a result, the required solar collection area was 66 m² (cooling air) or 62 m² (cooling water) respectively. The study paves the road for system design and operation control in the future.     

Thermochemical waste‐heat recuperation by steam methane reforming with flue gas addition

The process flow schematic of fuel‐consuming equipment with thermochemical waste‐heat recuperation by steam methane reforming with an addition of flue gas to the reaction mixture is suggested. The advantages of such a thermochemical recuperation (TCR) system compared with the TCR system by steam methane reforming are shown and justified. Based on the first law energy analysis, the heat inputs and outputs of the TCR system were determined. To determine the exhaust gases heat transformed into chemical energy of a new synthetic fuel, the thermodynamic analysis by minimizing Gibbs energy via Aspen HYSYS was performed. It was found that with an increase in the mole fraction of combustion products in the reaction mixture, the enthalpy of the methane reforming reaction increases, especially noticeable at the temperature range above 1000 K. Based on the heat, balance of the TCR system was established that the addition of combustion products to the reaction mixture has the following effects: reducing the heat input for steam production in a steam generator; reduction of the steam generator size because of the need to produce a smaller amount of steam in comparison with TCR by pure steam methane reforming; and reducing the amount of heat transferred through the wall of the reformer and, as a consequence, reduction in size of the reformer.     

Measurement of solar energy radiation in Abu Dhabi,UAE

This paper presents data on measurement of actual solar radiation in Abu Dhabi (24.43°N, 54.45°E). Global solar radiation and surface temperatures were measured and analyzed for one complete year. High resolution, real-time solar radiation and other meteorological data were collected and processed. Daily and monthly average solar radiation values were calculated from the one-minute average recorded values. The highest daily and monthly mean solar radiation values were 369 and 290 W/m², respectively. The highest one-minute average daily solar radiation was 1041 W/m². Yearly average daily energy input was 18.48 MJ/m²/day. Besides the global solar radiation, the daily and monthly average clearness indexes along with temperature variations are discussed. When possible, global solar energy radiation and some meteorological data are compared with corresponding data in other Arab state capitals. The data collected indicate that Abu Dhabi has a strong potential for solar energy capture.