Simulation-based sensitivity analysis of an on-site hydrogen production unit in Hungary

This article examines the additional profit that can be achieved with the integrated operation of an on-site electrolyser, a hydrogen tank, a photovoltaic system, and a wind power plant based on Hungarian data from 2019. The results of the optimisation show that the system economically reduces the volatility of weather-dependent renewable production, so there is a promising demand-side management potential in coordination. We found that the operating profit is highest in April at EUR 19,416, 18,932 in July, and lowest at EUR 17,075 in January. The production curve of photovoltaic capacities is better matched to fuel demand, so increasing the share of solar energy results in lower balancing activity but higher profits. Increasing the size of the hydrogen storage and electrolyser, with constant hydrogen demand and prices, will cause a convergent increase in profits, however above a 10 kg storage capacity or 350 kW electrolyser capacity there is no substantial profit increase. In the case of the economically optimal asset size, there is a slight competition between the electricity market and the hydrogen distribution activity. The choice between the two activities depends on current electricity and hydrogen prices and the cost of unmet hydrogen demand.     

A flexible analytical model for operational investigation of solar hydrogen plants

Hydrogen will become a dominant energy carrier in the future and the efficiency and lifetime cost of its production through water electrolysis is a major research focus. Alongside efforts to offer optimum solutions through plant design and sizing, it is also necessary to develop a flexible virtualised replica of renewable hydrogen plants, that not only models compatibility with the “plug-and-play” nature of many facilities, but that also identifies key elements for optimisation of system operation. This study presents a model for a renewable hydrogen production plant based on real-time historical and present-day datasets of PV connected to a virtualised grid-connected AC microgrid comprising different technologies of batteries, electrolysers, and fuel cells. Mathematical models for each technology were developed from chemical and physical metrics of the plant. The virtualised replica is the first step toward the implementation of a digital twin of the system, and accurate validation of the system behaviour when updated with real-time data. As a case study, a solar hydrogen pilot plant consisting of a 60 kW Solar PV, a 40 kW PEM electrolyser, a 15 kW LIB battery and a 5 kW PEM fuel cell were simulated and analysed. Two effective operational factors on the plant's performance are defined: (i) electrolyser power settings to determine appropriate hydrogen production over twilight periods and/or overnight and (ii) a user-defined minimum threshold for battery state of charge to prevent charge depletion overnight if the electrolyser load is higher than its capacity. The objective of this modelling is to maximise hydrogen yield while both loss of power supply probability (LPSP) and microgrid excess power are minimised. This analysis determined: (i) a hydrogen yield of 38–39% from solar DC energy to hydrogen energy produced, (ii) an LPSP <2.6 × 10^?4 and (iii) < 2% renewable energy lost to the grid as excess electricity for the case study.     

Off-grid hybrid renewable energy system with hydrogen storage for South African rural community health clinic

Most inhabitants of rural communities in Africa lack access to clean and reliable electricity. This has deprived the rural dwellers access to modern healthcare delivery. In this paper, an off-grid renewable energy system consisting of solar PV and wind turbine with hydrogen storage scheme has been explored to meet the electrical energy demands of a health clinic. The health clinic proposed is a group II with 10 beds located in a typical village in South Africa. First, the wind and solar energy resources of the village were analysed. Thereafter, the microgrid architecture that would meet the energy demand of the clinic (18.67 kWh/day) was determined. Some of the key results reveal that the average annual wind speed at 60 m anemometer height and solar irradiation of the village are 7.9 m/s and 4.779 kWh/m²/day, respectively. The required architecture for the clinic composes of 40 kW solar PV system, 3 numbers of 10 kW wind turbines, 8.6 kW fuel cell, 25 kW electrolyser and 40 kg hydrogen tank capacity. The capital cost of the microgrid was found to be $177,600 with a net present cost of $206,323. The levelised cost of energy of the system was determined to be 2.34 $/kWh. The project has a breakeven grid extension distance of 8.81 km. Since this distance is less than the nearest grid extension distance of 21.35 km, it is established that the proposed renewable energy microgrid with a hydrogen storage system is a viable option for the rural community health clinic.     

Design and simulation of a solar-hydrogen system for different situations

In recent years, hybrid photovoltaic–fuel cell energy systems have been popular as energy production systems for different applications. A typical solar-hydrogen system can be modeled the electricity supplied by PV panels is used to meet the demand directly to the maximum extent possible. If there is any surplus PV power over demand, and capacity left in the tank for accommodating additional hydrogen, this surplus power is supplied to the electrolyser to produce hydrogen for storage. When the output of the PV array is not sufficient to supply the demand, the fuel cell draws on hydrogen from storage and produces electricity to meet the supply deficit.     

Analyzing the levelized cost of hydrogen in refueling stations with on-site hydrogen production via water electrolysis in the Italian scenario

Hydrogen refueling infrastructures with on-site production from renewable sources are an interesting solution for assuring green hydrogen with zero CO₂ emissions. The main problem of these stations development is the hydrogen cost that depends on both the plant size (hydrogen production capacity) and on the renewable source.In this study, a techno-economic assessment of on-site hydrogen refueling stations (HRS), based on grid-connected PV plants integrated with electrolysis units, has been performed. Different plant configurations, in terms of hydrogen production capacity (50 kg/day, 100 kg/day, 200 kg/day) and the electricity mix (different sharing of electricity supply between the grid and the PV plant), have been analyzed in terms of electric energy demands and costs.The study has been performed by considering the Italian scenario in terms of economic streams (i.e. electricity prices) and solar irradiation conditions.The levelized cost of hydrogen (LCOH), that is the more important indicator among the economic evaluation indexes, has been calculated for all configurations by estimating the investment costs, the operational and maintenance costs and the replacement costs.Results highlighted that the investment costs increase proportionally as the electricity mix changes from Full Grid operation (100% Grid) to Low Grid supply (25% Grid) and as the hydrogen production capacity grows, because of the increasing in the sizes of the PV plant and the HRS units. The operational and maintenance costs are the main contributor to the LCOH due to the annual cost of the electricity purchased from the grid.The calculated LCOH values range from 9.29 €/kg (200 kg/day, 50% Grid) to 12.48 €/kg (50 kg/day, 100% Grid).     

Design of hybrid power-to-power systems for continuous clean PV-based energy supply

The increasing penetration of intermittent renewable sources, fostering power sector decarbonization, calls for the adoption of energy storage systems as an essential mean to improve local electricity exploitation, reducing the impact of distributed power generation on the electric grid. This work compares the use of hydrogen-based Power-to-Power systems, battery systems and hybrid hydrogen-battery systems to supply a constant 1 MW_el load with electricity locally generated by a photovoltaic plant. A techno-economic optimization model is set up that optimizes the size and annual operation of the system components (photovoltaic field, electrolyzer, hydrogen storage tanks, fuel cell and batteries) with the objective of minimizing the annual average cost of electricity, while guaranteeing an imposed share of local renewable self-generation. Results show that, with the present values of investment costs and grid electricity prices, the installation of an energy storage system is not economically attractive by itself, whereas the installation of PV panels is beneficial in terms of costs, so that the baseline optimal solution consists of a 4.2 MW_p solar field capable to self-generate 33% of the load annually. For imposed shares of self-generation above 40%, decoupling generation and consumption becomes necessary. The use of batteries is slightly less expensive than the use of hydrogen storage systems up to a 92% self-generation rate. Above this threshold, seasonal storage becomes predominant and hybrid storage becomes cheaper than batteries. The sale of excess electricity is always important to support the plant economics, and a sale price reduction sensibly impacts the results. Hydrogen storage becomes more competitive when the need for medium and long terms energy shift increases, e.g. in case of having a cap on the available PV capacity.     

Technical and economical design of PV system and hydrogen storage including a sodium hypochlorite plant in a small community: Case of study of Paraguay

The increasing use of renewable power sources for distributed generation (DG) has made the application of storage systems a necessity to ensure the continuous supply. This paper analyzes technically and economically an autonomous sodium hypochlorite plant using a renewable energy source and a hydrogen storage system in the Western Region of Paraguay. In this region, there is abundant underground brackish water to produce industrial and energetic hydrogen. In addition, an isolated photovoltaic (PV) system feeds with electricity an electrolyzer, used for sodium hypochlorite production, and the brackish water and freshwater pumping systems. The hydrogen and fuel cell are used as backup system in the operation of the electrolyzer. Preliminary results show that hydrogen stored during the day can increase hypochlorite production by up to 31%. The PV solar system surplus can supply the demand of an off-grid community near the plant. The results show that the plant's return on investment (ROI) is 7 years.     

Assessment of hydrogen as a potential energy storage for urban areas’ PV-assisted energy systems - Case study

The world is experiencing unprecedented development in the clean energy sector in residential and industrial applications. This paper provides a case study assessing different scenarios of greenizing the electrical energy demand in El-Mostakbal city in Egypt. Three scenarios are studied with consideration of a photovoltaic (PV) system integrated with the grid-connected city with different integrated system configurations. The scenarios for the grid-connected city are scenario-I: only PV, scenario-II: PV with batteries for electricity storage along with grid electricity, and scenario-III: PV with hydrogen production, storage, and utilization for covering the electric demand along with grid electricity, these scenarios are assessed technoeconomically, and the results show an optimized case where the electricity demand of the city can be met with 64.3% produced from solar energy, at $71.7 M of the net present cost.     

Techno-economic assessment of hydrogen production from seawater

Population growth and the expansion of industries have increased energy demand and the use of fossil fuels as an energy source, resulting in release of greenhouse gases (GHG) and increased air pollution. Countries are therefore looking for alternatives to fossil fuels for energy generation. Using hydrogen as an energy carrier is one of the most promising alternatives to replace fossil fuels in electricity generation. It is therefore essential to know how hydrogen is produced. Hydrogen can be produced by splitting the water molecules in an electrolyser, using the abondand water resources, which are covering around ? of the Earth's surface. Electrolysers, however, require high-quality water, with conductivity in the range of 0.1–1 μS/cm. In January 2018, there were 184 offshore oil and gas rigs in the North Sea which may be excellent sites for hydrogen production from seawater. The hydrogen production process reported in this paper is based on a proton exchange membrane (PEM) electrolyser with an input flow rate of 300 L/h. A financially optimal system for producing demineralized water from seawater, with conductivity in the range of 0.1–1 μS/cm as the input for electrolyser, by WAVE (Water Application Value Engine) design software was studied. The costs of producing hydrogen using the optimised system was calculated to be US$3.51/kg H₂. The best option for low-cost power generation, using renewable resources such as photovoltaic (PV) devices, wind turbines, as well as electricity from the grid was assessed, considering the location of the case considered. All calculations were based on assumption of existing cable from the grid to the offshore, meaning that the cost of cables and distribution infrastructure were not considered. Models were created using HOMER Pro (Hybrid Optimisation of Multiple Energy Resources) software to optimise the microgrids and the distributed energy resources, under the assumption of a nominal discount rate, inflation rate, project lifetime, and CO₂ tax in Norway. Eight different scenarios were examined using HOMER Pro, and the main findings being as follows:The cost of producing water with quality required by the electrolyser is low, compared with the cost of electricity for operation of the electrolyser, and therefore has little effect on the total cost of hydrogen production (less than 1%).The optimal solution was shown to be electricity from the grid, which has the lowest levelised cost of energy (LCOE) of the options considered. The hydrogen production cost using electricity from the grid was about US$ 5/kg H₂.Grid based electricity resulted in the lowest hydrogen production cost, even when costs for CO₂ emissions in Norway, that will start to apply in 2025 was considered, being approximately US$7.7/kg H₂.From economical point of view, wind energy was found to be a more economical than solar.     

The role of hydrogen in achieving the decarbonization targets for the UK domestic sector

To meet the UK's decarbonization targets the introduction of novel integrated renewable energy generation, storage and demand management systems is required. In this paper the current role of fuel cells in the British domestic sector is discussed using simulation results of a solid oxide fuel cell (SOFC) system in a typical British single dwelling. 17% of carbon dioxide emissions are saved and 69% of the electricity generated by the SOFC system is exported to the grid for this single dwelling according to simulation results. Additionally, the same SOFC system is integrated with photovoltaic technology in a 7 home zero carbon community. The community approach adds a significant benefit given it increases the amount of electricity generated by the SOFC system which is used onsite by 128%, being the price of imported electricity 3 times higher than the export tariff. Then, a combination of short-term and long-term energy storage strategies is suggested by means of a lithium-ion battery and polymer electrolyte membrane (PEM) electrolyser which increased the self-consumption by 118%. According to simulation results, a 6 kW PEM electrolyser with an annual efficiency of 66% only generates 19% of the hydrogen which is consumed by the SOFC system which was used to meet the peak demand using PV generation.     

Hydrogen production by coupling pressurized high temperature electrolyser with solar tower technology

Solar hydrogen production by coupling of pressurized high temperature electrolyser with concentrated solar tower technology is studied. As the high temperature electrolyser requires constant temperature conditions, the focus is made on a molten salt solar tower due to its high storage capacity. A flowsheet was developed and simulations were carried out with Aspen Plus 8.4 software for MW-scale hydrogen production plants. The solar part was laid out with HFLCAL software. Two different scenarios were considered: the first concerns the production of 400 kg/d hydrogen corresponding to mobility use (fuel station). The second scenario deals with the production of 4000 kg/d hydrogen for industrial use. The process was analyzed from a thermodynamic point of view by calculating the overall process efficiency and determining the annual production. It was assumed that a fixed hydrogen demand exists in the two cases and it was assessed to which extent this can be supplied by the solar high temperature electrolysis process including thermal storage as well as hydrogen storage. For time periods with a potential over supply of hydrogen, it was considered that the excess energy is sold as electricity to the grid. For time periods where the hydrogen demand cannot be fully supplied, electricity consumption from the grid was considered. It was assessed which solar multiple is appropriate to achieve low consumption of grid electricity and low excess energy. It is shown that the consumption of grid electricity is reduced for increasing solar multiple but the efficiency is also reduced. At a solar multiple of 3.0 an annual solar-to-H₂ efficiency greater than 14% is achieved at grid electricity production below 5% for the industrial case (4000 kg/d). In a sensitivity study the paramount importance of electrolyser performance, i.e. efficiency and conversion, is shown.     

Hybridization strategies of power-to-gas systems and battery storage using renewable energy

In this paper, the hybrid concept to use renewable electricity to produce hydrogen with an electrolyser in combination with a battery is introduced and analysed. This hybrid system opens the possibility to optimise operation and to increase operation times of the system and thus to improve the techno-economic performance. To analyse the performance, a model has been developed, which designs and operates a single or hybrid power-to-gas system in a cost optimal manner. The underlying method is a mixed integer linear programming (MILP) approach, which minimises total system costs. The cost optimisation modelling is performed by a case study for a hybrid electrolyser/battery system directly coupled with a large PV power plant without grid connection. The results show, that batteries can support electrolyser operation in a reasonable way. This is however associated with higher hydrogen production costs and not competitive compared to the installation of additional electrolyser capacity or curtailment of electricity.     

The value chain of green hydrogen for fuel cell buses – A case study for the Rhine-Main area in Germany

As an immanent necessity to reduce global greenhouse gas emissions, the energy transition poses a major challenge for the next 30 years, as it includes a cross-sectoral increase of fluctuating renewable energy production, grid extension to meet regional electricity supply and demand as well as an increase of energy storage capacity. Within the power-to-gas concept, hydrogen is considered as one of the most promising solutions.The paper presents a scenario-based bottom-up approach to analyse the hydrogen supply chain to substitute diesel with fuel cell buses in the Rhine-Main area in central Germany for the year 2025. The analysis is based on field data derived from the 6 MW power-to-gas plant “Energiepark Mainz” and the bus demonstration project “H₂-Bus Rhein-Main”. The system is modelled to run simulations on varying demand scenarios. The outcome is minimised hydrogen production costs derived from the optimal scheduling of a power-to-gas plant in terms of the demand. The assessment includes the energy procurement for hydrogen production, different hydrogen delivery options and spatial analysis of potential power-to-gas locations.     

Hybrid systems to address seasonal mismatches between electricity production and demand in nuclear renewable electrical grids

A strategy to enable zero-carbon variable electricity production with full utilization of renewable and nuclear energy sources has been developed. Wind and solar systems send electricity to the grid. Nuclear plants operate at full capacity with variable steam to turbines to match electricity demand with production (renewables and nuclear). Excess steam at times of low electricity prices and electricity demand go to hybrid fuel production and storage systems. The characteristic of these hybrid technologies is that the economic penalties for variable nuclear steam inputs are small. Three hybrid systems were identified that could be deployed at the required scale. The first option is the gigawatt-year hourly-to-seasonal heat storage system where excess steam from the nuclear plant is used to heat rock a kilometer underground to create an artificial geothermal heat source. The heat source produces electricity on demand using geothermal technology. The second option uses steam from the nuclear plant and electricity from the grid with high-temperature electrolysis (HTR) cells to produce hydrogen and oxygen. Hydrogen is primarily for industrial applications; however, the HTE can be operated in reverse using hydrogen for peak electricity production. The third option uses variable steam and electricity for shale oil production.     

Stand-alone operation of an alkaline water electrolyser fed by wind and photovoltaic systems

Over the last few years, hydrogen technologies have established themselves as key enablers in the medium and long-term development of a new energy model that offers greater sustainability and independence than the present-day one. In this respect, the integration of water electrolysis with renewable energy-based systems can play an important part in the large-scale production of sustainable hydrogen. This paper reports on the complete experimental characterisation of a 1 Nm³ h⁻¹ alkaline water electrolyser located in the Public University of Navarre (UPNa). Specifically, a study was made of the electrical performance, hydrogen production rate, purity of the gases generated and energy efficiency, for a range of operating currents (40–120 A), temperatures (35–65 °C) and pressures (5–25 bar). Additionally, an experimental study was conducted on the electrolyser operation under conditions that are characteristic of a stand-alone wind power and PV-based renewable energy system, installed at the UPNa. The results obtained for the wind power and PV emulations showed that the electrolyser performed correctly, with regard to balance of plant and its principal electrochemical characteristics. Furthermore, the mean energy efficiency of the electrolyser was 77.7% for the wind power emulation, and 78.6% for the PV emulation on a day with stable irradiance, and 78.1% on a day with highly variable irradiance (day with scattered clouds).     

Efficient utilization of waste heat from molten carbonate fuel cell in parabolic trough power plant for electricity and hydrogen coproduction

Direct steam generating parabolic trough power plant is an important technology to match future electric energy demand. One of the problems related to its emergence is energy storage. Solar-to-hydrogen is a promising technology for solar energy storage. Electrolysis is among the most processes of hydrogen production recently investigated. High temperature steam electrolysis is a clean process to efficiently produce hydrogen. In this paper, steam electrolysis process using solar energy is used to produce hydrogen. A heat recovery steam generator generates high temperature steam thanks to the molten carbonate fuel cell's waste heat. The analytical study investigates the energy efficiency of solar power plant, molten carbonate fuel cell and electrolyser. The impact of waste heat utilization on electricity and hydrogen generation is analysed. The results of calculations done with MATLAB software show that fuel cell produces 7.73 MWth of thermal energy at design conditions. 73.37 tonnes of hydrogen and 14.26 GWh of electricity are yearly produced. The annual energy efficiency of electrolyser is 70% while the annual mean electric efficiency of solar power plant is 18.30%.The proposed configuration based on the yearly electricity production and hydrogen generation has presented a good performance.     

Assessing green energy growth in Nepal with a hydropower-hydrogen integrated power grid model

The involvement of green hydrogen in energy transformation is getting global attention. This assessment examines the hydrogen production and its utilization potential in one of the hydropower-rich regions, Nepal under various demand growth and technology intervention scenarios by developing a power grid model of 52 nodes and 68 transmission lines operating at an hourly time-step. The model incorporates a grid-connected hydrogen storage system as well as charging stations for electric and hydrogen vehicles. The least-costly pathways for power grid expansion at the nodal and provincial levels are identified through optimization. The results show that 32 GW of installed capacity is required to meet domestic electricity demand and 14 GW more hydropower should be exploited to completely decarbonize the transport sector by 2050. For maintaining 50% shares of hydrogen vehicle in the transport sector and meet government electricity export targets, Nepal requires 5.7 GW, 12 GW and 23 GW of the additional electrolyzer, hydrogen storage tanks and storage-based hydropower capacities respectively. For a given electricity demand, introducing hydrogen systems can reduce the capacity requirements of hydro storage by storing surplus power generated from pondage run-of-the-river and run-of-the-river hydropower during the rainy season and using it in the dry season.     

Techno-economic analysis of photovoltaic-hydrogen refueling station case study: A transport company Tunis-Tunisia

This paper sheds the light on the future of green hydrogen in Tunisia. So, a detailed economic assessment and evaluation of the Levelized Hydrogen Cost (LHC) and the Net Profit (NP) of a Photovoltaic (PV) Hydrogen Refueling Station (HRS) are presented and discussed. Tunisia is characterized by its high PV potential which makes the production of electricity from solar energy an effective alternative source. However, due to the regulations and issues related to the connection of medium PV scale to the power grid, the energy produced from renewable sources (RS) is still less than 3% of the total produced electricity. On the other hand, the price of hydrocarbon fuels is still increasing. The gap between production and total demand in hydrocarbons has created a deficit in the primary energy balance. Therefore, the production of hydrogen from solar energy for refueling Fuel Cell Vehicles (FCV)s consists of a promising solution to boost the development of the country, reduce hydrocarbon fuels consumption, and protect the environment. The sizing of a small PV-HRS to produce 150 kg of hydrogen per day shows the necessity to install PV systems with a total Direct Current (DC) capacity of 1.89 MWp. The Initial Cost (IC) analysis shows that while the PV system cost represents 48.5% of the total IC, the IC of electrolysers represents 41%. The storage system cost is approximately equal to 3.2% of the total IC. The LHC is equal to 3.32€/kg with a total IC of 2.34 million €.     

Thermodynamic analysis of a combined PV/T–fuel cell system for power,heat, fresh water and hydrogen production

A hybrid renewable energy system is proposed and analyzed for electricity, heated air, purified water and hydrogen production. Energy, exergy and economic analyses are performed to analyze and determine the performance of the system under different operating conditions. The photovoltaic/thermal (PV/T) system produces heat and electricity for residential applications. Excess power is used to operate electrolyser which produces hydrogen to be fed directly to a fuel cell. Fuel cell is operated during high power demand, and it produces electricity, heat and water for residential applications. The water produced as a by-product by the fuel cell is used for drinking water supply. The parametric studies are conducted to determine the efficiencies of the system with and without fuel cell network for hot air, power and purified water. When fuel cell heat is used, the overall system efficiency increases to 5.65% for energy and 19.8% for exergy. Up to 80 L of drinkable water can be collected from the fuel cell when operated for extended periods. The present study confirms a significant economic gain when fuel cell heat and water are utilized as useful outputs.     

Green hydrogen as feedstock: Financial analysis of a photovoltaic-powered electrolysis plant

The weather-dependent electricity generation from Renewable Energy Sources (RES), such as solar and wind power, entails that systems for energy storage are becoming progressively more important. Among the different solutions that are being explored, hydrogen is currently considered as a key technology allowing future long-term and large-scale storage of renewable power.Today, hydrogen is mainly produced from fossil fuels, and steam methane reforming (SMR) is the most common route for producing it from natural gas. None of the conventional methods used is GHG-free. The Power-to-Gas concept, based on water electrolysis using electricity coming from renewable sources is the most environmentally clean approach. Given its multiple uses, hydrogen is sold both as a fuel, which can produce electricity through fuel cells, and as a feedstock in several industrial processes. Just the feedstock could be, in the short term, the main market of RES-based hydrogen.In this paper, we present the results obtained from a techno-economic-financial evaluation of a system to produce green hydrogen to be sold as a feedstock for industries and research centres. A system which includes a 200 kW photovoltaic plant and a 180 kW electrolyser, to be located in Messina (Italy), is proposed as a case study. According to the analyses carried out, and taking into account the current development of technologies, it has been found that investment to realise a small-scale PV-based hydrogen production plant can be remunerative.