Effect of leavening agents and sugars on the formation of hydroxymethylfurfural in cookies during baking

The effects of recipe compositions in terms of leavening agent (ammonium and sodium bicarbonates) and sugars (sucrose and glucose), and baking conditions (temperature and time) on HMF formation in cookies were studied. Five recipes were prepared by varying the types of leavening agent and sugar. The cookies were baked at different temperatures (180, 200, 210 and 220 °C) for different time (10, 15, 20 and 25 min) to monitor physical and chemical changes in cookie composition in terms of water activity, pH, surface browning, sugar decomposition, and hydroxymethylfurfural (HMF) formation. Decreasing moisture to a level under a water activity of 0.4 appeared as the critical point in baking where the rate of HMF formation drastically increased after this point. After this stage, sucrose decomposed very rapidly if ammonium bicarbonate was used as the leavening agent at temperatures greater than 200 °C. Replacing ammonium bicarbonate with sodium bicarbonate maintained pH of cookies ranging between 9.0 and 10.0 during baking, which limited the decomposition of sucrose.     

Baking High-Ratio White Layer Cakes with Microwave Energy

Microwave energy was evaluated as a means of baking high-ratio white-layer cakes by considering the effects of various processing conditions and amounts of ingredients. Minimal water in cakes baked with microwave energy did not result in surface collapse as with cakes baked by conventional means. As the amount of monocalcium phosphate monohydrate in the baking powder blend was increased, volume and specific volume decreased and crumb firmness and internal score increased. There was no evidence of any significant internal nor surface batter flow in the conventional cake, while in the microwave cake considerable batter flow was observed on the surface and internally in the upper central regions of the cake. Scanning electron micrograph showed differences in cell structure between both types of cake. The cells in the center of the cake baked with microwave energy were more irregular and had thicker cell walls than the conventional cake.     

Temperature influences epimerization and composition of flavanol monomers,dimers and trimers during cocoa bean roasting

Cocoa consumption is suggested to promote many health benefits, since cocoa is a rich source of flavanols; but amounts and profiles of flavanols depend strongly on the bean type, origin and manufacturing process. Roasting is known as a crucial step in technical treatment of cocoa, which leads to flavanol losses and modifications, especially the epimerization of (−)-epicatechin to (−)-catechin. This study monitors the influence of cocoa bean roasting on the composition of flavanol monomers to trimers, with special focus on epimerization, which was quantified for procyanidin dimers, and also observed for trimers for the first time. Five dimeric and two trimeric potential epimerization products were detected and the extent of epimerization during cocoa roasting was shown to be a function of temperature. The data also showed remarkable variations in the change of flavanol content. The quantified flavanols decreased about 50% in Java beans and increased about 30% in Ivory Coast beans, despite being roasted under equal conditions.     

EFFECTS OF BAKING PARAMETERS ON THE WHITE LAYER CAKE QUALITY BY COMBINED USE OF CONVENTIONAL AND MICROWAVE OVENS

The effects of combined conventional and microwave oven baked white layer cake characteristics were studied. Two types of commercially milled wheat flour, white (A) and whole wheat (B), were used. The modified white layer cake making method was used for conducting the cake baking trials. The conventional baking times (8 or 11 min), microwave power (400 or 600 W) and microwave baking time (30, 40, or 50 s) were chosen as baking parameters. Conventional baking was applied to form the cake crust before baking with the microwave oven used to form the crumb of the cakes. The performance of combination baking was compared with the performance of conventional baking. The volume, bake loss, internal factors, and crust color of cakes were evaluated as quality characteristics. The bake losses of cakes using the combination of short oven times and low microwave power for selected microwave times were smaller than the bake losses of the control cakes for both flours. Long oven times and low microwave power increased the specific volume of cakes. Cakes baked from flours A and B exhibited similar internal properties. Oven time significantly affected the crust color of cakes made with flour A. The crust color of cakes made with flour B was similar to the crust color of control cakes. Using a combination of conventional and microwave baking produces cakes with qualities equivalent to the qualities of cakes produced with conventional baking.     

The effect of par‐baking and frozen storage time on the quality of cup cake

The effects of frozen storage and initial baking time of par‐baked cake on baking loss, volume, moisture, colour and textural properties of cake obtained after thawing and rebaking were investigated. Cakes, par‐baked at 175 °C for 15, 20 and 25 min, were stored at ?18 °C for 3, 6 and 9 months. After storage, par‐baked cakes were thawed and rebaked at 175 °C for 10, 15 and 20 min. Baking loss, moisture content, L and +b colour values, firmness, gumminess and chewiness of the resulting full‐baked cakes were significantly affected by both par‐baking and frozen storage time, while specific volume, cohesiveness, springiness and resilience values were significantly affected by frozen storage time. The increase in the time of frozen storage of the par‐baked cake leads to a decrease in the quality of the rebaked cake, namely an increase of baking loss and cake crumb firmness, and a loss in the moisture content and specific volume. Moisture of cake crumb, L and +b colour values, firmness, gumminess and chewiness significantly increased as the par‐baking time increased. However, regarding baking loss, specific volume, moisture content and textural properties, 3‐month intermediate storage at ?18 °C and 20‐min initial baking time gave the best result among the cakes produced by using the two‐step baking procedure.     

Effect of Flour Type and Baking Temperature on Cake Dynamic Height Profile Measurements During Baking

A dynamic height profile method using digital imaging of cakes at 2 min intervals during baking was used to analyze changes in volume during baking for cakes made with three different flour types (plain flour, heat-treated cake flour, and strong white flour) and baked at three different temperatures (175°C, 190°C, and 205°C). The cakes made from the different flours showed, with some exceptions, a similar trend in the shape and development of the top contour during baking. In the first 4–6 min of baking, there was relatively little expansion followed by a period of rapid expansion to the maximum volume and a period of contraction up to the end of baking. For the three flour types, volume peaked at 16–17 min for the medium and high baking temperatures and at 20 min for the low baking temperature. Cakes made from heat-treated cake flour and strong white flour baked at low and high temperatures produced cakes where the center of the cake was lower than the surrounding pins resulting in a final undesirable dimpled cake contour. A higher baking temperature caused the cake to rise more rapidly. Baking at high temperature produced cakes which shrank the most (P < 0.001) during cooling. Among all combinations of flour type and different temperature treatments, cake made from heat-treated cake flour baked at the middle temperature produced the best final cake in terms of a final dome-shape contour, an appreciable volume during baking, less volume shrinkage during baking, and maximum cross-sectional area of the half cake after 1 h cooling.     

Relative importance of moisture migration and amylopectin retrogradation for pound cake crumb firming

Moisture migration largely impacts cake crumb firmness during storage at ambient temperature. To study the importance of phenomena other than crumb to crust moisture migration and to exclude moisture and temperature gradients during baking, crustless cakes were baked using an electrical resistance oven (ERO). Cake crumb firming was evaluated by texture analysis. First, ERO cakes with properties similar to those baked conventionally were produced. Cake batter moisture content (MC) was adjusted to ensure complete starch gelatinisation in the baking process. In cakes baked conventionally, most of the increase in crumb firmness during storage was caused by moisture migration. Proton nuclear magnetic resonance (¹H NMR) showed that the population containing protons of crystalline starch grew during cake storage. These and differential scanning calorimetry (DSC) data pointed to only limited amylopectin retrogradation. The limited increase in amylopectin retrogradation during cake storage cannot solely account for the significant firming of ERO cakes and, hence, other phenomena are involved in cake firming.     

Use of Yuja (Citrus junos) pectin as a fat replacer in baked foods

Pectin from yuja pomace was incorporated into cake formulations to evaluate the baking performance as a fat replacer. When shortening in cakes was replaced with different levels of pectin gel, cake batter exhibited greater viscosity and less shear-thinning behavior. The viscosities were well characterized using a Power-law model. The specific gravity of cake batter significantly increased with increasing levels of pectin gel (p<0.05) and was highly correlated with the cake volume after baking. Although cakes containing pectin exhibited increased textural hardness, shortening replacement with pectin up to 10% by weight was effective in producing cakes as soft as the control cake without a volume loss. There was an overall tendency that cakes with higher amounts of pectin showed a lighter surface color. Yuja pectin was thus used in cake baking as a fat replacer, producing baked goods with reduced fat and calorie content.     

EFFECTS OF OVEN HUMIDITY ON FOODS BAKED IN GAS CONVECTION OVENS1

Bread, cakes, and cookies were baked in direct‐ and indirect‐gas fired, foodservice style convection ovens. Oven humidity was varied by including different numbers of perlite and water dummy loads during baking. Oven, product, and dummy temperatures were continuously recorded during baking, as was oven humidity. The properties of the finished baked foods were measured. Increased oven humidity resulted in products with higher yield, greater volume or spread, lighter color, and reduced firmness.     

Comparison of crumb microstructure from pound cakes baked in a microwave or conventional oven

Imaging, light microscopy and scanning electron microscopy were used to compare the microstructure of crumbs from pound cakes baked in a microwave or conventional oven. The microwave baking conditions for pound cake (240 W, 5 min) were established in previous research, conventional baked pound cakes were obtained using a swing oven at 180 °C for 40 min. Statistical differences in total cell, cell/cm² and mean cell area (P?0.05) were observed in the image analysis. Cells from microwaved pound cake crumbs were 20% larger. However, factor shape was 0.81 for both microwave and conventionally baked crumbs, and crumbs from both oven types were similar in appearance. Light microscopy revealed birefringence in crumbs from both types of pound cakes. Scanning electron microscopy revealed that the conventionally baked product had a greater amount of protein matrix however; the matrix structure of the crumb was comparable between microwave-baked and conventionally baked pound cakes. In conclusion, our results suggest that the unique aspects of pound cake dough, including its high content of fat, sugar and moisture, make it well suited to microwave baking.     

Cake baking in tunnel type multi-zone industrial ovens Part II. Evaluation of quality parameters

In addition to characterization of baking conditions during industrial cake baking, some important quality parameters, such as texture, color, density and viscosity of the cake batter were evaluated during baking in two different multi-zone industrial scale ovens: gas fired band oven and electric powered mold oven. The flow behavior of all batters was pseudo-plastic with a yield stress. The average moisture removal rates (3.59×10⁻⁴–1.40×10⁻³ kg H₂O/kg solid s) of cakes fell between those of cookies and breads. During baking, pH increased and then decreased at the late stage of baking. Batter positions (side or center) on the band were not critical for quality parameters with the exception of moisture content. Most color changes occurred 1/4–3/4 way through the baking. After 21 days of storage, the hardness of all cakes increased 1.8–3 times the original value.     

Use of applied air pressure to improve the baking properties of whey protein isolates in angel food cakes

Whey protein isolate (WPI) possesses limited application in angel food cake baking compared to liquid egg white (LEW). This study was conducted to determine whether applying air pressure in the oven during baking would improve the baking properties of WPI in angel food cakes. A special oven was designed for baking at oven air pressures up to 1.5 bar. Control angel food cakes were formulated with LEW (100/0) as its protein source and WPI-containing cakes were formulated with a mixture of 75 mL/100 mL LEW and 25 mL/100 mL WPI solution (75/25) or a mixture of 50 mL/100 mL LEW and 50 mL/100 mL WPI solution (50/50). Cakes were baked at atmospheric air pressure (AP) and at constant applied air pressure (CAP) or variable applied air pressure vs. baking time (VAP) to prevent overexpansion and collapse of WPI-containing cake batter. Cakes 75/25 and 50/50 baked at VAP exhibited improved physical, textural and sensory properties compared to those baked at AP or CAP conditions. Cakes 75/25 baked at VAP compared well with control angel food cakes baked at AP. Although 50/50 cakes baked at VAP were improved slightly over those baked at AP, none of them exhibited satisfactory properties. Therefore, additional research is needed to optimize baking conditions for cakes formulated with less than 75 mL/100 mL LEW.     

Effect of Fermentation and Drying on Procyanidins, Antiradical Activity and Reducing Properties of Cocoa Beans

This work was aimed to determine the effect of fermentation and drying on the content and profile of procyanidins (from monomers P1 to polymers P10) as well as on the antiradical and scavenging properties of cocoa beans. To this purpose, three experiments were carried out: a traditional fermentation process followed by air drying and two pilot-scale fermentation processes by either natural microbiota or starter followed by sun drying. Procyanidins were evaluated by HPLC analysis, while the total polyphenol index (TPI), the antiradical activity as well as the reducing power were determined by means of the reaction with the Folin–Ciocalteu reagent, the decolorization assays of the ABTS radical (TEAC) and the Ferric Reducing Antioxidant Power (FRAP) methods, respectively. Both the traditional and pilot-scale processes resulted to affect the profile and content of the procyanidins fractions as well as the antiradical and reducing power functionality. Drying caused a severe reduction of compounds and thus resulted to be the critical step for the loss of procyanidins and monomers in particular. The indices of functionality generally showed a decreasing trend as a consequence of processing, and their evolution was similar to that observed in procyanidins content. To study the relationship between the individual procyanidins and the antioxidant activity expressed as TEAC, FRAP and TPI, the data set were processed by modified partial least squares regression. The obtained models presented a good predictive ability. Normalised regression coefficients showed that the relative contribution of each single class of compounds to total antioxidant activity resulted as follows: P1?>?P2?>?P3?>?P4?>?P6?>?P8?>?P5?>?P7?>?P9?>>?P10.     

Effect of baking method on some characteristics of starch in pound cake crumbs

BACKGROUND: The effect of the baking process (microwave versus conventional oven) on some starch characteristics of pound cake was evaluated. Proximal chemical analysis, total resistant starch (RS), retrograded resistant starch (RS3), differential scanning calorimetry (DSC), and X‐ray diffraction (XRD) were evaluated. Pound cake, one of the major products of Mexico's bread industry, was selected for analysis because the high moisture and fat content in the beaten dough might reduce the quality defects often associated with microwave baking. RESULTS: Crumbs from microwave‐baked pound cakes contained lower moisture than crumbs from conventionally baked pound cake. Lower RS was observed in fresh microwave‐baked than conventionally baked pound cake. RS3 increased significantly in conventionally baked products stored for 8 days at room temperature, whereas slightly lower changes in RS3 were observed in the microwaved product. DSC revealed less gelatinisation in microwaved pound cake which is related to limited water availability during the microwave heating process. The crystallinity peaks present in conventionally baked pound cake might be associated with RS3 content; the resistant retrograded starch formed during storage, is reflected in the XRD pattern. CONCLUSION: Microwave‐baked pound cake crumbs showed less gelatinisation than conventionally baked pound cake crumbs. Copyright © 2007 Society of Chemical Industry     

Effect of flour extraction rate and baking process on vitamin B1 and B2 contents and antioxidant activity of ginger-based products

The effect of flour extraction rate and baking on thiamine (vitamin B₁) and riboflavin (vitamin B₂) content and antioxidant capacity of traditional ginger cake was studied and then compared to white wheat bread. Ginger cake was formulated either with whole-grain (100% extraction rate) or with brown (92% extraction rate) rye flour and baked at 180 °C for 18 min. The antioxidant capacity was evaluated in terms of radical scavenging activity against peroxyl (ROO·) and superoxide anion radicals (O ₂ ^·? ). Thiamine content in rye doughs (F-100% and F-92%) was found to be 38% lower when compared to wheat dough. In contrast, whole-grain and brown rye doughs exhibited an almost fourfold higher riboflavin content than wheat dough. Rye dough baking led to reductions in thiamine (from 53 to 65%) and riboflavin (from 69 to 71%) contents. Likewise, thiamine and riboflavin contents in wheat dough were also reduced (56 and 10%, respectively) after baking; however, ginger cake with whole-grain rye flour exhibited significantly higher thiamine and riboflavin contents. Rye doughs and ginger cakes showed higher scavenging activities against ROO· radicals when compared to that of wheat dough and bread. Thus, baking significantly enhanced ROO· scavenging properties of ginger cakes while only a slight increase was observed in wheat bread. In contrary, baking gave rise to a decrease in SOD-like activity both in ginger cake or wheat bread. Our findings suggest that formulation with whole-grain rye flour can potentially increase B₁ and B₂ vitamin contents as well as the ROO· scavenging capacity of traditional ginger cake.     

Occurrence of ochratoxin A in cocoa by-products and determination of its reduction during chocolate manufacture

This work reports an investigation carried out to assess the natural occurrence of ochratoxin A in 168 samples from different fractions obtained during the technological processing of cocoa (shell, nibs, liquor, butter, cake and cocoa powder) and the reduction of ochratoxin A during chocolate manufacture. Ochratoxin A analyses were performed with immunoaffinity columns and detection by high performance liquid chromatography. Concerning the natural ochratoxin A contamination in cocoa by-products, the highest levels of ochratoxin A were found in the shell, cocoa powder and cocoa cake. The cocoa butter was the least contaminated, showing that ochratoxin A seems to remain in the defatted cocoa solids. Under the technological conditions applied during the manufacture of chocolate in this study and the level of contamination present in the cocoa beans, this experiment demonstrated that 93.6% of ochratoxin A present in the beans was reduced during the chocolate producing.     

Effect of oven temperature profile and different baking conditions on final cake quality

This study discusses the effect of airflow on oven temperature profiles, the internal cake temperature and the final cake quality. It was found that the presence of airflow reduced the oscillation in the oven temperature profile from 12.98–30.27% to 3.17–4.02%. The bottom of the oven chamber experienced the greatest reduction in temperature oscillation in the presence of airflow. During the second stage of baking with airflow, the heating rate was increased from 5.07 to 7.52 °C min^?1 and 8.35 °C min^?1 to the increase of the baking temperature from 160 to 170 °C and 180 °C, respectively. The cake volume expansion rate was also increased 5–10% during second stage when baking with airflow condition. The cakes baked in the presence of airflow had a more porous crumb texture and lower moisture content compared to the cakes baked without airflow.     

Optimization of microwave baking of model layer cakes

 Response surface methodology was used to optimize the formulation of microwave-baked cakes. The independent variables were water content, emulsifier content baking time, oven power, shortening content and starch type. The quality factors evaluated were specific gravity of batter and volume index, uniformity index and tenderness of the crumb. Constraints for quality factors were obtained by conventional baking of American Association of Cereal Chemists high-ratio cake formulation. Multiple contour plots showed the optimum region for various water and shortening combinations at different emulsifier, time and power levels. Cakes formulated with wheat starch, containing 0.3% polysorbate 60, 133.7% water and 45.2% shortening (flour substitute basis), baked for 6 min at 100% power yielded acceptable cakes that can compete with conventionally baked cakes. Rice and corn cakes had lower quality than conventionally baked high-ratio cakes. Power was found to be the most efficient independent variable affecting all the dependent variables. Received: 26 August 1999 / Revised version: 11 October 1999     

D-最优混料与响应面法优化甜茶无糖抗氧化活性蛋糕配方

为满足市场对新型烘焙功能食品的需求,研制无糖、低热量、富含纤维且具有抗氧化特性的蛋糕。本实验采用D-最优混料设计研究葛根粉、南瓜粉和低筋粉3种主要原料的不同配比对蛋糕感官品质的影响,以甜茶提取液替代砂糖作为甜味剂,采用单因素及响应面试验优化加工工艺,考察甜茶添加量、甜茶提取液体积和泡打粉添加量对蛋糕感官品质及质构特性的影响。结果表明:蛋糕主要混合原材料最优配方为葛根粉43%、南瓜粉 20%、低筋粉37%;甜茶添加量4.3 g、甜茶提取液体积30.0 mL、泡打粉2.5 g。该混料配方及制作工艺生产的蛋糕感官评分为 87.36分,总酚含量为629.1 mg/100 g,总黄酮含量为564.5 mg/100 g,总抗氧化能力为396.7 mg/100 g,为功能性营养蛋糕开发提供了新途径。