钢铁表面黑色转化膜处理技术

黑色转化膜技术是目前较为先进的钢铁表面处理技术 ,本文试验研究了一种新工艺 ,提出了TB值的概念 ,通过控制TB值即可控制处理液的质量 ,获得性能优良的转化膜。此工艺性能可靠 ,可操作性强 ,并可应用于激光热处理前的预处理。     

Direct electroless Ni-P deposition on AM50 magnesium alloy from sulfate bath

A bright electroless Ni-P deposition on AM50 magnesium alloy in a sulfate plating bath was proposed by using direct plating process with non-chromate pretreatment. The electroless Ni-P plating on AM50 magnesium alloy has an admirable appearance and good adhesion. The results indicate that the electroless Ni-P deposition with non-chromate pretreatment has better adhesion than that of zinc immersion coating. Anodic polarization curves indicate that the electroless Ni-P deposition obtained from the sulfate bath has similar corrosion-resistance to that obtained from basic nickel carbonate bath. The deposition process generates less pollutant by a non-chromate plating bath and is suitable for the magnesium alloys manufacture because of its low cost. The hardness of the electroless Ni-P plated AM50 is about HV 720.6 and HV 969.7 after heat treatments at 180℃ for 2 h. The wear resistance of Ni-P plated magnesium alloy specimens is about 5 to 9 times as high as that of bare magnesium alloys.     

混合稀土及半固态等温热处理对原位Mg_2Si/Al复合材料组织与性能的影响

在原位Mg2Si/Al复合材料中,通过混合稀土变质及半固态等温热处理,分析变质及等温热处理后材料组织与力学性能的变化。结果表明:添加0.8%的混合稀土对Mg2Si起到很好的变质效果,初生Mg2Si的形貌由变质前的粗大十字状变为均匀分布的不规则块状,平均尺寸由变质前的74μm减小至24μm左右;同时,材料的力学性能也显著提升,抗拉强度由变质前的134 MPa提高至187.5 MPa,布氏硬度由HB 74.5提升至HB 89.5左右。最佳的等温热处理工艺为600℃保温90 min,此时,材料中初生Mg2Si转变为近球形,其形状因子为0.93左右,平均尺寸29μm左右。     

原位20Mg_2Si/Al复合材料变质工艺优化

通过正交试验,对原位20Mg2Si/Al复合材料中的初生Mg2Si进行变质处理。结果表明,最佳的工艺参数是:P的加入量为0.03%,混合稀土的加入量为0.4%,变质温度为780℃,变质时间为30min。在影响变质效果的因素中,P的加入量对变质效果影响最大。混合稀土、变质温度和变质时间对试验有一定的影响。     

P和稀土复合变质的Mg_2Si/Al半固态组织与性能

在原位Mg2Si/Al复合材料中,通过P和混合稀土复合变质及改变半固态等温热处理的保温温度和保温时间,研究了复合变质及等温热处理对合金组织与力学性能的影响。结果表明,P和混合稀土联合变质后初生Mg2Si的形貌由粗大的十字状结构转变为不规则的多边形,均匀分布在铝基体上。初生相颗粒尺寸由未变质前的83μm减小到约17μm;经过570℃×90min半固态等温热处理后,初生Mg2Si相和α-Al相均转变为近球形,初生Mg2Si相形状因子约为0.96,平均等积圆直径约为16μm,此时材料的硬度(HB)达到最大值,为106。     

镁合金轮椅小轮轴套焊接结构改进

研究了镁合金轮椅小轮轴套焊接部位的结构,改变了焊道的部位和方向,大大降低了焊接部位应力集中,有效地提高了焊接部位的疲劳强度。结果表明:焊道长度与疲劳性能有一定的关系,当焊道长度大于25 mm时,其疲劳寿命可达21万次以上,根据GB/T13800-2009标准测试满足轮椅的使用要求。     

电流密度对纳米锌镍合金镀层显微组织的影响

采用适当的添加剂在碱性体系中获得了晶粒度为14—33 nm的纳米锌镍合金电镀层。并应用赫尔槽试验、透射电镜(TEM)、扫描电镜(SEM)和X射线衍射(XRD)等技术研究了电流密度对镀层晶体结构的影响。结果表明,在该体系中,在电流密度为0.5—50 A/dm2得到的纳米锌镍合金镀层均为单一的γ-相(N i5Zn21)结构。随电流密度的增加,在低电流密度区镀层的晶粒度由33 nm迅速降至17 nm,在中高电流密度区晶粒度保持在14—17 nm。另外,镀层中还存在亚微米级晶粒团簇,其尺寸随电流密度的增加呈线性增大。     

Influence of sodium metanitrobenzene sulphonate on structures and surface morphologies of phosphate coating on AZ91D

1 Introduction Recently many researches on light alloys have focused on magnesium alloy such as AZ31[1?3], AZ91[4?8] and AM60[9,10]. Many surface treatment coatings, including chemical conversion coating [3, 5, 11?13], anodizing[2,14,15], plating[16?19] …     

镁表面防腐蚀植酸处理方法

采用浸渍法,室温下在以植酸为主要成分的水溶液中制备了镁表面的耐蚀性转化膜,膜层制备后自然沥干,不需水洗.整个工艺过程中无废水及废气排放.利用正交试验分析了多因素对镁植酸转化膜耐蚀性影响,探明了膜层形成的最佳条件.结果表明,在处理液中主要成分植酸的质量分数为3%、pH值2.5～3.5、反应时间7 min的条件下制备的膜层具有最佳的性能,并对膜层的微观形貌进行了表征.环境友好型防腐蚀植酸处理技术有望成为新的镁表面防腐处理技术.     

Improvement of anticorrosion and adhesion to magnesium alloy by phosphate coating formed at room temperature

A new surface protection process was developed to magnesium alloy against corrosion in aggressive environments. Firstly, a phosphate coating was formed on rinsed magnesium alloy. Then, powder painting was carried out on the phosphated magnesium alloy. Surface morphologies and phase compositions of the phosphate coating were investigated by X-ray diffraction （XRD） and scanning electron microscope （SEM）. The results show that the phosphate coatings formed in bath containing earth additives at room temperature have dense and fine microstructure. The phosphate coating provides excellent paint adhesion to the magnesium alloy. Salt spray tests indicate that the corrosion resistance of the phosphate coating plus paint could meet the demand of magnesium alloy automobile components in aggressive environments.