Effects of (Li0.5Sm0.5)/W co-substitution and sintering temperature on the structure and electrical properties of ultrahigh Curie temperature piezoceramics,Ca0.92(Li0.5Sm0.5)0.08Bi2Nb2-xWxO9

With co-substitution of (Li_0.5Sm_0.5) at A site and W at B site, the electrical properties of modified Ca_0.92(Li_0.5Sm_0.5)_0.08Bi₂Nb_2-xW_xO₉ [(CLS)BN-xW, x = 0, 0.015 and 0.03] piezoceramics with ultrahigh Curie temperature (T_C) of > 930 °C were enhanced dramatically. The increased resistivity induced by the co-substitution ensure them to be polarized under an enough high field. Combined with the increase of spontaneous ferroelectric polarization (P_S), the significant enhancements in the piezoelectric, dielectric and ferroelectric properties can be obtained in the composition x = 0.015. Furthermore, the piezoelectric activity (d₃₃) and bulk resistivity (ρ_b) of (CLS)BN-0.015 W can be further enhanced at an appropriate sintering temperature. This optimum composition sintered at 1170 °C shows ultrahigh T_C of ～948 °C, d₃₃ of ～17.3 pC/N and ρ_b of ～6.9 MΩ cm at 600 °C, which are comparable to those of the reported high-temperature Aurivillius piezoceramics with T_C > 850 °C.     

Constructing magnetically recoverable CdS/CaFe2O4 P–N heterojunctions for enhanced photoelectrochemical properties towards H2 evolution reaction

A novel CdS/CaFe₂O₄ (CS/CFO) heterogeneous p-n junction was created by thermal deposition of CaFe₂O₄ nanoparticles on CdS rods. The CS/CFO hetero-structured photocatalysts exhibited increasingly efficient visible light harvesting compared to the bare CdS. The CS/CFO composites also presented higher photocurrent and slower decay of photoluminescence, suggesting a better separation of the photo-generated electrons and holes. The photocatalytic H₂ evolution quantity on the optimized CS/CFO composite from water in the presence of ethanol was up to 2200 μmol after 3-h visible light illumination, which is more than twice that of the pristine CdS. The chemical interaction between CdS and CaFe₂O₄ was confirmed by the shifts in the XPS peaks, which made it possible for the charge carriers to transfer across the p-n junction interface. This research highlights the importance of forming an interfacial p-n heterojunction between two semiconductors for efficient charge separation and improved photocatalytic performance.     

基于TRNSYS的茯砖茶生产工艺能源系统节能环保特性研究

茯砖茶发酵、干燥过程中，烘房内温湿度稳定性和能源系统低能耗是保证茯砖茶品质与成本的重要因素。本文采用TRNSYS仿真与实验研究相结合的方法，对咸阳某茯砖茶厂实际使用的空气源热泵系统进行建模，通过研究各季节典型代表月烘房温湿度的波动情况，确定该空气源热泵系统在全年的运行状态是否满足工艺要求，在此基础上，对比了该系统在全年可运行季节代表月与该生产厂房早期使用的燃气锅炉系统的能耗仿真结果，对空气源热泵系统的节能与环保特性进行研究。结果表明：由于夏季送风质量流量过大且室外空气含湿量较高，7月烘房温湿度不满足工艺要求。热泵系统在1、4、10月的总标煤消耗量的平均值是锅炉系统的44.42%，平均CO2、SO2、NOx排放量分别为锅炉系统的34.13%、44.1%、40.60%。在茯砖茶发酵、干燥的过程中，相比于燃气锅炉系统，空气源热泵系统具有更好的节能与环保特性。     

DCS分布式冷却系统在通信基站的应用研究

针对基站柜式空调耗电量大的问题,创造性地使用基站分布式冷却的方式,达到精确送风,节能高效的目的.在应用实践中检验了分布式冷却系统实际节能量和应用效果,总结出分布式冷却系统应用场景和范围,为更大范围推广应用DCS分布式冷却系统提供实践依据.     

Broad-Spectral-Range Sustainability and Controllable Excitation of Hyperbolic Phonon Polaritons in α-MoO3

Hyperbolic phonon polaritons (HPhPs) in orthorhombic-phase molybdenum trioxide (α-MoO₃) show in-plane hyperbolicity, great wavelength compression, and ultralong lifetime, therefore holding great potential in nanophotonic applications. However, its polaritonic response in the far-infrared (FIR) range remains unexplored due to challenges in experimental characterization. Here, monochromated electron energy loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM) is used to probe HPhPs in α-MoO₃ in both mid-infrared (MIR) and FIR frequencies and correlate their behaviors with microstructures and orientations. It is found that low structural symmetry leads to various phonon modes and multiple Reststrahlen bands (RBs) over a broad spectral range (over 70 meV) and in different directions (55–63 meV and 119–125 meV along the b-axis, 68–106 meV along the c-axis, and 101–121 meV along the a-axis). These HPhPs can be selectively excited by controlling the direction of swift electrons. These findings provide new opportunities in nanophotonic and optoelectronic applications, such as directed light propagation, hyperlenses, and heat transfer.     

广东早期砖薄壳结构的建构技术研究——1957-1958年新会的"逼拱"实验

揭示1957-1958年华南工学院土木系薄壳结构研究小组在新会的砖薄壳结构实验图景.以田野调查、文献分析、三维图示、超声波检测等方法发现、确认此研究小组在新会的6处薄壳建筑及其遗存情况.它们是广东地区推广砖薄壳建筑的起点,其中的回旋砖薄壳实验是从结构角度探索中国建筑民族形式的重要案例,弥补国内结构工程史学研究的薄弱点,也是共和国早期节约"三材"约束下的薄壳建造技术自主创新设计的重要内容.     

基于SCAE⁃ACGAN的直升机行星齿轮裂纹故障诊断

直升机行星传动轮系结构复杂、工况多变,其振动信号受工况影响大,在故障样本较少的情况下导致行星齿轮箱故障诊断准确率不高,早期故障诊断困难。针对上述问题,提出将堆栈收缩自动编码网络(stacked contractive autoencoder,简称SCAE)与辅助分类生成式对抗网络(auxiliary classifier generative adversarial networks,简称ACGAN)相结合的SCAE-ACGAN故障诊断方法。ACGAN的生成器产生与真实样本具有类似分布的生成样本,扩展训练样本集,并与真实样本一起输入至判别器进行训练。ACGAN采用SCAE作为判别器,利用SCAE良好的抗数据波动能力,从扩展样本集中挖掘出有效的深度特征,并实现样本的真伪与类别的判定。ACGAN的判别器和生成器在对抗学习训练机制下交替优化,提高方法的样本生成质量与故障判定能力。将SCAE-ACGAN应用于直升机行星轮裂纹故障诊断,结果表明,SCAE-ACGAN的故障诊断性能好,在样本数量少与工况变化情况下具有较好的健壮性和适应性。     

用于疏浚工程泥浆密度测量的电阻层析成像技术

江河湖海疏浚工程对于拓展和保障航运安全、促进生态恢复、维护/改善远海岛礁环境具有不可或缺的作用.目前,在绞吸和耙吸疏浚船上,多采用射线密度计及电磁流量计对输泥密度、产量等进行在线计量,并作为实现疏浚系统自动控制的重要参量.由于射线密度计潜在的人员健康、公共安全和环保风险,在一些国家和地区已建立了放射源的有序退出机制.电阻层析成像使用安装于管壁的电极阵列获得管道内流体的电导率分布,进而推导出管道内的泥浆密度,具有无辐射、全场测量及实时可视化的优点.电阻层析成像测量系统经过特殊设计,可适应从内陆淡水到海水的巨大电导率变化.初步测试表明,电阻层析成像测量数据与射线密度计具有良好一致性,具备了作为在线泥浆密度测量的可行性.此外,ERT可提供实时的流动成像,对于提高对疏浚管道监测能力和降低堵管概率具有重要意义.