A highly active composite electrocatalyst Ni–Fe–P–Nb2O5/NF for overall water splitting

This work demonstrates a facile Nb₂O₅-decorated electrocatalyst to prepare cost-effective Ni–Fe–P–Nb₂O₅/NF and compared HER & OER performance in alkaline media. The prepared electrocatalyst presented an outstanding electrocatalytic performance towards hydrogen evolution reaction, which required a quite low overpotential of 39.05 mV at the current density of ?10 mA cm^?2 in 1 M KOH electrolyte. Moreover, the Ni–Fe–P–Nb₂O₅/NF catalyst also has excellent oxygen evolution efficiency, which needs only 322 mV to reach the current density of 50 mA cm^?2. Furthermore, its electrocatalytic performance towards overall water splitting worked as both cathode and anode achieved a quite low potential of 1.56 V (10 mA cm^?2).     

新型工程轮胎定型硫化机的设计

介绍了一种新型液压定型硫化机的结构,对一些形状复杂、受力苛刻的零件进行了有限元力学分析,使设计的零件参数更合理,结构更加紧凑,机器的使用性能更好。     

数字式静态应变测量实验系统的设计

数字式静态应变测量实验系统一改传统应变仪使用机械开关转换通道的设计模式,采用现代电子模拟开关技术,彻底解决了预调平衡工作中长期难以解决的问题.具有稳定性好、分辨率高、精度高、操作简单等特点,适合于初学者使用,是新一代的应力、应变测试及数据处理强有力的工具,提高了工作效率.     

液相中气泡上升行为与界面传质:实验研究与数值计算

在工业生产过程中，气泡在液相中的上升行为及气液界面的传质行为极为常见。本文针对不同条件下气泡上升过程的实验研究方法以及数值计算方法进行了总结。从实验与数值计算的角度，综述了单气泡上升过程的影响因素、多气泡上升过程聚并与破裂的现象和机理以及工业装置中气液两相流型和气泡特性，并对传质模型进行了归纳，主要关注了气侧-界面传质模型的研究现状。综述结果表明：当前对于单气泡上升行为的研究较为充分，而对于多气泡的行为机理的研究尚需深入。此外，受到研究手段的限制，进行气侧-界面传质模型研究具有一定挑战性。针对当前的相关研究进展和存在的问题，对今后气泡上升行为和传质行为的研究提出以下建议，即开展气泡聚并与破裂可控性研究，强化对气侧-界面传质过程的研究，包括泡内流体行为可视化研究和相关传质模型的建立。     

ZnO／Ag纳米复合材料光催化性能研究

通过XRD、TEM测试研究了自制ZnO／Ag纳米复合材料的结构和形貌，通过UV检测确定了以该纳米复合材料为光催化剂，在不同条件下对甲基橙的光催化降解率。结果表明：与空气煅烧相比，真空煅烧所得纳米复合材料的光催化降解效果更好，且光催化降解率随纳米复合材料用量增加而增大：甲基橙溶液的pH在5左右时，光催化降解率最高：H2O2浓度为0．9g／L时，光催化降解率可达100％。     

纳米硫化铋-锌复合镀膜的制备及其抗菌性能研究

目的将锌镀层与具有光催化抗菌性能的纳米粒子复合,实现对锌镀层的改性,成功制备一种具有光催化抗菌性能的功能性复合镀层。方法通过向弱酸性硫酸盐锌镀液中加入梯度浓度具有可见光催化杀菌性能的硫化铋纳米粒子,在20#碳钢表面利用恒电流法一步成功制备了系列硫化铋-锌复合镀膜。利用电化学工作站监测了沉积过程中的沉积电位,分别记录沉积前和沉积后的样品质量并测量沉积面积,通过计算,确定了沉积过程的电流效率。通过扫描电子显微镜(SEM)、X-射线晶体衍射仪(XRD)及电子能谱仪(EDS)对镀层进行了形貌及成分分析,采用大肠杆菌作为代表性的细菌,检测了复合镀膜的抗菌性能。结果与纯锌镀膜相比,硫化铋的加入显著促进了(100)晶相的晶体生长,而抑制了(102)晶相的晶体生长,使镀膜形貌由标准六方晶系变为块状晶体;硫化铋的加入使沉积电位变得更正,且随硫化铋添加量的增加,变正增幅变大;硫化铋的加入使电沉积过程的电流效率与纯锌镀膜的电流效率相比增大了5%左右,但硫化铋的添加量对电流效率的影响不大;硫化铋-锌复合镀膜在可见光下对大肠杆菌具有良好的抗杀性能,且硫化铋的复合量越高,抗菌效果越好。结论通过笔者提出的电沉积方法,硫化铋可成功复合到了锌镀膜中,从而使硫化铋-锌复合镀膜获得了良好的抗菌性能,最终发现当镀液中硫化铋质量浓度为2 g/L时,硫化铋在锌镀层中的复合量最高,抗菌性能最好。     

工艺参数对合成ZnO／Ag纳米复合抗菌剂产率的影响

通过正交实验，研究了反应温度、反应时间、反应物配比对ZnO／Ag纳米复合抗菌剂合成产率的影响规律。获得了高产率合成ZnO／Ag纳米复合抗菌剂的优选工艺条件：反应温度为10～25℃，ZnSO4与NH4HCO3的摩尔比为1：2-2．5，ZnSO4与NH4HCO3的反应时间为2．5～3h，AgNO3与NH4HCO3的摩尔比为1：1．5～2，反应时间为0．5h，ZnO／Ag的产率超过98％。XRD、TEM和SAED结果表明：ZnO／Ag纳米复合抗菌剂为具有纤锌矿结构的ZnO和立方结构的Ag组成。粒径为15～25nm，分散性较好。     

Robust tracking control for operator-based uncertain micro-hand actuator with Prandtl–Ishlinskii hysteresis

Since the hysteresis property inherently exists in the rubber material, it is necessary to deal with the control issues for the micro-hand by considering the hysteresis property. Therefore, in this paper, the robust tracking control for the micro-hand systems is discussed from the aspect of the Prandtl–Ishlinskii hysteresis property which is more applicable for the real applications. Firstly, a new model is obtained by combining the dynamic model of the micro-hand with Prandtl–Ishlinskii hysteresis property. Secondly, a new stability condition based on bounded input and bounded output stability is proposed for the Prandtl–Ishlinskii hysteresis modeled micro-hand system from two different cases. Thirdly, by designing the robust controllers based on the internal model control method, the tracking performance can be improved by eliminating the effect from the disturbance. Finally, simulation is used to further demonstrate the effectiveness of the proposed design scheme.     

基于SVM的大鱼际掌纹图像二分类法

提出一种基于支持向量机(SVM)的大鱼际掌纹图像二分类法。采用高频强调滤波,对分割得到的大鱼际掌纹图像进行图像增强,提取其灰度共生矩阵4个方向的8个特征量作为分类特征向量。对比不同核函数下的分类准确率,结果表明,组合特征向量的SVM方法对大鱼际掌纹的初步二分类效果较好。     

Using social media to enrich information systems field trip experiences: Students’ satisfaction and continuance intentions

A well-designed field trip can promote active learning and reinforce classroom materials. Few studies have examined the potential for social media to enhance IS field trip experiences by promoting active and collaborative learning. One major barrier to the exploitation of this potential is the lack of the adoption of social media by students as a learning tool to enhance field trip experiences. Therefore, the first task is to understand how to increase the satisfaction of students in their use of social media to enhance IS field trips. This research sets out to understand the factors that could help increase students’ satisfaction with the use of social media to enhance IS field trips, and thereby their intentions to continue to use social media in future field trips. The results show that to increase user satisfaction, course instructors should ensure that students perceive the social media sites used for enhancing field trip study to be trustworthy, effortless, useful and accepted by their peers. Future research could determine how we can incorporate the use of social media to enhance the field trip learning experience.