GD-OES study on oxidation behavior of FeMnAlC TWIP steel sheets during heating

The oxidation behavior of Fe-16%Mn-1.5%Al-0.6%C-0.11%Cr TWIP steel sheet during heating process was studied by simulation experiments. The effects of heating temperature and O2 content in heating atmosphere on the depth distribution of surface elements were analyzed by GD-OES. When TWIP steel sheet is heated to 550-700℃ in the atmosphere of N2-0.05 vol%O2, an oxide layer composed of Fe, Mn and O covers the surface, a Mn depleted zone, a decarburized zone and an internal oxidation zone will be formed in the subsurface layer. The thicknesses of the oxide layer and the subsurface zones increase with heating temperature increasing. When being heated in an oxidizing atmosphere, Al preferentially forms internal oxidation in the subsurface layer, and a small amount of Cr forms external oxidation at the oxide layer/matrix interface. The surface oxide layer basically contains no Al and Cr. When the heating temperature is 650℃, the change of O2 volume fraction in the atmosphere between 0.025%-0.20% has little effect on the thickness of the oxide layer, and the oxide layer with a thickness of 400-500nm can be obtained. In order to obtain the appropriate thickness of the pre oxide layer of TWIP steel and reduce the oxide at the interface between the pre oxide layer and matrix interface, the temperature control of the direct fire heating outlet is more important than the air-fuel ratio control.     

热镀锌TRIP钢还原铁/基板界面表征

预氧化还原工艺是改善热镀锌先进高强钢(AHSS)可镀性的有效手段之一。当它用于生产热镀锌先进高强钢时,有时也会出现镀层附着性不良的问题。为了明确还原铁/基板界面对热镀锌高强钢镀层附着性的影响,以预氧化还原工艺生产的、镀层附着性不同的热镀锌TRIP钢为研究对象,采用GDOES、SEM、FIB、TEM等手段研究了还原铁/基板界面位置的微观特征。结果表明,镀层附着性不良表现为150～300 nm厚的还原铁层与镀层一起从基板表面脱落,失效发生在还原铁/基板界面,而非镀层/还原铁界面,与常见的镀层/基板界面Fe₂Al₅抑制层缺失引起的镀层附着性不良明显不同。镀层附着性不同的试样在还原铁/基板界面位置均存在硅、锰元素富集,但硅、锰富集程度有差异,镀层附着性不良试样的界面硅、锰富集更高。还原铁/基板界面氧化物形态显著影响了还原铁/基板界面的结合力,当还原铁与基板之间形成连续的氧化膜时,界面结合力较差,易发生界面分离;当还原铁/基板界面形成细小的、不连续的氧化物颗粒时,界面结合力较好。在对热镀锌先进高强钢实施预氧化还原工艺时,为了获得良好的还原铁/基板界面结...     

非钙处理对高等级齿轮钢夹杂物的影响

 为解决水口堵塞、B类夹杂物超标及控制Ds类夹杂物,通过热力学计算和工业试验研究了SCr420H齿轮钢钙处理与非钙处理对中间包夹杂物的影响。研究发现,非钙处理炉次中间包夹杂物数量低于钙处理炉次。非钙处理炉次中间包夹杂物主要为棱角状镁铝尖晶石;钙处理炉次夹杂物主要为Al₂O₃-CaO-MgO与CaS复合球状夹杂物。优化工艺后非钙处理炉次中间包高熔点尖晶石类夹杂物数量大幅降低,水口堵塞及B类夹杂物问题得到解决。非钙处理圆钢夹杂物评级结果为,A类不大于0.5,B类不大于0.5级,C类为0,D(细)类不大于1.0级,D(粗)类不大于0.5级,Ds类不大于1.0级。     

超高强梁零件筋槽的辊冲成形工艺分析

辊冲成形工艺为一种新型成形工艺,该工艺兼具辊压和冲压特点,特别适合超高强、尤其是超高强变截面梁类零件的生产。筋槽是汽车零部件中常见的局部形状,在各类纵梁、加强梁等零件上用于装配定位、避让和加强刚度。针对筋槽的辊冲成形,选取了平底筋槽和圆底筋槽两类典型的筋槽形状,基于ABAQUS软件平台,建立了筋槽辊冲成形仿真分析模型,并对不同尺寸筋槽的辊冲成形进行了对比分析,结果表明,当筋槽圆角半径增大时,辊冲成形过程最大Mises应力、最大应变和最大减薄率均减小;采用辊冲成形工艺,两类筋槽安全成形的最小圆角半径分别为8mm和4mm。     

轧制温度对GCr15轴承钢组织性能的影响

在Gleeble-3500热模拟试验机上对GCr15钢试样进行了双道次热压缩,模拟其在预精轧与精轧阶段在不同温度下的组织演变过程。同时设计了特殊GCr15钢试样,可在Gleeble-3500上双道次压缩试验后,再加工成拉伸样,得到相应压缩条件下试样的拉伸性能。采用光学显微镜、扫描电镜(SEM)和拉伸试验机等观察测试了不同压缩温度条件下GCr15钢试样的组织形貌及拉伸性能。结果表明:当精轧温度为800~850℃时,GCr15钢试样可获得珠光体团直径较小、渗碳体片层较细、网状碳化物较少的组织;拉伸试验表明,精轧温度为800℃时,GCr15钢试样的抗拉强度达到最大,温度低于800℃和高于800℃时,抗拉强度逐渐降低。     

Characterization of the Trace Phosphorus Segregation and Mechanical Properties of Dual-Phase Steels

The segregation behavior of trace amount of phosphorus (P) and the mechanical properties of dual-phase (DP) steels have been systematically studied. The microstructure of DP steels is mainly composed of martensite, ferrite and nanoscale carbides. For the DP steels with different trace amounts of P (≤ 0.015 wt%), P has almost no effect on the mechanical properties. Atom probe technology (APT) analyses confirm that P segregation was only found at the precipitate/matrix interface. Moreover, the precipitates of (Ti, Mo) C are widely distributed in the ferrite, martensite and ferrite/martensite interface regions. The special segregation feature of P would not concentrate at specific regions such as ferrite/martensite interface and/or martensite lath interface, which reveals that trace amounts of P (≤ 0.015wt%) have almost no effect on the mechanical properties of DP steels. It is proved for the first time that the MC-type carbides of (Ti, Mo) C can reduce or eliminate the damage effect of P on the mechanical properties of steels, which provides a new way for the design of alloys to reduce P damage. This work will promote to increase the P content control standard in DP steels from 0.01 to 0.015 wt%, which will not change the mechanical properties, but greatly reduce the scrap rate and increase the energy efficiency of the manufacturing process.     

热浸镀Zn-11Al-3Mg镀层黑点缺陷形成机理研究

目的 研究Zn-11Al-3Mg镀层黑点缺陷位置与正常位置组织特征差异,阐明黑点缺陷的形成机理,寻找导致黑点缺陷的原因,从而控制和消除黑点缺陷。方法 以工业生产的Zn-11Al-3Mg镀层钢板表面的黑点缺陷为研究对象,综合运用光学显微镜(OM)、扫描电镜(SEM)、能谱仪(EDS)、双束聚焦离子束显微镜(FIB-SEM)等,详细对比了缺陷位置和正常位置镀层显微组织的差异,分析了引起镀层组织差异的根本原因,揭示了Zn-11Al-3Mg镀层表面黑点缺陷的形成机理。结果 Zn-11Al-3Mg镀层组织由初生Al枝晶和枝晶间第二相组成,缺陷位置和正常位置枝晶间第二相显微组织存在明显差异,宏观上表现为局部黑点缺陷。缺陷位置枝晶间第二相的平均成分与原始镀液成分接近,组织为细小的颗粒状Zn/Al/MgZn₂三元组织,未出现明显的Zn/MgZn₂二元共晶;而正常位置枝晶间第二相由大量的层片状Zn/MgZn₂二元共晶及少量Zn/Al/MgZn₂三元共晶组成。造成上述镀层组织差异的根本原因是镀后凝固过程中冷却速率不均匀...     

硼对铬锰钼系含硼调质钢淬透性的影响

摘要：以实验室冶炼的铬锰钼系含硼调质钢为材料,通过末端淬火实验和微观组织分析,研究了硼元素对铬锰钼系含硼调质钢淬透性的影响。结果表明,硼元素对实验钢所表现的淬透性效果,仅在一定的区间（J11~J40）内作用明显,在这个区间内,淬透性随酸溶硼(Bsol)含量的增加而升高,且当Bsol质量分数为0.0012%左右,其淬透性最好。但是,如钢中添加了合金元素如V、Nb等,易形成含硼析出相,会降低酸溶硼中有效硼的占比,进而影响以Bsol含量来判断淬透性的准确性。研究结果可为含硼调质钢生产实践和新工艺的制定提供一定的参考依据。     

硅钢自粘结涂层的常规性能研究

基于常规热固型自粘结涂料性状,讨论其涂布作业性和涂层产品的基本性能,研究了涂层厚度、一次烘干和二次固化过程中的工艺参数对涂层主要性能的影响。结果发现:一定范围的涂料性状(黏度、固含等)能获得较好的涂层表观和膜厚均匀性,进而对产品性能起到积极效果;控制膜厚为3~5μm,并选用合适的一次烘干和二次固化工艺参数,能获得最优的涂层综合性能;该类热固性自粘结涂层产品的绝缘性和粘结性能分别满足180℃和150℃的长期服役工况。