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1.
Salehe Gomroki Zahra Yavari Ahmad Reza Abbasian Meissam Noroozifar 《International Journal of Applied Ceramic Technology》2021,18(6):2099-2110
The spongy nickel oxide (SNO) was synthesized the solution combustion method. The SNO was selected as a promoter to boost the catalytic activity of nanoraspberry-like palladium (NRPd) toward electrooxidation of five light fuels (LFs): methanol, ethanol, formaldehyde, formic acid, and ethylene glycol. The X-ray powder diffraction, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy, and field emission scanning electron microscope techniques were used for the materials characterization. In comparison with nonpromoted Pd, the NRPd-SNO electrocatalyst shown an excellent efficiency in parameters like the electrochemical active surface area and anti-CO poisoning behavior. The turnover data and the parameters, including reaction order, activation energy, and the coefficients of electron transfer and diffusion, were evaluated for the each process of LFs electrooxidation. The outcome for NRPd-SNO activity toward LFs electrooxidation was compared to some reported electrodes. The SNO increases the removal of intermediates created in the oxidation of LFs that can poison the surface of palladium catalyst. This is due to the presence of the lattice oxygens in SNO structure and Ni switching between its high and low valances. The compatibility of the adsorption process of LFs on the surface of the NRPd-SNO catalyst with different isotherms was determined by studying the Tafel polarization and calculating the surface coverage. 相似文献
2.
现阶段的语义解析方法大部分都基于组合语义,这类方法的核心就是词典。词典是词汇的集合,词汇定义了自然语言句子中词语到知识库本体中谓词的映射。语义解析一直面临着词典中词汇覆盖度不够的问题。针对此问题,该文在现有工作的基础上,提出了基于桥连接的词典学习方法,该方法能够在训练中自动引入新的词汇并加以学习,为了进一步提高新学习到的词汇的准确度,该文设计了新的词语—二元谓词的特征模板,并使用基于投票机制的核心词典获取方法。该文在两个公开数据集(WebQuestions和Free917)上进行了对比实验,实验结果表明,该文方法能够学习到新的词汇,提高词汇的覆盖度,进而提升语义解析系统的性能,特别是召回率。 相似文献
3.
This study is to evaluate the potential for development of a cellulosic ethanol facility in Vietnam. Rice straw is abundant in Vietnam and highly concentrated in the Mekong Delta, where about 26 Mt year−1 of rice straw has been yearly produced. To minimize the overall production cost (PC) of ethanol from rice straw, it is crucial to choose the optimal facility size. The delivered cost of rice straw varied from 20.5 to 65.4 $ dry t−1 depending on transportation distance. The Mekong Delta has much lower rice straw prices compared with other regions in Vietnam because of high density and quantity of rice straw supply. Thus, this region has been considered as the most suitable location for deploying ethanol production in Vietnam. The optimal plant size of ethanol production in the region was estimated up to 200 ML year−1. The improvement in solid concentration of material in the hydrothermal pre-treatment step and using residues for power generation could substantially reduce the PC in Vietnam, where energy costs account for the second largest contribution to the PC, following only enzyme costs. The potential for building larger ethanol plants with low rice straw costs can reduce ethanol production costs in Vietnam. The current estimated production cost for an optimal plant size of 200 ML year−1 was 1.19 $ L−1. For the future scenario, considering improvements in pre-treatment, enzyme hydrolysis steps, specific enzyme activity, and applying residues for energy generation, the ethanol production cost could reduce to 0.45 $ L−1 for a plant size of 200 ML year−1 in Vietnam. These data indicated that the cost-competitiveness of ethanol production could be realized in Vietnam with future improvements in production technologies. 相似文献
4.
Rice straw is the most abundant agricultural residue on a global scale and is widely available as feedstock for cellulosic fuel production. However, it is highly recalcitrant to biochemical deconstruction and also generates inhibitors that affect enzymatic saccharification. Rice straw from eastern Arkansas was subjected to dilute acid pretreatment (160 °C, 48 min and 1.0% sulfuric acid) and solid-state fermentation with two lignocellulolytic fungi, Trametes hirsuta and Myrothecium roridum, and their saccharification efficacies were compared. T. hirsuta and M. roridum were tested separately; pretreatment of rice straw with either strain for seven days resulted in 19 and 70% enrichment of its holocellulose content, respectively. However, liquid chromatography analysis of the alkali extracts showed significant differences in cell wall degradation by T. hirsuta and M. roridum. T. hirsuta removed 15% more phenolic compounds and 38% more glucan than M. roridum, while M. roridum removed 77% more xylan than T. hirsuta. Fungal and dilute acid pretreated biomass was then hydrolyzed using Accellerase® 1500, a saccharification cocktail. Saccharification efficiency of M. roridum was 37% higher than that of dilute acid pretreatment of rice straw, requiring 8% lower enzyme loading and 50% shorter enzymatic hydrolysis duration. Alkali extraction of fungal pretreated biomass also yielded 10–15 g kg−1 of acid precipitable polymeric lignin (APPL), which is a valuable co-product for biorefineries. In comparison to dilute acid pretreatment, fungal pretreatment could be a cost-effective alternative for the degradation of recalcitrant biomass, such as rice straw. 相似文献
5.
本文介绍了秸杆毡的成型工艺 ,通过植物所需的水、肥料和空气三种因素对秸杆毡的化学和物理性能进行了研究 ,该材料可被用作草皮栽培基质 相似文献
6.
7.
Larissa Canilha Walter Carvalho Marco Giulietti Maria Das Graças Almeida Felipe João Batista Almeida E Silva 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(5):715-721
BACKGROUND: Xylitol bioproduction from lignocellulosic residues comprises hydrolysis of the hemicellulose, detoxification of the hydrolysate, bioconversion of the xylose, and recovery of xylitol from the fermented hydrolysate. There are relatively few reports on xylitol recovery from fermented media. In the present study, ion‐exchange resins were used to clarify a fermented wheat straw hemicellulosic hydrolysate, which was then vacuum‐concentrated and submitted to cooling in the presence of ethanol for xylitol crystallization. RESULTS: Sequential adsorption into two anion‐exchange resins (A‐860S and A‐500PS) promoted considerable reductions in the content of soluble by‐products (up to 97.5%) and in medium coloration (99.5%). Vacuum concentration led to a dark‐colored viscous solution that inhibited xylitol crystallization. This inhibition could be overcome by mixing the concentrated medium with a commercial xylitol solution. Such a strategy led to xylitol crystals with up to 95.9% purity. The crystallization yield (43.5%) was close to that observed when using commercial xylitol solution (51.4%). CONCLUSION: The experimental data demonstrate the feasibility of using ion‐exchange resins followed by cooling in the presence of ethanol as a strategy to promote the fast recovery and purification of xylitol from hemicellulose‐derived fermentation media. Copyright © 2008 Society of Chemical Industry 相似文献
8.
This paper concerns CDMA cellular networks equipped with conventional matched filter receivers. For this type of cellular networks, two problems exist. One is the inverse relationship between the coverage and capacity, and the other one is the near-far unfair access problem. To resolve these two problems, a bandwidth-space partitioning technique is adopted. Several admission control schemes based on the bandwidth-space partitioning technique are proposed, and their performances are evaluated based on the simulation.Shih-Tsung Yang received his B.S. (1989) and M.S. (1991) degrees in electrical engineering from the National Taiwan University, and Ph.D. (1999) degree in electrical and computer engineering from University of Maryland, College Park.From 1999 to 2000, he was with SBC Technology Resourtces, Inc. where he was involved in the network architecture design for the ATM based networks. From November 2000 to May 2003, he was with Transilica/Microtune where he was involved in the design of Baseband and RF for the wireless communications. Since May 2003, Dr. Yang is now with Genesys Logic, Inc. where he is responsible for the baseband design of the WLAN and Ethernet.Dr. Yang’s research interests are in the area of Digital Communications, Communication networks and signal processing. E-mail: thomas.yang@genesyslogic.com.twAnthony Ephremides received his B.S. degree from the National Technical University of Athens (1967), and M.S. (1969) and Ph.D. (1971) degrees from Princeton University, all in Electrical Engineering. He has been at the University of Maryland since 1971, and currently holds a joint appointment as Professor in the Electrical Engineering Department and in the Institute of Systems Research (ISR) of which he is a founding member. He is co-founder of the NASA Center for Commercial Development of Space on Hybrid and Satellite Communications Networks established in 1991 at Maryland as an off-shoot of the ISR. He served as Co-Director of that Center from 1991 to 1994.He was a Visiting Professor in 1978 at the National Technical University in Athenas, Greece, and in 1979 at the EECS Department of the University of California, Berkeley, and at INRIA, France. During 1985-1986 he was on leave at MIT and ETH in Zurich, Switzerland. He was the General Chairman of the 1986 IEEE Conference on Decision and Control in Athens, Greece and of the 1991 IEEE International Symposium on Information Theory in Budapest, Hungary. He also organized two workshops on Information theory in 1984 (Hot Springs, VA) and in 1999 (Metsovo, Greece). He was the Technical Program Co-Chair of the IEEE INFOCOM in New York City in 1999 and of the IEEE International Symposium on Information theory in Sorrento, Italy in 2000. He has also been the Director of the Fairchild Scholars and Doctoral Fellows Program, an academic and research partnership program in Satellite Communications between Fairchild Industries and the University of Maryland. He won the IEEE Donald E. Fink Prize Paper Award (1992) and he was the first recipient of the Sigmobile Award of the ACM (Association of Computer Machinery) for contributions to wireless communications in 1997. He has been the President of the Information Theory Society of the IEEE (1987) and has served on its Board of Governors almost continuously from 1981 until the present. He was elected to the Board of Directors of the IEEE in 1989 and 1990. Dr. Ephremides has authored or co-authored over 100 technical journal papers and 300 technical conference presentations. He has also contributed chapters to several books and edited numerous special issues of scientific journals. He has also won awards from the Maryland Office of Technology Liaison for the commercialization of products and ideas stemming from his research. He has served on the Editorial Boards of the IEEE Transactions on Automatic Control, IEEE Transactions on Information theory, the Journal of Wireless Networks, and the International Journal of Satellite Communications.He has been the Dissertation Supervisor of over twenty Ph.D. students who now hold prominent positions in academia, industry, and research labs. He is the founder and President of Pontos, Inc., a Maryland company that provides technical consulting services, since 1980.Dr. Ephremides’ interests are in the areas of communication theory, communication systems and networks, queueing systems, signal processing, and satellite communications. His research has been continuously supported since 1971 by NSF, NASA, ONR, ARL, NRL, NSA, and Industry. E-mail: tony@eng.umd.edu 相似文献
9.
简要描述了近几年来研究开发的为移动、便携和固定接收服务的地面发射数字声音广播(DAB)系统总的特点、应达到的技术和运行要求。重点介绍了系统采用的最适合克服移动接收中出现的多径效应影响的先进源编码技术(MUSICAM)、信道编码技术(COFDM)等的基本原理、系统参数、并介绍了规划DAB业务时,在VHF/FM频段考虑的最佳频段及频谱利用改善情况,还提供了DAB单频网洛(SFN)覆盖的大体情况。其内容取材均来自1990~1992年EBU、CCIR等的最新文稿资料。 相似文献
10.