Analysis of suitability of TPP ash-slag waste as materials for hydrogen fuel storage

The current trends in energy were described, the main of which is the use of alternative energy sources, especially hydrogen. The most common methods of hydrogen accumulation were proposed: accumulation of compressed gaseous hydrogen in high-pressure tanks; accumulation of liquid hydrogen in cryogenic tanks; storing hydrogen in a chemically bound state; accumulation of gaseous hydrogen in carriers with a high specific surface area. Based on the combination of advantages and disadvantages, the most promising methods of accumulation were selected: storage of liquid hydrogen and storage of hydrogen in carriers with a high specific surface area. The main requirement for materials for hydrogen storage by these methods was revealed – a high specific surface area. Prospects for the development of waste-free low-emission technologies due to the recycling of secondary raw materials and the development of low-temperature technologies for the synthesis of functional and structural materials were substantiated. The applicability of large-scale ash and slag waste from coal-fired thermal power plants as a raw material for obtaining materials by low-temperature technologies was shown. The traditional ways of using ash and slag waste as a raw material, active additive and filler in the production of cements were described. Modern technologies for the production of innovative materials with a unique set of properties were presented, namely carbon nanotubes, silica aerogel and geopolymer materials. The prospect of using geopolymer matrices as a precursor for the synthesis of a number of materials was described; the most promising type of materials was selected – geopolymer foams, which are mainly used as sorbents for purifying liquids and gases or accumulating target products, as well as heat-insulating materials. The possibility of obtaining products of any shape and size on the basis of geopolymer matrices without high-temperature processing was shown. The special efficiency of the development of the technology of porous granules and powders obtained from a geopolymer precursor using various methods was substantiated. The obtained granules can be used in the following hydrogen storage technologies: direct accumulation of hydrogen in porous granules; creation of insulating layers for liquid hydrogen storage units.     

Temperature cycling and its effect on mechanical behaviours of highporosity chalks

Temperature history can have a significant effect on the strength of water-saturated chalk.In this study,hydrostatic stress cycles are applied to understand the mechanical response of chalk samples exposed to temperature cycling between each stress cycle,compared to the samples tested at a constant temperature.The total accumulated strain during a stress cycle and the irreversible strain are reported.Chalk samples from Kansas(USA)and Mons(Belgium),with different degrees of induration(i.e.amount of contact cementation),were used.The samples were saturated with equilibrated water(polar)and nonpolar Isopar H oil to quantify water weakening.All samples tested during 10 stress cycles with varying temperature(i.e.temperature cycled in between each stress cycle)accumulated more strain than those tested at constant temperatures.All the stress cycles were performed at 30℃.The two chalk types behaved similarly when saturated with Isopar H oil,but differently when saturated with water.When saturated with water,the stronger Kansas chalk accumulated more total strain and more irreversible strain within each stress cycle than the weaker Mons chalk.     

大庆长垣以东地区深层天然气输导特征及成藏

大庆长垣以东地区深层天然气输导通道主要由断裂、不整合面和砂体构成。该区砂体横向分布不稳定，物性差，不是天然气侧向长距离运移的输导通道，但可以起到衔接输导作用。输导通道时该区天然气成藏与分布起到了重要控制作用，主要表现在断裂将天然气输导致上覆不同储集层中聚集成藏。不整合面和砂体将天然气输导到四周古隆起上聚集成藏。沿断裂输导的天然气形成以断层为主的构造气藏。沿不整合面和砂体输导的天然气形成以地层及岩性为主的气藏。沿断裂输导运移聚集的天然气在剖面上呈串多层分布，沿不整合面和砂体输导运移聚集的天然气在平面上呈环状分布。     

同沉积压扭断层在柴达木盆地西部南区油气成藏中的意义

柴达木盆地西部南区逆断层断面产状呈上陡下缓的铲式特征,生长系数变化在1.3~2.5之间,断距纵向上向浅层逐渐变小和横向上向一个方向逐渐增大,总体表现为典型的同沉积压扭断层。指出该断层演化主要经历了同生冲断期、褶皱发育期、平静期及二次活动期4个阶段,长期活动的NWW向主干断层除控制构造带的展布格局外,还控制着烃源岩、储集层、盖层及其组合的空间发育,同时还有效地沟通着源岩与圈闭并成为有效输导体系的一部分,近N S向展布的次级断层决定着局部构造的发育特点,与NWW向断层联合控制着油气的局部富集。     

2.5GHz低相位噪声CMOS LC VCO的设计

用0 .35μm、一层多晶、四层金属、3.3V的标准全数字CMOS工艺设计了一个全集成的2 .5 GHz L C VCO,电路采用全差分互补负跨导结构以降低电路功耗和减少器件1/ f噪声的影响.为了减少高频噪声的影响,采用了在片L C滤波技术.可变电容采用增强型MOS可变电容,取得了2 3%的频率调节范围.采用单个16边形的对称片上螺旋电感,并在电感下加接地屏蔽层,从而减少芯片面积,优化Q值.取得了在离中心频率1MHz处- 118d Bc/ Hz的相位噪声性能.电源电压为3.3V时的功耗为4 m A.     

反转构造的反转程度及其与油气聚集的关系

结合典型反转构造地震剖面，分析了断层型和褶皱型两类反转构造的反转程度，上下皆正断层型和向形褶皱型反转构造的反转程度轻微；上逆下正断层型和透镜形褶皱型反转构造的反转程度中等；上下皆逆断层型和背形褶皱型反转构造的反转程度强烈。分析了反转构造的反转程度与油气聚集的关系，处于轻微反转程度的上下皆正断层型反转和向形褶皱型反转，以及处于强烈反转程度的上下皆逆断层型反转和背形褶皱型反转不利于油气聚集；处于中等反转程度的上逆下正断层型反转和透镜形褶皱型反转类型有利于油气聚集成藏。     

塔里木油田水碳酸盐平衡系数与有机酸的意义

根据统计学规律,对塔里木盆地油田水进行了研究,阐明了该盆地油田水的碳酸盐平衡系数(简称为R_C)与有机酸的基本特征。从油田水的无机组分与有机组分的统计分析中发现了油田水的碳酸盐平衡系数与有机酸存在明显的负相关性,进一步论证了碳酸盐平衡系数和有机酸与油气聚集及油气性质的关系。碳酸盐平衡系数越低及低碳有机酸的含量越高,它们与油藏,尤其是与 轻质油或气藏的关系越密切。从两者的关系中初步了解到有机酸的溶蚀作用对油气藏中储层次生孔隙的形成应有较重要的影响。     

乘累加运算器的高性能解决方案

在设计数字信号处理器时我们经常要设计高性能的乘累加运算器，文章详细分析了乘累加运算器的结构，提出了其高性能设计方案并采用标准单元进行了实现，同时提出了DCT运算单元的高性能解决方案。     

柴达木盆地断裂系统特征与油气勘探战略方向

基底断裂格局决定了盆地构造演化和沉积发育,导致了北缘、中部和昆北3个各具特色的断裂构造系统。北缘断裂构造系统平面上以反S展布、剖面上以一系列北倾南冲的逆冲断层带及其所控制的同沉积构造呈阶梯向南下掉为特点,受北部祁连山构造应力系统的作用;南部昆北断裂构造系统发育压陷断槽和断阶带,受南部昆仑山构造应力系统的作用;中部断裂构造系统以两断夹一隆的冲起构造为特色,同时受祁连山和昆仑山构造应力的共同作用。断裂对油气藏的形成和分布有重要的控制作用,表现在对烃源岩、储集条件、圈闭形成及油气运聚等方面。依据断裂控烃特征并针对柴达木盆地的具体情况,柴达木盆地油气勘探应迅速转移到盆地腹地即中部断裂构造系统区,尤其是鄂博梁Ⅱ号一伊克雅乌汝、鸭湖—台吉乃尔构造带和中南隆起区,有望取得重大突破。