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Itwasreported[1] thatthemicro stereostructureofprimaryausteniteincastironconsistsofprimarystemsandsecondaryarmsthat growaccordingtodendritecrystalsbranchrule ,andsomeofprimaryausteniteevenhavethirdarms .MiyakeHetal[2 ]proposedaconceptofregionmodelbystudying… 相似文献
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本文利用可控平均冷却速度的单向凝固实验炉测定了45号钢在不同平均冷却速度下的冷却曲线,由此得到其在凝固期间的平均冷却速度R,相应地测量了不同平均冷却速度下试样的二次枝晶臂间距S2,通过回归,得到了如下关系式:S2=727R-0.41,并将引式成功地应用于实际生产中。 相似文献
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Measurements of the thermal conductivities of the frozen layer of aqueous binary solutions have been performed using the transient hot-wire method. Solutions of ethylene glycol and sodium chloride were utilized as the testing fluids, and they were frozen up in the test section in which the platinum wires 40 m in diameter and 170 mm in length were strung. Measurements were carried out under equilibrium at a variety of both the initial concentration of the solution and the temperature of the frozen layer. The expressions of the thermal conductivity of the frozen layer were determined. It was found that the thermal conductivity of the dendritic ice layer was favorably assessed with the Lichteneker's model by introducing the solid fraction under an assumption of the equililbrium within the range of parameters examined.Paper presented at the Tenth Symposium on Thermophysical Properties, June 20–23, 1988, Gaithersburg, Maryland, U.S.A. 相似文献
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金属镍电沉积中枝晶分形生长的研究 总被引:5,自引:4,他引:5
将分形几何与电化学原理相结合,通过改进的有限扩散凝聚模型(diffusion-limited aggregation,DLA),采用基于Microsoft Visual C 6.0的Open GL编程,对点电极为阴极进行二维电沉积时沉积产物的形貌进行了模拟.以环形金属镍为阳极,石墨为阴极,用自行设计的试验设备制备了二维的金属镍枝晶以验证模拟结果.结果表明,在保持电压恒定的条件下,镍沉积层的形貌特征为具有分形结构的枝晶,这与采用DLA模型模拟所得的二维枝晶形貌具有相似性,表明该模型对枝晶电沉积的实验研究具有很好的指导意义. 相似文献
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The electrochemical behavior of Li/V6O13 cells is investigated at room temperature (22 °C) both in liquid electrolyte consisting of oligomeric poly(ethyleneglycol)dimethylether+lithium bis(trifluoromethylsulfonylimide) and composite electrolytes formed by blending the liquid electrolyte with silica nanoparticles (fumed silica). The addition of fumed silica yields a gel-like electrolyte that demonstrates the desirable property of suppressing lithium dendrite growth due to the rigidity and immobility of the electrolyte structure. The lithium/electrolyte interfacial resistance for composite gel electrolytes is less than that for the corresponding base-liquid electrolyte, and the charge-discharge cycle performance and electrochemical efficiency for the Li/V6O13 cell is significantly improved. The effect of fumed silica surface group on the electrochemical performance is discussed; the native hydrophilic silanol surface group appears better than fumed silica that is modified with a hydrophobic octyl surface moiety. 相似文献
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为了研究铋(Bi)对Al-30%Mg2Si复合材料显微组织和力学性能的影响,利用原位内生工艺制备了Al-30%Mg2Si复合材料,并加入不同量的Bi对其细化变质.利用扫描电镜进行显微组织观察,并利用布氏硬度计和液压式万能试验机进行力学性能测试.试验结果显示,稀土Bi的质量分数由0%增加至5%时,初生相Mg2Si的平均晶粒尺寸先减小后变大,而抗拉强度、硬度和伸长率则先提高后减小;当Bi加入量约为3%时,初生相Mg2Si显微组织细化效果最为明显,综合力学性能最好. 相似文献
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Niranjan Sitapure Hyeonggeon Lee Francisco Ospina-Acevedo Perla B. Balbuena Sungwon Hwang Joseph Sang-II Kwon 《American Institute of Chemical Engineers》2021,67(1):e17073
Li metal anode is the “Holy Grail” material of advanced Lithium-ion-batteries (LIBs). However, it is plagued by uncontrollable dendrite growth resulting in poor cycling efficiency and short-circuiting of batteries. This has spurred a plethora of research to understand the underlying mechanism of dendrite formation. While experimental studies suggest that there are complex physical and chemical interactions between heterogeneous solid-electrolyte interphase (SEI) and dendrite growth, most of the studies do not reveal the mechanisms triggering these interactions. To deal with this knowledge gap, we propose a multiscale modeling framework which couples kinetic Monte Carlo and Molecular Dynamics simulations. Specifically, the model has been developed to account for (a) heterogeneous SEI, (b) dendrite-SEI interactions, and (c) effect of electrolyte on Li electrodeposition and potential dendrite formation. This allows the proposed computational model to be extended to various electrolytes and SEI species and generate results consistent with previous experimental studies. 相似文献
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