全文获取类型
收费全文 | 19879篇 |
免费 | 2611篇 |
国内免费 | 1805篇 |
专业分类
电工技术 | 1789篇 |
综合类 | 1791篇 |
化学工业 | 2383篇 |
金属工艺 | 941篇 |
机械仪表 | 998篇 |
建筑科学 | 738篇 |
矿业工程 | 794篇 |
能源动力 | 791篇 |
轻工业 | 734篇 |
水利工程 | 372篇 |
石油天然气 | 4398篇 |
武器工业 | 300篇 |
无线电 | 1198篇 |
一般工业技术 | 1324篇 |
冶金工业 | 545篇 |
原子能技术 | 134篇 |
自动化技术 | 5065篇 |
出版年
2024年 | 83篇 |
2023年 | 344篇 |
2022年 | 657篇 |
2021年 | 776篇 |
2020年 | 866篇 |
2019年 | 759篇 |
2018年 | 636篇 |
2017年 | 854篇 |
2016年 | 902篇 |
2015年 | 1035篇 |
2014年 | 1332篇 |
2013年 | 1529篇 |
2012年 | 1610篇 |
2011年 | 1694篇 |
2010年 | 1260篇 |
2009年 | 1303篇 |
2008年 | 1114篇 |
2007年 | 1209篇 |
2006年 | 1140篇 |
2005年 | 851篇 |
2004年 | 643篇 |
2003年 | 563篇 |
2002年 | 508篇 |
2001年 | 458篇 |
2000年 | 360篇 |
1999年 | 319篇 |
1998年 | 264篇 |
1997年 | 222篇 |
1996年 | 199篇 |
1995年 | 170篇 |
1994年 | 120篇 |
1993年 | 84篇 |
1992年 | 64篇 |
1991年 | 61篇 |
1990年 | 77篇 |
1989年 | 51篇 |
1988年 | 25篇 |
1987年 | 24篇 |
1986年 | 23篇 |
1985年 | 17篇 |
1984年 | 16篇 |
1983年 | 8篇 |
1982年 | 12篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1964年 | 5篇 |
1959年 | 3篇 |
1957年 | 3篇 |
1956年 | 3篇 |
1951年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 359 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(79):33765-33780
This work investigates selective Ni locations over Ni/CeZrOx–Al2O3 catalysts at different Ni loading contents and their influences on reaction pathways in ethanol steam reforming (ESR). Depending on the Ni loading contents, the added Ni selectively interacts with CeZrOx–Al2O3, resulting in the stepwise locations of Ni over CeZrOx–Al2O3. This behavior induces a remarkable difference in hydrogen production and coke formation in ESR. The selective interaction between Ni and CeZrOx for 10-wt.% Ni generates more oxygen vacancies in the CeZrOx lattice. The Ni sites near the oxygen vacancies enhance reforming via steam activation, resulting in the highest hydrogen production rate of 1863.0 μmol/gcat·min. In contrast, for 15 and 20-wt.% Ni, excessive Ni is additionally deposited on Al2O3 after the saturation of Ni–CeZrOx interactions. These Ni sites on Al2O3 accelerate coking from the ethylene produced on the acidic sites, resulting in a high coke amount of 19.1 mgc/gcat·h (20Ni/CZ-Al). 相似文献
2.
边坡位移的时间序列曲线存在复杂的非线性特性,传统的预测模型精度不足以满足预测要求。为此提出了基于变分模态分解的鸟群优化-核极限学习机的预测模型,并用于河北省某水泥厂的边坡位移预测。该方法首先采用VMD把边坡位移序列分解为一系列的有限带宽的子序列,再对各子序列分别采用相空间重构并用核极限学习机预测,采用鸟群算法优化相空间重构的嵌入维度和KELM中惩罚系数和核参数三个数值,以取得最优预测模型。最后将各个子序列预测值叠加,得到边坡位移的最终预测值。结果表明:和KELM、BSA-KELM、EEMD-BSA-KELM模型相比,基于VMD的BSA-KELM预测精度更高,为边坡位移的预测提供一种有效的方法。 相似文献
3.
Ahmed Fathy Mohammad Ali Abdelkareem A.G. Olabi Hegazy Rezk 《International Journal of Hydrogen Energy》2021,46(8):6087-6099
Cell temperature and water content of the membrane have a significant effect on the performance of fuel cells. The current-power curve of the fuel cell has a maximum power point (MPP) that is needed to be tracked. This study presents a novel strategy based on a salp swarm algorithm (SSA) for extracting the maximum power of proton-exchange membrane fuel cell (PEMFC). At first, a new formula is derived to estimate the optimal voltage of PEMFC corresponding to MPP. Then the error between the estimated voltage at MPP and the actual terminal voltage of the fuel cell is fed to a proportional-integral-derivative controller (PID). The output of the PID controller tunes the duty cycle of a boost converter to maximize the harvested power from the PEMFC. SSA determines the optimal gains of PID. Sensitivity analysis is performed with the operating fuel cell at different cell temperature and water content of the membrane. The obtained results through the proposed strategy are compared with other programmed approaches of incremental resistance method, Fuzzy-Logic, grey antlion optimizer, wolf optimizer, and mine-blast algorithm. The obtained results demonstrated high reliability and efficiency of the proposed strategy in extracting the maximum power of the PEMFC. 相似文献
4.
Sehar Tasleem Muhammad Tahir Wesam Alsayeh Khalifa 《International Journal of Hydrogen Energy》2021,46(27):14148-14189
Photocatalytic H2 generation using semiconductor photocatalysts is considered as a cost-effective and eco-friendly technology for solar to energy conversion; however, the present photocatalysts have been recognized to depict low efficiency. Currently, porous coordination polymers known as metal-organic frameworks (MOFs) constituting flexible and modifiable porous structure and having excess active sites are considered to be appropriate for photocatalytic H2 production. This review highlights current progress in structural development of MOF materials along with modification strategies for enhanced photoactivity. Initially, the review discusses the photocatalytic H2 production mechanism with the concepts of thermodynamics and mass transfer with particular focus on MOFs. Elaboration of the structural categories of MOFs into Type I, Type II, Type III and classification of MOFs for H2 generation into transition metal based, post-transition metal based, noble-metal based and hetero-metal based has been systematically discussed. The review also critically deliberate various modification approaches of band engineering, improvement of charge separation, efficient irradiation utilization and overall efficiency of MOFs including metal modification, heterojunction formation, Z-scheme formation, by introducing electron mediator, and dye based composites. Also, the MOF synthesized derivatives for photocatalytic H2 generation are elaborated. Finally, future perspectives of MOFs for H2 generation and approaches for efficiency improvement have been suggested. 相似文献
5.
6.
The proliferating need for sustainability intervention in food grain transportation planning is anchoring the attention of researchers in the interests of stakeholders and environment at large. Uncertainty associated with food grain supply further intensifies the problem steering the need for designing robust, cost-efficient and sustainable models. In line with this, this paper aims to develop a robust and sustainable intermodal transportation model to facilitate single type of food grain commodity shipments while considering procurement uncertainty, greenhouse gas emissions, and intentional hub disruption. The problem is designed as a mixed integer non-linear robust optimisation model on a hub and spoke network for evaluating near optimal shipment quantity, route selection and hub location decisions. The robust optimisation approach considers minimisation of total relative regret associated with total cost subject to several real-time constraints. A version of Particle Swarm Optimisation with Differential Evolution is proposed to tackle the resulting NP-hard problem. The model is tested with two other state-of the art meta-heuristics for small, medium, and large datasets subject to different procurement scenarios inspired from real time food grain operations in Indian context. Finally, the solution is evaluated with respect to total cost, model and solution robustness for all instances. 相似文献
7.
8.
《Journal of the European Ceramic Society》2021,41(15):7868-7877
In this work, 0.5TRPO•0.5Gd2Zr2O7 ceramic with an average grain size of only ∼15 nm was prepared by a high pressure (5 GPa/520 °C) sintering method. Phase evolutions and microstructure changes of the as-fabricated super nano and micron-grained ceramics under a high-dose displacement damage induced by 300 keV Kr2+ ions were investigated. The results show that the super nano-grained ceramic has low degree of amorphization, obvious grain growth (2–3 times in grain size) and big Kr bubbles (10–68 nm) formation after irradiation. The micron-grained ceramic was severely amorphized after irradiation and many microcracks were formed parallel to its surface. The formation mechanism of Kr bubbles in the super nano-grained ceramic is on account of grain boundary diffusion and migration induced by the accumulation of the injecting Kr ions and irradiation defects. Nevertheless, microcracks formed in the micron-grained sample are caused by the accumulation of Kr atoms. 相似文献
9.
Sustainable and efficient food supply chain has become an essential component of one’s life. The model proposed in this paper is deeply linked to people's quality of life as a result of which there is a large incentive to fulfil customer demands through it. This proposed model can enhance food quality by making the best possible food quality accessible to customers, construct a sustainable logistics system considering its environmental impact and ensure the customer demand to be fulfilled as fast as possible. In this paper, an extended model is examined that builds a unified planning problem for efficient food logistics operations where four important objectives are viewed: minimising the total expense of the system, maximising the average food quality along with the minimisation of the amount of CO2 emissions in transportation along with production and total weighted delivery lead time minimisation. A four objective mixed integer linear programming model for intelligent food logistics system is developed in the paper. The optimisation of the formulated mathematical model is proposed using a modified multi-objective particle swarm optimisation algorithm with multiple social structures: MO-GLNPSO (Multi-Objective Global Local Near-Neighbour Particle Swarm Optimisation). Computational results of a case study on a given dataset as well as on multiple small, medium and large-scale datasets followed by sensitivity analysis show the potency and effectiveness of the introduced method. Lastly, there has been a scope for future study displayed which would lead to the further progress of these types of models. 相似文献
10.