全文获取类型
收费全文 | 1249篇 |
免费 | 112篇 |
国内免费 | 69篇 |
专业分类
电工技术 | 42篇 |
综合类 | 65篇 |
化学工业 | 519篇 |
金属工艺 | 39篇 |
机械仪表 | 23篇 |
建筑科学 | 30篇 |
矿业工程 | 30篇 |
能源动力 | 36篇 |
轻工业 | 267篇 |
水利工程 | 46篇 |
石油天然气 | 43篇 |
武器工业 | 10篇 |
无线电 | 59篇 |
一般工业技术 | 114篇 |
冶金工业 | 56篇 |
原子能技术 | 33篇 |
自动化技术 | 18篇 |
出版年
2024年 | 2篇 |
2023年 | 30篇 |
2022年 | 27篇 |
2021年 | 49篇 |
2020年 | 48篇 |
2019年 | 39篇 |
2018年 | 26篇 |
2017年 | 34篇 |
2016年 | 39篇 |
2015年 | 36篇 |
2014年 | 66篇 |
2013年 | 75篇 |
2012年 | 115篇 |
2011年 | 109篇 |
2010年 | 77篇 |
2009年 | 71篇 |
2008年 | 63篇 |
2007年 | 87篇 |
2006年 | 60篇 |
2005年 | 81篇 |
2004年 | 56篇 |
2003年 | 38篇 |
2002年 | 32篇 |
2001年 | 26篇 |
2000年 | 24篇 |
1999年 | 17篇 |
1998年 | 16篇 |
1997年 | 21篇 |
1996年 | 9篇 |
1995年 | 14篇 |
1994年 | 8篇 |
1993年 | 8篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
排序方式: 共有1430条查询结果,搜索用时 31 毫秒
1.
Xueli Du Yuelong Wang Rongna Shi Zhiyong Mao Zhihao Yuan 《Journal of the European Ceramic Society》2018,38(10):3512-3517
The PbClxS1-x and Pb1-xBixS (x? =?0–0.05) bulks were fabricated with a facile method of hydrothermal synthesis and microwave sintering, and the effect of anionic and cationic donors on the thermoelectric performance of PbS was investigated. Although Cl? and Bi3+ both effectively improved the thermoelectric properties of n-type PbS, more excellent thermoelectric performance was obtained from Cl? doped samples because of higher electrical property and lower thermal conductivity at higher temperature (T? >?600?K). The thermoelectric figure of merit (ZT) reaches 1.04 for PbCl0.015S0.985 at 800?K and increases with temperature increasing without sign of saturation, which is probably the highest value ever reported for single-phase polycrystalline n-type PbS. The results also indicate that the hydrothermal synthesis and microwave sintering can realize anion doping as well as cation doping for n-type PbS at low cost, and PbS should be a robust alternative for PbTe thermoelectric materials. 相似文献
2.
A device able to electrokinetically concentrate cationic samples has many potential medical and industrial applications, but until now has remained undeveloped due to the lack of a commercial anion-permselective material leading to a prohibitively complex fabrication procedure. Herein, a novel multiscale-porous anion exchange membrane (MP-AEM) that enables the convenient and scalable electrokinetic concentration of cationic species is proposed. A mechanically enhanced multiscale-porous structure with a solid framework is realized by adopting polyester resin as an additive to overcome the intrinsic limitations of the AEM material. The scalable MP-AEM-embedded electrokinetic concentrator is devised based on the peculiar properties of the MP-AEM that for allow both ion and fluid transport. With the MP-AEM, the concentrator is fabricated in a highly streamlined manner consisting only of a simple insertion and assembly. The concentration performance of the MP-AEM-embedded electrokinetic concentrator is demonstrated with a positively charged fluorescent dye and a fluorescein-labeled protein, and the results show enrichment factors of 250 and 500, respectively. The MP-AEM makes cationic electrokinetic concentration more accessible and scalable, thereby enabling further progress in a wide range of fields. 相似文献
3.
唐德修 《成都纺织高等专科学校学报》2007,24(3):13-15
科学焚烧处理垃圾法具有占地少,场地易选择,时间短,减量化显著,无害化彻底以及回收余热供发电供热等优点.其处理设备和控制系统是保证科学焚烧处理垃圾成功,并带来巨大经济效益的关键.鉴于此,文章对科学焚烧垃圾系统设计作了比较详细的介绍. 相似文献
4.
Studies on Catalytic Side-Chain Oxidation of Nitroaromatics to Aldehydes with Oxygen 总被引:2,自引:0,他引:2
The side-chain oxidation of 2-nitrotoluene in liquid phase in the presence of catalytic amount of manganese sulfate and stoichiometric amount of potassium hydroxide with oxygen was studied. In the most favorable conditions, over 80% of conversion of 2-nitrotoluene and 50% of selectivity to 2-nitrobenzaldehyde was achieved. Effects of the reaction parameters on the conversion of the reactant and the selectivity of the product were examined. These results, together with EPR spectroscopic study, show that a benzyl anion was formed in the early stage of the reaction, which was then converted to the final product via a free radical mechanism. 相似文献
5.
6.
从理论上分析了液碱对阴树脂再生度的影响。通过两种不同纯度的液碱再生阴树脂的实际运行经济指标统计分析,说明用高纯度液碱再生阴树脂,可提高树脂的工作交换容量和周期制水量,有很好的经济效益。 相似文献
7.
Anion exchange membranes (AEMs) are one of the core components of AEM fuel cells. A series of poly(vinyl alcohol)/polyquaternium-10 (PVA/PQ-10) AEMs with semi-interpenetrating networks (s-IPNs) are prepared by a simple solution-casting method using glutaraldehyde (GA) as a cross-linking agent. Subsequently, the prepared PVA/PQ-10 cross-linked membranes are characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, mechanical analysis, water uptake and swelling ratio tests, ion exchange capacity (IEC) tests, ionic conductivity measurements, and oxidative/alkaline stability tests. The effects of the mass ratio of PVA and PQ-10 and the amount of cross-linking agent GA on the performance of the PVA/PQ-10 cross-linked membranes are systematically explored. The results show that the cross-linked PVA/PQ-10 AEMs have high IEC and low water uptake and swelling ratio, and its maximum ionic conductivity can reach 79.37 mS cm–1 at 80 °C. In addition, the PVA/PQ-10 cross-linked membrane has good oxidative and alkaline stability under optimal preparation conditions. These results may provide valuable insights toward more effective scheme designs and new, simple preparation methods for AEMs with s-IPN structures. 相似文献
8.
9.
10.