全文获取类型
收费全文 | 5732篇 |
免费 | 362篇 |
国内免费 | 129篇 |
专业分类
电工技术 | 16篇 |
综合类 | 277篇 |
化学工业 | 3756篇 |
金属工艺 | 55篇 |
机械仪表 | 45篇 |
建筑科学 | 71篇 |
矿业工程 | 93篇 |
能源动力 | 119篇 |
轻工业 | 572篇 |
水利工程 | 8篇 |
石油天然气 | 589篇 |
武器工业 | 10篇 |
无线电 | 54篇 |
一般工业技术 | 421篇 |
冶金工业 | 82篇 |
原子能技术 | 38篇 |
自动化技术 | 17篇 |
出版年
2024年 | 10篇 |
2023年 | 39篇 |
2022年 | 74篇 |
2021年 | 105篇 |
2020年 | 92篇 |
2019年 | 109篇 |
2018年 | 106篇 |
2017年 | 162篇 |
2016年 | 184篇 |
2015年 | 203篇 |
2014年 | 261篇 |
2013年 | 327篇 |
2012年 | 396篇 |
2011年 | 348篇 |
2010年 | 279篇 |
2009年 | 297篇 |
2008年 | 242篇 |
2007年 | 395篇 |
2006年 | 378篇 |
2005年 | 294篇 |
2004年 | 279篇 |
2003年 | 208篇 |
2002年 | 210篇 |
2001年 | 205篇 |
2000年 | 180篇 |
1999年 | 143篇 |
1998年 | 122篇 |
1997年 | 100篇 |
1996年 | 75篇 |
1995年 | 68篇 |
1994年 | 66篇 |
1993年 | 49篇 |
1992年 | 35篇 |
1991年 | 29篇 |
1990年 | 24篇 |
1989年 | 15篇 |
1988年 | 14篇 |
1987年 | 16篇 |
1986年 | 2篇 |
1985年 | 24篇 |
1984年 | 22篇 |
1983年 | 12篇 |
1982年 | 15篇 |
1980年 | 4篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1975年 | 1篇 |
1956年 | 1篇 |
排序方式: 共有6223条查询结果,搜索用时 34 毫秒
1.
Material encapsulation is a relatively new technique for coating a micro/nanosize particle or droplet with polymeric or inorganic shell. Encapsulation technology has many applications in various fields including drug delivery, cosmetic, agriculture, thermal energy storage, textile, and self-healing polymers. Poly(methyl methacrylate) (PMMA) is widely used as shell material in encapsulation due to its high chemical stability, biocompatibility, nontoxicity, and good mechanical properties. The main approach for micro/nanoencapsulation of materials using PMMA as shell comprises emulsion-based techniques such as emulsion polymerization and solvent evaporation from oil-in-water emulsion. In the present review, we first focus on the encapsulation techniques of liquid materials with PMMA shell by analyzing the effective processing parameters influencing the preparation of PMMA micro/nanocapsules. We then describe the morphology of PMMA capsules in emulsion systems according to thermodynamic relations. The techniques to investigation of mechanical properties of capsule shell and the release mechanisms of core material from PMMA capsules were also investigated. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48039. 相似文献
2.
The separation of iron oxide from banded hematite jasper(BHJ) assaying 47.8% Fe, 25.6% Si O2 and 2.30%Al2O3 using selective magnetic coating was studied. Characterization studies of the low grade ore indicate that besides hematite and goethite,jasper, a microcrystalline form of quartzite, is the major impurity associated with this ore. Beneficiation by conventional magnetic separation technique could yield a magnetic concentrate containing 60.8% Fe with 51% Fe recovery. In order to enhance the recovery of the iron oxide minerals, fine magnetite, colloidal magnetite and oleate colloidal magnetite were used as the coating material. When subjected to magnetic separation, the coated ore produces an iron concentrate containing 60.2% Fe with an enhanced recovery of56%. The AFM studies indicate that the coagulation of hematite particles with the oleate colloidal magnetite facilitates the higher recovery of iron particles from the low grade BHJ iron ore under appropriate conditions. 相似文献
3.
4.
Epoxy novolac/anhydride cure kinetics has been studied by differential scanning calorimetry under isothermal conditions. The system used in this study was an epoxy novolac resin (DEN431), with nadic methyl anhydride as hardener and benzyldimethylamine as accelerator. Kinetic parameters including the reaction order, activation energy and kinetic rate constants, were investigated. The cure reaction was described with the catalyst concentration, and a normalized kinetic model developed for it. It is shown that the cure reaction is dependent on the cure temperature and catalyst concentration, and that it proceeds through an autocatalytic kinetic mechanism. The curing kinetic constants and the cure activation energies were obtained using the Arrhenius kinetic model. A suggested kinetic model with a diffusion term was successfully used to describe and predict the cure kinetics of epoxy novolac resin compositions as a function of the catalyst content and temperature. Copyright © 2003 Society of Chemical Industry 相似文献
5.
6.
N-油酰基肌氨酸钠对除盐水缓蚀性能的探讨 总被引:1,自引:0,他引:1
梁劲翌 《石油化工腐蚀与防护》2006,23(1):17-20
对N-油酰基肌氨酸钠单体的缓蚀性能以及与常用除盐水缓蚀剂的协同作用作了探讨,发现在一定浓度下,单体对经过加氨调节后的高温除盐水(氨后除盐水)有良好的缓蚀作用,且与大多数除盐水缓蚀剂有良好的协同效应。在此基础上研制了一种复合药剂,并对其缓蚀、阻蚀性能作了研究。动电位极化曲线扫描图谱表明,该复合药剂属于抑制阳极腐蚀的阳极型缓蚀剂,其适用的水质条件为[Cl~-+SO_4~(2-)]不超过50 mg/L,pH不低于8.0;与阻垢剂复配,可以适用于含Ca~(2+)不超过45 mg/L的水质条件。 相似文献
7.
本文研究了用冠醚树脂二苯并-18-冠-6甲醛聚合物(简称PDB-18C6)对T1(Ⅰ),Au(Ⅲ),Cu(Ⅱ)的吸附行为。实验表明,在盐酸溶液中冠醚树脂的吸附效率顺序为Au(Ⅲ)>T1(Ⅰ)>Cu(Ⅱ)。用高氯酸和乙二醇乙醚淋洗T1(Ⅰ),Au(Ⅲ),它们的回收率一般在82-98.9%和98-100%。还在1.2m回旋加速器的外靶装置上,用25-27MeV的α粒子轰击金靶,累计束流强度为27μA·h,经处理分离后得到仅含0.50%~(200)T1的较高纯度的~(199)T1。 相似文献
8.
9.
镁钴铝类水滑石催化合成安息香甲醚 总被引:1,自引:0,他引:1
采用共沉淀法制备了镁钴铝类水滑石化合物(MgCoAl-HTLcs),并用 X 射线衍射、扫描电子显微镜、NH_3程序升温脱附等方法对 MgCoAl-HTLcs 进行了表征,并以 MgCoAl-HTLcs 为催化剂催化苯甲醛与甲醇反应合成安息香甲醚,研究了n(Mg):n(Co):n(Al)、催化剂用量、原料配比、反应温度、反应时间对合成反应的影响。表征结果显示,MgCoAl-HTLcs 的晶相完整,表面主要为弱酸、弱碱性。催化合成安息香甲醚的适宜条件为:MgCoAl-HTLcs 催化剂用量0.10 g(约为原料总质量的0.23%),n(Mg):n(Co):n(Al)=0.4:1.6:1.0,V(苯甲醛):V(甲醇)=3:50,反应温度50℃,反应时间150 min。在此条件下,苯甲醛的平衡转化率达77.49%,安息香甲醚选择性接近100%。为洁净合成安息香甲醚开辟了一条新的途径。 相似文献
10.
This study investigates the relationship between the critical surface tension of wetting of celestite and agglomeration recovery as well as the zeta potential in dependence of pH and amount of collector (Na‐Oleate). For this purpose, effects of pH and collector amount on the agglomeration recovery are investigated and zeta potential measurements and Fourier Transform Infrared Spectrophotometer (FTIR) analyses are carried out to determine the adsorption type of Na‐Oleate on celestite surface. The sessile drop technique is used for the measurement of contact angle and determination of the critical surface tension of wetting (YC) of celestite. The maximum agglomeration recovery is obtained at pH 7. The critical surface tension of wetting of celestite is very close to the surface tension of kerosene, which is 25.95 mN/m. Furthermore, at the optimum Na‐Oleate amount of 10 kg/ton, the critical surface tension of wetting of celestite is approximately equal to the surface tension of kerosene. 相似文献