海底沉积物中天然气水合物生成和分解规律研究进展

对国内外有关海底沉积物中天然气水合物生成和分解规律方面的研究进行了详细调研,得到如下结论:天然气水合物的生成和分解条件在海底沉积物中与在井筒、管道中有明显不同,其主要原因是多孔介质中流体与孔隙壁面间的界面效应对海底沉积物中天然气水合物的形成条件会产生明显影响;在海底沉积物中天然气水合物生成和分解条件的数值模拟技术研究方面,研究者大都假设以天然气水合物作为盖层的成藏类型,借助常规油气藏数值模拟技术进行模拟研究;影响海底沉积物中天然气水合物生成和分解条件的因素很多,因此海底沉积物中天然气水合物生成和分解规律研究必须借助试验模拟、数值模拟和现场测试相结合的综合方式进行。该调研成果可为今后天然气水合物经济有效开采技术方案选择和进行天然气水合物危害控制等提供参考。     

Baseline assessment of metals and hydrocarbons in the sediments of Lake Mulwala, Australia

An assessment of hydrocarbon and metal/metalloids (arsenic, cadmium, copper, lead, mercury, selenium, zinc) contamination in sediments from Lake Mulwala, Australia, was undertaken. The objectives of the study were: (i) to determine the extent of contamination in the lake sediments, compared to Australian and international sediment quality guidelines, and (ii) to attempt to identify the contaminant sources to the lake. With the exception of a few samples containing elevated levels of arsenic and/or mercury, the levels of all contaminants in the sediment samples taken from the lake were below the ‘lower trigger’ of the Australian Sediment Quality Guidelines that would warrant further investigation. High molecular weight hydrocarbons (up to 700 mg kg⁻¹) were found in most sediment samples. Non‐metric statistical analysis indicated that the contaminant distribution was different in different parts of the lake, with the lowest concentrations generally found at the influent to the lake. No definitive source(s) of contamination could be identified for either metalloids or hydrocarbons.     

Influence of Coherent Flow Structures on the Dynamics of Suspended Sediment Transport in Open-Channel Flow

The influence of suspended sediments on coherent flow structures has been studied by simultaneously measuring the longitudinal and vertical components of the instantaneous velocity vector and the instantaneous suspended particle concentration with an acoustic particle flux profiler. The measurements were carried out in clear water and in particle-laden open-channel flows. In both cases, they clearly show the predominance of ejection and sweep phases that are part of a burst cycle. The analysis further demonstrates the importance of the ejection and sweep phases in sediment resuspension and transport. Ejections pick up the sediment at the bed and carry it up through the water column close to the surface. It is shown that ejections and sweeps are in near equality in the near-bottom layer, whereas ejections clearly dominate in the remaining water column. The implications of these results for sediment transport dynamics are discussed.     

Monitoring water quality in reservoirs with IRS-1A-LISS-I

An attempt has been made to quantify the relationship between the variation in IRS-IA-LISS-I (Indian Remote Sensing Satellite-1A Linear Imaging Self-Scanning System) radiance data and field measured change in secchi disc depth. Secchi disc depth was measured for 47 predetermined sampling locations on reservoir surface water. At extinction depth (secchi depth), water samples were collected from all the sampling locations. Suspended sediments of eight locations representing various reaches of the reservoir were selected for mineralogical, particle size and optical properties analysis. The LISS-I radiance value in band 1 (0.45–0.52µm) band 2 (0-52–0.59 µm) and band 3 (0.62–0.68 µm) were used in a regression analysis. The absorption infrared band 4 (0.77–0.86 µm) was not included in the analysis. In these, the dependable variable was secchi depth (SD) and the LISS-I-radiance data was the estimator variable. Forty-seven data sets of 20 October 1988 from Tawa reservoir surface water were used to obtain an estimator equation for SD. The verification of the estimator equation was tested by applying it to a data set of 21 measurements of 28 September 1988 for this reservoir. The coefficient of correlation between observed and estimated values for the 28 September 1988 data set wasr=0.92 for SD, indicating that the equation could accurately predict the water clarity (SD) for this reservoir on new occasions from IRS-IA-LISS-I spectral data. It is shown that mineral composition and optical properties of suspended sediments influence the reflected radiance of water quality. It is concluded that IRS-IA-LISS-I data provide a useful means of mapping water quality in reservoir.     

Methane generation from Miocene lacustrine coals and organic-rich sedimentary rocks containing different types of organic matter

Ten selected samples with varying types and amounts of organic matter from two Miocene lacustrine basins in northwestern Turkey were analyzed by programmed-temperature open-system pyrolysis to determine methane generation potential and reaction kinetics. Open-system pyrolysis was performed at heating rates 0.1, 0.7 and 5.0 K/min, where generated gases were measured using an on-line gas chromatograph. Frequency factors and activation energy distributions of reaction kinetics for methane generation from the investigated lacustrine coals and sedimentary rocks indicated that type of kerogen controls the sequential order of methane generation. Methane from Type-III kerogen is generated at lower temperatures, which will be followed by methane from Type-II and Type-I kerogen. Methane generation potentials in the range 14-35 mg CH₄/g TOC correlates also with type of organic matter. For Type-III kerogen up to 28% of the total hydrocarbon generation potential belongs to methane. The respective value is only 2% for a Type-I kerogen.     

Variability of sedimentary phosphorus fractions in the western and Sandusky basins of Lake Erie

Surface sediments and three sediment cores from the western basin and one sediment core from the Sandusky basin were analyzed to document spatial and temporal changes in five phosphorus fractions and total phosphorus (TP). The areal distributions of the bioavailable fractions NaCl-Pi, NaBD-Pi, and NaOH-Pi and the refractory organic fraction Res-P were broadly consistent and contrasted with those of the detrital fraction HCl-Pi which showed that high concentrations occurred mostly in high-energy littoral zones and low concentrations largely in profundal depositional areas. The contrasting distributions were induced by interactions among tributary inputs, wave action, circulation, and biogeochemical cycling and transfer in the basin. As revealed by the Sandusky basin sediment record, the detrital fraction HCl-Pi was dominant (70% of TP) during European settlement and decreased rapidly by 28.0% in the early 1910s due largely to impoundments of the Maumee and Sandusky Rivers. While HCl-Pi has ever since remained relatively constant, NaCl-Pi, NaBD-Pi, and NaOH-Pi increased significantly between 1950 and 1970 in the two basins. However, the post-regulation sediment records differed considerably among these coring sites. There was a marked increase of TP in two cores, corresponding to recent return of eutrophication and massive harmful algal blooms but contrasting with a relatively constant, low loading into the lake. This signified the role of internal loading as derived partialy from legacy pollution. Furthermore, NaCl-Pi has increased progressively throughout all the records. We conclude that the increased levels of NaCl-Pi in surface sediments may have altered the internal loading and contributed to the resurgences of harmful algal blooms in Lake Erie.     

Restoring Murray River floodplain wetlands: Does the sediment record inform on watering regime?

The floodplain wetlands of the southern Murray Darling Basin (MDB) have been subject to the impacts of catchment and water resource development for more than a century. Their current degraded state is attributed to the regulation of the rivers and abstraction of water volume for irrigation. The MDB Plan is to return at least 2,750 Gl of mean annual flow to the system to restore the condition of waterways. Considerable recent investment in infrastructure enables water to be released into the basin's floodplain wetlands. The proposed watering regime is underpinned by modelling that suggests that, before regulation, overbank flows would have occurred regularly as discharge peaked in winter and spring. Sediment cores have been extracted from over 50 floodplain wetlands of the southern Murray Basin. Those from several, large meander wavelength billabongs extend for 1,000–5,000 years suggesting that these sites were permanently inundated over that time. Others extend to ~200 years and are presumed not to have accumulated sediment until more recently. The records of most wetlands, however, only extend to the onset of river regulation in the 1920s, suggesting that before then they were not inundated for sufficient duration for net accumulation to occur. Preserved diatoms suggest that the shallow, plant‐dominated wetlands of the past have transitioned to deep, turbid water systems today. As rivers are identified as a source of sediment to wetlands, less regular inundation, rather than more, is a viable option in restoring the ecological function of these floodplain wetlands and in slowing sediment infill.     

海底沉积物岩芯横向声学测量系统的标定

水平轴向测量技术相对成熟,但较难获取海底沉积物的无扰动分层声学特性,采用横向测量技术可以解决这一问题。文章研究了海底沉积物岩芯横向测量技术,将水作为海底沉积物测量的参考标准,进行测量系统的标定。提出了等效换能器的概念,将样品以外的声传播介质整合成等效换能器的一部分,标定测量等效换能器声延时和声传播初始能量。以水为标准介质,分别采用33、80、100 kHz三种频率的声学换能器,以及75、90、110 mm三种管径的聚氯乙烯(Polyvinyl Chloride,PVC),测量所得的水中的声速与标准计算水中的声速具有一致性,其中以采用80 kHz频率声学换能器和90 mm管径PVC管测量时的声速误差最小,选用此状态进行标定,得出当隔水耦合测量法换能器相对距离为142.02 mm时,标定的等效换能器声延时为45.88±0.08 μs,等效换能器声传播初始能量(以接收换能器的接收电压表示)为0.86±0.03 V。应用标定的等效换能器声延时和声传播初始能量测量海底沉积物。计算得到声速和声衰减系数符合黏土质粉砂的声学特性。     

GENOTOXICITY IN CHIRONOMUS KIIENSIS (CHIRONOMIDAE: DIPTERA) AFTER EXPOSURE TO POLLUTED SEDIMENTS FROM RIVERS OF NORTH PENINSULAR MALAYSIA: IMPLICATION FOR ECOTOXICOLOGICAL MONITORING

Rapid industrialization and urbanization has led to increasing input of chemical contaminants into the aquatic environment of Malaysia. Despite the threat civilization poses to the biota, there are still very few relevant studies on ecotoxicological testing of river ecosystems. To overcome this knowledge gap, we examined lethal and genotoxic effects of sediments from different rivers of the northern Malaysia against Chironomus kiiensis, a group well represented in the aquatic fauna of this region. We exposed the larvae to sediments from Selama River (SR), Permatang Rawa River (PRR) and Kilang Ubi River (KUR) at various durations (0, 6, 12, 24 and 48 h). The larval mortality was monitored, whereas DNA damage in survivors' cells was determined using the comet assay. Pollution level indexed by the amounts of heavy metals and other organic contaminants in the sediment showed progressive increases from SR to PRR to KUR. Highly polluted sediments (PRR to KUR) were detrimental to C. kiiensis larvae, most of which did not survive following exposure for long periods. DNA analyses revealed greater damages in nuclei derived from larvae maintained on polluted sediments, in particular, those from KUR. The effects on the genomic material of C. kiiensis larvae occurred in a time‐dependent manner, with damage level increasing as exposure time progressed. Our results highlight the genotoxic properties of polluted sediments. More importantly, this study showed that C. kiiensis larvae could respond to different levels of pollution with respect to exposure time. It is concluded that C. kiiensis larvae is a potential candidate for river ecotoxicological monitoring. Copyright © 2012 John Wiley & Sons, Ltd.     

烟台套子湾海域表层沉积物粒度分布特征及其动力响应

根据2010年10月采集的山东烟台套子湾大范围表层沉积物样品以及收集到的实测水文资料,分析研究套子湾海域表层沉积物的粒度分布特征,同时在应用GSTA模型对沉积物进行输运趋势分析的基础上,探讨该区域泥沙运移趋势.结果表明:整个套子湾内主要以细砂或极细砂和粉砂质砂为主,沉积物总体呈条带状分布向外逐渐变细;海区大部分区域的表层沉积物分选性都很好,相对与较小的潮流动力而言,波浪动力因素对泥沙的长期分选起到了主要作用;套子湾海域沉积物内细颗粒含量很少,平均值仅在3.49％,该海域细颗粒泥沙来源少,揭示了套子湾海域以波浪作用为主的沉积环境.应用GSTA模型对表层沉积物运移趋势分析结果显示,套子湾海域以垂直岸线横向输沙为主,近岸存在一定的纵向输沙,但强度不大,在优势浪垂岸入射和横向输沙作用控制下,纵向输沙强度较弱.