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1.
《International Journal of Hydrogen Energy》2022,47(25):12726-12738
The use of a Pt-based catalyst was evaluated for autocatalytic hydrogen recombination. The Pt was supported on a mixture of Ce-, Zr- and Y-oxides (CZY) to yield nanosized Pt particles. The Pt/CZY/AAO catalyst was then prepared by the spray-deposition of the Pt/CZY intermediate onto an anodized aluminium oxide (AAO) layer on a metallic aluminum core. The Pt/CZY/AAO catalyst (3 × 1 cm) was evaluated for hydrogen combustion (1–8 vol% hydrogen in the air) in a recombiner section testing station. The thermal distribution throughout the catalyst surface was investigated using an infrared camera. The maximum temperature gradient (ΔT) for the examined hydrogen concentrations did not exceed 36 °C. The Pt/CZY/AAO catalyst was also evaluated for prolonged hydrogen combustion duration to assess its durability. An average combustion temperature of 239.0 ± 10.0 °C was maintained for 53 days of catalytic hydrogen combustion, suggesting that there was limited, or no, catalyst deactivation. Finally, a Pt/CZY/AAO catalytic plate (14.0 × 4.5 cm) was prepared to investigate the thermal distribution. An average surface temperature of 212.5 °C and a maximum ΔT of 5.4 °C was obtained throughout the catalyst surface at a 3 vol% hydrogen concentration. 相似文献
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NaY晶化母液制备硅铝胶的技术探讨 总被引:3,自引:0,他引:3
在导向剂法合成Y型分子筛的工艺下,晶化母液中SiO2的含量为50~55g/l,Na2O含量为20~25g/l,相当于模数为1.65~2.58的稀水玻璃,将晶化母液分离处理后,在晶化母液中加入一定量的硫酸铝溶液使硅沉淀,经过滤和水洗后即可制备出合格的硅铝胶,以便进行重新利用。 相似文献
4.
Jatuporn Wittayakun Pongtanawat Khemthong Sanchai Prayoonpokarach 《Korean Journal of Chemical Engineering》2008,25(4):861-864
Rice husk silica (RHS) in amorphous phase with 98% purity was prepared from a waste rice husk from rice milling by leaching
with hydrochloric acid and calcination. The RHS was used effectively as a silica source for the synthesis of zeolite Y in
sodium form (NaY). The zeolite in pure phase was obtained from a two-step synthetic route in which the starting gels were
mixed, aged for 24 h at room temperature and crystallized for 24 h at 90 °C. The diameter of single crystal particles from
a scanning electron microscope was approximately 1.0 μm, whereas the average particle diameter from laser diffraction particle
size analyzer was approximately 10 μm because of the agglomeration of small crystals. Longer crystallization time in this
route resulted in a mixed phase containing NaY and zeolite P in sodium form (NaP). In addition, a one-step synthetic route
(no aging) was studied and the product was also a mixed phase zeolite. 相似文献
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Beatriz O. Hincapie Luis J. Garces Sinue Gomez Ruma Ghosh Steven L. Suib 《Catalysis Today》2005,110(3-4):323
Copper containing faujasite has been successfully prepared for the first time using a direct synthesis method. Faujasite type zeolite can be prepared in the presence of copper species by tuning the synthesis conditions. Ammonium hydroxide was used to form a copper complex that was later mixed with the reacting gel. Sodium is required to obtain copper faujasite. The complete elimination of sodium ions from the starting gel produces amorphous material. Crystallization took place at 358 K for 11 days. Crystallization temperature of 373 K produces ANA type zeolite as an impurity. Increasing by two times the amount of copper complex added to the reacting gel increases the crystallization time of Cu-FAU from 11 to 20 days (the crystallization rate decreases). The copper containing faujasite obtained was characterized by XRD, FESEM, EDX, EPR, FT-IR, TPR, and BET. According to the XRD pattern only FAU type zeolite was obtained. According to TPR experiments, the reduction temperature for Cu2+ ions present in Cu-FAU prepared by direct synthesis was 70 K more than for Cu-FAU prepared by ion-exchange. This difference can be due to the different location of the copper ions in the supercages or in the sodalite cages of the faujasite. 相似文献
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The Y2O3: Yb3 , Er3 microstructures were fabricated by a hydrothermal method without surfactants.The microstructures structure was characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM,KYKY 1000B).The up-conversion luminescence spectra were studied under 978 nm laser diode excitation.In Yb3 and Er3 codoped Y2 O3 microcrystals, the relative intensity of green emission became stronger as the morphology of sample changed from wires to films. 相似文献
9.
天桥水电站是黄河中游北干上的第一座高泥沙、低水头、大流量的径流式试验电站。它成功的施工与运营经验不仅对在黄河中游北干上开发梯级水电站,而且对中小型径流式水电站的施工都具有重要的借鉴作用。这篇文章总结了两期截流工程、基坑排水、固结灌浆、帷幕灌浆方面的施工经验。在诸如厂房位置的选择以及它的布置,泥沙、冰凌、洪水以及拦污方面的工程设计与运营的宝贵经验,使得水库长期保持高的有效库容和良好的运营状态。特剐是防止进水口淤积和水轮机的磨蚀方面的七条措施是非常有价值的。 相似文献
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