Comparative Assay of Antioxidant Packages for Dimer of Estolide Esters

A series of 26 different antioxidants and commercial antioxidant packages designed for petroleum‐based materials, containing both natural and synthetic‐based materials, were evaluated with dimeric coconut‐oleic estolide 2‐ethylhexyl ester (2‐EH), a bio‐based material. The different antioxidants were categorized into different classes of phenolic, aminic, and blended/others materials. The oxidation onset temperatures (OT) using non‐isothermal pressurized differential scanning calorimetry (PDSC) were measured and recorded under previously reported standard conditions. The aminic series gave the best resistance to oxidation as defined by the PDSC method with OT of 246.6 and 244.7 °C for the best two performers, which was a 38 °C improvement over the uninhibited or unformulated dimer estolide material. The phenolic series, containing most of the naturally occurring antioxidants, was the least successful formulation package for the dimer estolide. The blended/other materials, which were specifically designed for petroleum‐based lubricants, did not have the best OT, since the estolides and other bio‐based materials interact differently than their petroleum counterparts. A number of potential antioxidants have been identified as useful additives for the estolides esters. The OT of the estolide and formulated materials correlated well with other bio‐based materials such as biodiesel.     

Review of Motivational interviewing in the treatment of psychological problems.

Reviews the book, Motivational interviewing in the treatment of psychological problems by Hal Arkowitz, Henny A. Westra, William R. Miller, and Stephen Rollnick (2007). The purpose of this book is to describe applications of motivational interviewing (MI) to the treatment of a variety of psychological disorders. This excellent book, edited by the originators of MI (Miller and Rollnick) along with two highly regarded scientist-practitioners (Arkowitz and Westra), begins with an introduction to the spirit and techniques of MI and provides an overview of the ways in which MI has been applied in clinical practise. The main portion of the book consists of 11 chapters written by foremost MI experts describing the use of MI in their research and clinical work treating anxiety disorders, depression, pathological gambling, eating disorders, and schizophrenia spectrum disorders, as well as the use of MI in the corrections system and with suicidal and dually diagnosed patients. Each chapter is similarly organised and offers a brief overview of the clinical population and treatment as usual, a rationale for using MI in treatment, a summary of available research regarding the use of MI in the population, and detailed examples of clinical applications of MI to treatment, including problems and suggested solutions. The chapters are well written and informative, with many offering vivid clinical examples. It is difficult to identify any significant weaknesses. There is some redundancy throughout the text, particularly with regard to the general spirit, principles, and techniques of MI. This is likely intentional and meant to reiterate important points; it also nicely allows each chapter to stand alone. In sum, this terrific book provides a highly readable and informative account of the application of MI to the treatment of psychological problems. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Photochemistry on a polarisable semi-conductor: what do we understand today?

The continued development of ferroelectric materials into more and more consumer led applications has been at the forefront of recent ferroelectric material research. It is, however, possible to view a ferroelectric as a wide band gap semi-conductor that can sustain a surface charge density. This charge density arises from the movement of ions in the crystal lattice and the need to compensate for this charge. When viewing ferroelectrics as polarisable semi-conductors a large number of new interactions are possible. One such is the use of super band gap illumination to generate electron–hole pairs. These photogenerated carriers can then perform local electrochemistry. What is most interesting for ferroelectric materials is that the REDOX chemistry can be chosen by selectively modifying the domain structure of the ferroelectric—we can perform oxidation and reduction on the surface of the same material at spatially separate locations, or use the material to drive photoexcited carriers apart. This means we can separate the REDOX products or produce patterns of photogenerated material in places we have predetermined. This review aims to introduce the background research that has led to the current understanding as well a highlight some of the current areas that require further development.     

The adsorption of an epoxy acrylate resin on aluminium alloy conversion coatings

A thermodynamic study of the adsorption of an epoxy acrylate resin used for UV-cured coatings on two different anticorrosion pretreatments on aluminium alloys relevant to aerospace industry has been undertaken. Aluminium alloy Al2219 specimens, treated with an inorganic chromate based conversion coating (Alodine 1200S) and an organic titanium based conversion coating (Nabutan STI/310), were immersed in solutions of different concentrations of the resin and adsorption isotherms were determined by assessing the uptake of the adsorbate, as a function of solution concentration, by time-of-flight secondary ion mass spectrometry (ToF-SIMS). The results show different behaviour for the two substrates, which can be attributed to the organic component of the titanium based coating. In the case of the inorganic conversion coating a clear plateau is achieved at relatively low concentrations and at a lower level of adsorption than for the hybrid coating. The data for both the coatings conform well to the Langmuir model, the organic coating, as well as showing a higher level of adsorption of the resin, also presents oscillatory behaviour at low concentration, which is shown to be complementary to the behaviour of the reactive diluent included with the epoxy acrylate to aid processing. A discussion of this competitive adsorption of the epoxy resin and the diluent on the different substrates is presented, based on considerations of the chemistry of the systems under investigation.     

Design and initial operation of a 367-m2 rectangular ring laser

The design and operation of a proof-of-principle rectangular He-Ne ring laser resonator with a cavity perimeter of 77.0 m and an area of approximately 367 m2 are described. With unevacuated beam lines this device gave an Earth-induced Sagnac frequency of 1513 Hz, with a relative Allan deviation over 1000 s down to 3 parts per million. The Earth's rotation provided a bias that eliminated the lock-in susceptibility. The use of increased pressure in the plasma tube facilitated single-mode operation by increasing the homogeneous pressure-broadened linewidth.     

Guest Editors' Editorial

Editorial Commentary

Guest Editors' Editorial     

电力系统低频振荡和储能系统

研究了将能量储存系统用于提高电力系统振荡稳定性的潜力。首先简要回顾了过去40年中在电力系统振荡稳定性领域的研究和应用的发展情况，包括电力系统振荡稳定性的分析和控制；然后论述了在电力系统中应用能量储存系统的不同课题；第3部分重点讨论了用能量储存系统改善电力系统振荡稳定性问题；最后提出了一些建议。