全文获取类型
收费全文 | 847篇 |
免费 | 52篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 16篇 |
综合类 | 1篇 |
化学工业 | 317篇 |
金属工艺 | 37篇 |
机械仪表 | 12篇 |
建筑科学 | 16篇 |
矿业工程 | 3篇 |
能源动力 | 50篇 |
轻工业 | 20篇 |
水利工程 | 11篇 |
石油天然气 | 4篇 |
无线电 | 52篇 |
一般工业技术 | 193篇 |
冶金工业 | 88篇 |
原子能技术 | 10篇 |
自动化技术 | 72篇 |
出版年
2024年 | 2篇 |
2023年 | 13篇 |
2022年 | 10篇 |
2021年 | 34篇 |
2020年 | 28篇 |
2019年 | 23篇 |
2018年 | 36篇 |
2017年 | 44篇 |
2016年 | 38篇 |
2015年 | 27篇 |
2014年 | 44篇 |
2013年 | 76篇 |
2012年 | 46篇 |
2011年 | 48篇 |
2010年 | 50篇 |
2009年 | 35篇 |
2008年 | 46篇 |
2007年 | 29篇 |
2006年 | 39篇 |
2005年 | 29篇 |
2004年 | 19篇 |
2003年 | 9篇 |
2002年 | 10篇 |
2001年 | 13篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 16篇 |
1997年 | 10篇 |
1996年 | 12篇 |
1995年 | 10篇 |
1994年 | 7篇 |
1993年 | 11篇 |
1992年 | 10篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 8篇 |
1988年 | 6篇 |
1987年 | 10篇 |
1986年 | 9篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1977年 | 6篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1970年 | 2篇 |
排序方式: 共有902条查询结果,搜索用时 187 毫秒
1.
The increase in the production of acid gas consisting of H2S, CO2, and associated impurities such as ammonia and hydrocarbons from oil and gas plants and gasification facilities has stimulated the interest in the development of alternative means of acid gas utilization to produce hydrogen and sulfur, simultaneously. The present literature lacks a detailed reaction mechanism that can reliably predict the thermal destruction of NH3 and its blend with H2S and CO2 to facilitate process optimization and commercialization. In this paper, a detailed mechanism of NH3 pyrolysis is developed and is merged with the reactions of NH3 oxidation and H2S/CO2 thermal decomposition from our previous works. The mechanism is validated successfully using different sets of experimental data on the pyrolysis and oxidation of NH3, H2S, and CO2. The proposed mechanism predicts the experimental data on NH3 pyrolysis remarkably better than the existing mechanisms in the literature. The mechanism is used to investigate the effects of NH3 concentration (0–20%) and reactor temperature (1000–1800 K) on the thermal decomposition of H2S and CO2. A synergistic effect is observed in the simultaneous decomposition of NH3 and CO2, i.e., NH3 conversion is improved in the presence of CO2 and the decomposition CO2 to CO is enhanced in the presence of NH3. The presence of H2S suppressed NH3 conversion, while the conversion of H2S remained unchanged with increasing NH3 concentration at temperature below 1400 K due to the low conversion of NH3 (up to 18%). At temperature above 1400 K, NH3 conversion increased rapidly and it triggered a decrease in H2S conversion as well as the yields of H2 and S2. The major reactions involved in the decomposition of H2S, CO2, and NH3 and the production of major products such as H2, S2, and CO are identified. The detailed reaction mechanism can facilitate the design and optimization of acid gas thermal decomposition to produce hydrogen and sulfur, simultaneously. 相似文献
2.
Sustainable biocomposites have gained considerable interest as an alternative to conventional composites in recent years due to their cost-effectiveness and environmental friendliness. The aim of this study was to investigate the performance and durability behavior of biocomposites from sustainable biocarbon (BC) as compared to conventional established fillers. The poly(butylene terephthalate) (PBT) and its composites reinforced with BC, talc, and glass fiber (GF) were prepared and the durability performances was investigated. The study showed that BC/PBT biocomposites provided a lighter weight alternative to traditionally used fillers. After undergoes thermo-oxidative aging, the mechanical properties of BC/PBT biocomposite were deteriorated. The GF/PBT showed the most stable in retaining its mechanical properties in comparison to the talc/PBT and BC/PBT. The aging behavior and mechanism of the PBT composites were discussed. This study provides further insight on the durability-related properties progression of biocomposites as compared to traditional used fillers. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47722. 相似文献
3.
Hyungson Ki Jyoti Mazumder Pravansu S. Mohanty 《Metallurgical and Materials Transactions A》2002,33(6):1817-1830
A three-dimensional laser-keyhole welding model is developed, featuring the self-consistent evolution of the liquid/vapor
(L/V) interface together with full simulation of fluid flow and heat transfer. Important interfacial phenomena, such as free
surface evolution, evaporation, kinetic Knudsen layer, homogeneous boiling, and multiple reflections, are considered and applied
to the model. The level set approach is adopted to incorporate the L/V interface boundary conditions in the Navier-Stokes
equation and energy equation. Both thermocapillary force and recoil pressure, which are the major driving forces for the melt
flow, are incorporated in the formulation. For melting and solidification processes at the solid/liquid (S/L) interface, the
mixture continuum model has been employed. The article consists of two parts. This article (Part I) presents the model formulation
and discusses the effects of evaporation, free surface evolution, and multiple reflections on a steady molten pool to demonstrate
the relevance of these interfacial phenomena. The results of the full keyhole simulation and the experimental verification
will be provided in the companion article (Part II). 相似文献
4.
5.
6.
7.
8.
9.
S. Sarkar P. K. Singha S. Dey M. Mohanty B. Adhikari 《Materials and Manufacturing Processes》2006,21(3):291-296
A polyester urethane was synthesized for use in a biodegradable scaffold. The polyurethane was synthesized in a two-step process: first, ester diol was synthesized from lactic acid and polyethylene glycol 400 (PEG 400), then it was polymerized with toluene diisocyanate using dibutyl tin dilaurate (DBTDL) as a catalyst to form a polyester urethane. Polyester urethane has tensile strength of 51-59 MPa and elongation at fracture of 369-439%. FTIR and XRD were used to confirm the formation and structure of the polymer. Hydrolytic degradation was studied in different alkali solutions and in saline water. In order to assess the cellular response of this material, cytotoxicity analysis was carried out against the cell line. 相似文献
10.
Jantana Tangaromsuk Abhijeet P. Borole Maleeya Kruatrachue Prayad Pokethitiyook 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(10):1375-1380
BACKGROUND: A single‐stage reactor, in which the growth of bacterial culture, induction of desulfurizing enzymes, and desulfurization reaction are carried out in a single step, was adopted to investigate desulfurization of dibenzothiophene (DBT) at high cell densities. Rhodococcus erythropolis, IGTS8 was used as the biocatalyst. Optimal conditions for bacterial growth and DBT desulfurization were investigated. RESULTS: Optimization of fermentation conditions was necessary to obtain high cell densities including controlling accumulation of acetate. Under optimal operating conditions, the maximum optical density at 600 nm (OD600) was measured to be 26.6 at 118 h of cultivation. When biodesulfurization of DBT in model oil with a high cell density culture of IGTS8 was investigated, accumulation of sulfate was found to limit the extent of desulfurization. A sulfate removal step was added to obtain a single‐stage integrated biodesulfurization process. Sulfate removal was achieved via an aqueous bleed stream and use of a separation unit to recycle the organic phase. CONCLUSION: A proof of principle of a complete system capable of biocatalyst growth, induction, desulfurization and by‐product separation was demonstrated. This system enables simplification of the biodesulfurization process and has potential to lower the operating cost of the bioprocess. Copyright © 2008 Society of Chemical Industry 相似文献