Ion Chromatographic Determination of Free Cyanide in Different Classes of Bottled Natural Mineral Water Consumed in Turkey

An ion chromatographic method for the quantitative determination of free cyanide in bottled natural mineral waters were measured in terms of selectivity, linearity, the limit of detection, limit of quantification, repeatability, precision, and accuracy. Chromatographic separation of free cyanide ions was accomplished with an anion-exchange column and detected by pulsed amperometric detection with a silver working electrode. The method was found to be selective, linear (r² = 0.999) at a concentration range of 0.5 to 134 μg L^?1, precise, and accurate. Recovery values of free cyanide in all classes of natural mineral water varied from 65.9 ± 1.6 to 95.2 ± 0.7 at different spiking levels (5–70 μg L^?1). Parameters (total dissolved solids, mineral interferences, and added sodium hydroxide) affecting the recovery values were studied in this project. The limit of detection and limit of quantification were found to be 0.295 and 0.983 μg L^?1, respectively. The proposed method was applied to 27 different brands of commercially available bottled natural mineral water products sold in Turkish markets. These natural mineral waters were classified as: (i) very low mineral concentration, (ii) low mineral concentration, (iii) intermediate mineral concentration, and (iv) high mineral concentration based on their total dissolved solids contents according to European Union Directive (Directive 80/777/EEC). Levels of free cyanide residues in the samples ranged from > limit of detection to 6.12 μg L^?1. The highest average concentration of free cyanide residues was found in the class of “high mineral concentration waters.” However, the determined free cyanide values in all of the tested natural mineral water samples were found to be within the limits of European Union legislation.     

Polymer electrolyte membrane fuel cell contamination: Testing and diagnosis of toluene-induced cathode degradation

The effects of toluene contamination on the performance of polymer electrolyte membrane (PEM) fuel cells were investigated, using various levels of toluene concentration in the air streams, under different operational conditions and with different catalyst loadings. Constant-current polarization and electrochemical impedance spectroscopy (EIS) were conducted to analyze the poisoning behaviour of toluene. The severity of the contamination effect increased with an increase in both the current density and the toluene concentration, but decreased with an increase in both the relative humidity (RH) and the cathode-side Pt loading. The toluene-poisoned fuel cell could not be fully recovered by replacing toluene-contaminated air with pure air. EIS measurements revealed that both kinetic resistance and mass transfer resistance increased as a result of toluene contamination, while membrane resistance remained unchanged. However, the increase in kinetic resistance was a major contributor to cell performance degradation.     

New genetic algorithms (GA) to optimize PWR reactors: Part III: The Haling power depletion method for in-core fuel management analysis

The Haling Power Distribution (HPD) has been applied in a unique process to greatly accelerate the in-core fuel management optimization calculations. These calculations involve; the arrangement of fuel assemblies (FAs) and the placement of Burnable Poisons (BPs) in the fresh FAs. The HPD deals only with the arrangement of FAs. The purpose of this paper is to describe past uses of the HPD, provide an example selected from many similar calculations to explain why and how it can be used, and also to show its effectiveness as a filter in the GARCO GA code. The GARCO (Genetic Algorithm Reactor Core Optimization) is an innovative GA code that was developed by modifying the classical representation of the genotype and GA operators. A reactor physics code evaluates the LPs in the population using the HPD Method, which rapidly depletes the core in a single depletion step with a constant power distribution. The HPD is used basically in GARCO as a filter to eliminate invalid LPs created by the genetic operators, to choose a reference LP for BP optimization, and to create an initial population for simultaneous optimization of the LP and BP placement into the core. The accurate depletion calculation of the LP with BPs is done with the coupled lattice and reactor physics CASMO-4/SIMULATE3 package. However, the fact that these codes validate safety of the core with the added BP placement design also validates the use of the HPD method. The calculations are applied to the TMI-1 core as an example PWR providing concrete results.     

Effects of premixed diethyl ether (DEE) on combustion and exhaust emissions in a HCCI-DI diesel engine

In this study, the effects of premixed ratio of diethyl ether (DEE) on the combustion and exhaust emissions of a single-cylinder, HCCI-DI engine were investigated. The experiments were performed at the engine speed of 2200 rpm and 19 N m operating conditions. The amount of the premixed DEE was controlled by a programmable electronic control unit (ECU) and the DEE injection was conducted into the intake air charge using low pressure injector. The premixed fuel ratio (PFR) of DEE was changed from 0% to 40% and results were compared to neat diesel operation. The percentages of premixed fuel were calculated from the energy ratio of premixed DEE fuel to total energy rate of the fuels. The experimental results show that single stage ignition was found with the addition of premixed DEE fuel. Increasing and phasing in-cylinder pressure and heat release were observed in the premixed stage of the combustion. Lower diffusion combustion was also occurred. Cycle-to cycle variations were very small with diesel fuel and 10% DEE premixed fuel ratio. Audible knocking occurred with 40% DEE premixed fuel ratio. NO_x-soot trade-off characteristics were changed and improvements were found simultaneously. NO_x and soot emissions decreased up to 19.4% and 76.1%, respectively, while exhaust gas temperature decreased by 23.8%. On the other hand, CO and HC emissions increased.     

Foaming of rigid PVC/wood‐flour composites through a continuous extrusion process

The effects of chemical foaming agent (CFA) types (endothermic versus exothermic) and concentrations as well as the influence of all‐acrylic processing aid on the density and cell morphology of extrusion‐foamed neat rigid PVC and rigid PVC/wood‐flour composites were studied. Regardless of the CFA type, the density reduction of foamed rigid PVC/wood‐flour composites was not influenced by the CFA content. The cell size, however, was affected by the CFA type, independent of CFA content. Exothermic foaming agent produced foamed samples with smaller average cell sizes compared to those of endothermic counterparts. The experimental results indicate that the addition of an all‐acrylic processing aid in the formulation of rigid PVC/wood‐flour composite foams provides not only the ability to achieve density comparable to that achieved in the neat rigid PVC foams, but also the potential of producing rigid PVC/wood‐flour composite foams without using any chemical foaming agents.     

Improving the accuracy of contact-type drawbead elements in panel stamping analysis

A finite element modeling technique is proposed to improve the accuracy of contact-type drawbead elements in panel forming analyses, and a performance assessment in terms of part border and thickness predictions is presented in conjunction with panel stamping experiments of two automotive sheets. Inherent model limitations causing incorrect part geometry and thickness predictions are, firstly, evaluated considering blank deformations on a plain–strain section of a stamping die. The influence of omitted drawbead geometry and overestimated drawbead exit thickness are described analytically, and a closed form expression is obtained to correct draw-in model error. Then a sectional deformation model is used to calculate restraint force and drawbead exit thickness for a particular blank and drawbead design. The proposed technique is applied in process modeling of polygon shaped panels made of draw-quality and bake-hardenable steels. Three bead penetrations were investigated in process simulations as well as in stamping experiments. The same blankholder force was applied in all process conditions. Computed draw-in and thickness distributions were compared with on-part measurements using an experimental panel-draw die. It was determined that drawbead models based on force parameters only resulted in remarkably high thickness values at the die entry and mostly overestimated draw-in along panel border lines. An evaluation of thickness distributions computed with proposed technique showed an improved correlation with experiment results of both blank materials and confirmed the use of the drawbead exit thickness as a drawbead modeling parameter. Effects of bead penetration on panel border lines were also simulated in accord with stamping experiments.     

A review of all‐vanadium redox flow battery durability: Degradation mechanisms and mitigation strategies

The all‐vanadium redox flow battery (VRFB) is emerging as a promising technology for large‐scale energy storage systems due to its scalability and flexibility, high round‐trip efficiency, long durability, and little environmental impact. As the degradation rate of the VRFB components is relatively low, less attention has been paid in terms of VRFB durability in comparison with studies on performance improvement and cost reduction. This paper reviews publications on performance degradation mechanisms and mitigation strategies for VRFBs in an attempt to achieve a systematic understanding of VRFB durability. Durability studies of individual VRFB components, including electrolyte, membrane, electrode, and bipolar plate, are introduced. Various degradation mechanisms at both cell and component levels are examined. Following these, applicable strategies for mitigating degradation of each component are compiled. In addition, this paper summarizes various diagnostic tools to evaluate component degradation, followed by accelerated stress tests and models for aging prediction that can help reduce the duration and cost associated with real lifetime tests. Finally, future research areas on the degradation and accelerated lifetime testing for VRFBs are proposed.     

Removal of ciprofloxacin from aqueous solution using wheat bran as adsorbent

Current study describes sorption of antibiotic drug (ciprofloxacin) by using nontoxic and biocompatible carrier, i.e., wheat bran (WB). For sorption study, various parameters were optimized and Freundlich, Dubinin–Radushkevich, Langmuir, and Temkin isotherm models were applied to demonstrate the mechanism of sorption, while kinetics study for sorption was evaluated using diffusion models, pseudo-first-order kinetic (Langergren) and pseudo-second-order (Ho and McKay) kinetic models. In addition, thermodynamics study was also carried out. However, sorption of ciprofloxacin was pH depended and it showed 75% drug release in alkaline medium (at pH = 1.5) indicating the good release ability of WB for ciprofloxacin.