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101.
In this study, we aimed to reduce the cure time, and to lower the cure temperature of the benzoxazine compound. Therefore, curing reaction of benzoxazine with bisoxazoline or epoxy resin using the latent curing agent and the properties of the cured resins were investigated. The cure behavior of benzoxazine with bisoxazoline or epoxy resin using the latent curing agent was monitored by differential scanning calorimetry and measurements for storage modulus (G′). The properties of the cured resin were estimated by mechanical properties, electrical insulation, water resistance, heat resistance, and flame resistance. As a result, it was confirmed that by using the latent curing agent, cure time of benzoxazine and bisoxazoline or epoxy resin was reduced, and cure temperature was lowered. And it was found that the curing reaction using phenol‐novolac based benzoxazine (Na) as the benzoxazine compound could proceed more rapidly than that using bisphenol‐A based benzoxazine (Ba) as the benzoxazine compound. However, the cured resins from Ba and bisoxazoline or epoxy resin using the latent curing agent showed good heat resistance, flame resistance, and mechanical properties compared with those from Na and bisoxazoline or epoxy resin using the latent curing agent. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
102.
103.
Joaquim M. Oliveira Noriko Kotobuki Alexandra P. Marques Rogério P. Pirraco Johan Benesch Motohiro Hirose Silgia A. Costa João F. Mano Hajime Ohgushi Rui L. Reis 《Advanced functional materials》2008,18(12):1840-1853
Novel highly branched biodegradable macromolecular systems have been developed by grafting carboxymethylchitosan (CMCht) onto low generation poly(amidoamine) (PAMAM) dendrimers. Such structures organize into sphere‐like nanoparticles that are proposed to be used as carriers to deliver bioactive molecules aimed at controlling the behavior of stem cells, namely their proliferation and differentiation. The nanoparticles did not exhibit significant cytotoxicity in the range of concentrations below 1 mg mL?1, and fluorescent probe labeled nanoparticles were found to be internalized with highly efficiency by both human osteoblast‐like cells and rat bone marrow stromal cells, under fluorescence‐activated cell sorting and fluorescence microscopy analyses. Dexamethasone (Dex) has been incorporated into CMCht/PAMAM dendrimer nanoparticles and release rates were determined by high performance liquid chromatography. Moreover, the biochemical data demonstrates that the Dex‐loaded CMCht/PAMAM dendrimer nanoparticles promote the osteogenic differentiation of rat bone marrow stromal cells, in vitro. The nanoparticles exhibit interesting physicochemical and biological properties and have great potential to be used in fundamental cell biology studies as well as in a variety of biomedical applications, including tissue engineering and regenerative medicine. 相似文献
104.
解释了为什么以利润为目的的公司参与标准化活动和特别关注标准与专利的关系,并从经济学角度,使用反公共的悲剧和跨越式发展的概念分析了这个问题.反公共的悲剧解释了为什么公司交叉授权他们的专利许可以及为什么标准化组织的专利政策包含交叉授权.跨越式发展解释了为什么拥有为实施标准的必要专利的公司将他们的专利许可授予没有相关专利的公司.通过向外授予专利许可,公司在短期内可以获得经济利益,在长期可以获得影响市场发展的战略机会,并为民营公司提供一些建议. 相似文献
105.
The Okinawan folks in Japan use Ficus pumila L. as a beverage or herbal medicine to treat diabetes and high blood pressure. Four flavonoid glycosides were isolated and identified as rutin (1 and 3), apigenin 6-neohesperidose (2), kaempferol 3-robinobioside (4) and kaempferol 3-rutinoside (5). Among these compounds, rutin exhibited the strongest antioxidant activity in DPPH radical scavenging assay and superoxide radical inhibition assay. The preparation of Ooitabi leaves in water provide sufficient amount of flavonoid glycosides to the Okinawan although 50% of aqueous ethanol extracted these flavonoid glycosides more effectively. These results show the potential of Ooitabi leaves as a natural source of antioxidant for health management. 相似文献
106.
Shigeru Katayama Rio Yamazaki Hikaru Umise Hsu Pei Han Toshihiro Mihara Kimiko Uchiyama Hajime Takahashi Soichiro Nakamura 《Molecular nutrition & food research》2023,67(16):2200212
Scope
Ultraviolet B (UVB) radiation causes skin barrier dysfunction, leading to decreased water-holding capacity, impaired epidermal barrier function, and increased skin thickness. This study investigates the protective effects of oral administration of Lacticaseibacillus paracasei K71 against skin barrier dysfunction in UVB-irradiated mice.Methods and results
Mice are fed diets with or without K71 and irradiated with UVB three times a week for 12 weeks. Oral administration of K71 suppresses UVB-induced decrease in stratum corneum water content, mitigates the increase of transepidermal water loss, and decreases epidermal thickness of the dorsal skin. Treatment with K71 reverses the upregulation of inflammatory cytokines and the activation of nuclear factor-κB induced by UVB irradiation and upregulates the expression of anti-inflammatory IL-10 in the dorsal skin. Notable upregulation of IL-10 is observed in the spleens of K71-treated mice. K71 treatment enhances IL-10 production in J774.1 macrophages; however, this enhancement is diminished by inhibiting K71 phagocytosis and TLR3. Furthermore, transfection using K71 RNAs significantly increases IL-10 production.Conclusion
These results indicate that K71 may alleviate UVB-induced skin barrier dysfunction by attenuating inflammation via increasing IL-10 production and that K71 RNAs may induce IL-10 production in macrophages. Therefore, K71 may be beneficial for preventing skin barrier dysfunction. 相似文献107.
Diabetes mellitus is a major cause of chronic kidney disease and end-stage renal disease. However, the management of chronic kidney disease, particularly diabetes, requires vast improvements. Recently, sodium-glucose cotransporter-2 (SGLT2) inhibitors, originally developed for the treatment of diabetes, have been shown to protect against kidney injury via glycemic control, as well as various other mechanisms, including blood pressure and hemodynamic regulation, protection from lipotoxicity, and uric acid control. As such, regulation of these mechanisms is recommended as an effective multidisciplinary approach for the treatment of diabetic patients with kidney disease. Thus, SGLT2 inhibitors are expected to become key drugs for treating diabetic kidney disease. This review summarizes the recent clinical evidence pertaining to SGLT2 inhibitors as well as the mechanisms underlying their renoprotective effects. Hence, the information contained herein will advance the current understanding regarding the pleiotropic effects of SGLT2 inhibitors, while promoting future research in the field. 相似文献
108.
ABSTRACTMode conversion between higher-order modes is attained in a step-index four mode fibre using an in-line polarization controller followed by a force-induced long period fibre grating. By adjusting the field orientation of the LP11 mode to the antisymmetric fibre grating, the LP11 mode is converted to the LP21 mode with a spatially periodic force of 50 N along the fibre length of 50?mm. The mode conversion is evaluated by observing the far-field and near-field patterns of the fibre output and by comparing the transmitted optical power with and without the additional two-mode fibre. The phase-matching grating period is required of the accuracy of roughly ±5?μm and the radiation loss during the mode conversion is as low as 0.01?dB. 相似文献
109.
Large Magnetovolume Effect Induced by Embedding Ferromagnetic Clusters into Antiferromagnetic Matrix of Cobaltite Perovskite 下载免费PDF全文
Ping Miao Xiaohuan Lin Akihiro Koda Sanghyun Lee Yoshihisa Ishikawa Shuki Torii Masao Yonemura Takashi Mochiku Hajime Sagayama Shinichi Itoh Kazutaka Ikeda Toshiya Otomo Yinxia Wang Ryosuke Kadono Takashi Kamiyama 《Advanced materials (Deerfield Beach, Fla.)》2017,29(27)
Materials that show negative thermal expansion (NTE) have significant industrial merit because they can be used to fabricate composites whose dimensions remain invariant upon heating. In some materials, NTE is concomitant with the spontaneous magnetization due to the magnetovolume effect (MVE). Here the authors report a new class of MVE material; namely, a layered perovskite PrBaCo2O5.5+x (0 ≤ x ≤ 0.41), in which strong NTE [β ≈ ?3.6 × 10?5 K?1 (90–110 K) at x = 0.24] is triggered by embedding ferromagnetic (F) clusters into the antiferromagnetic (AF) matrix. The strongest MVE is found near the boundary between F and AF phases in the phase diagram, indicating the essential role of competition between the F‐clusters and the AF‐matrix. Furthermore, the MVE is not limited to the PrBaCo2O5.5+x but is also observed in the NdBaCo2O5.5+x . The present study provides a new approach to obtaining MVE and offers a path to the design of NTE materials. 相似文献
110.
Yasuaki Okamoto Hajime Nakano Takafumi Shimokawa Toshinobu Imanaka Shiichiro Teranishi 《Journal of Catalysis》1977,50(3):447-454
The promotional effects of Co in hydrodesulfurization (HDS) catalysts were studied by means of X-ray photoelectron spectroscopy. The higher MoO3-content catalysts (10 and 20 wt% MoO3) contain mobile Mo, which migrates from the pores to the outermost surface layers of the catalysts and segregates to form less active crystalline MoS2 during the HDS reaction, while in the case of (5 wt% MoO3) catalyst: no migration of Mo was observed. It is revealed that the Co in catalyst inhibits the migration and segregation of Mo and that it keeps Mo effective for the HDS reaction, since no surface enrichment of Mo was observed. It is concluded that stabilization of the Mo monomolecular layer is the main role of Co. The active species of Mo is suggested to have the composition of S/Mo(IV) = 1 on the basis of the sulfur contents of the catalysts under the mild HDS reaction conditions. 相似文献