宽条带与离层注浆开采地表移动计算

本文根据宽条带与离层注浆联合开采的工程实践,推导了该种采矿方法地表移动理论计算公式,从理论上完善了该项技术,为更好地推广该技术打下理论基础.     

Rheological studies of hyaluronan solutions based on the scaling law and constitutive models

We have investigated the scaling relationship between rheological behavior and concentration for both salt-free and saline solutions of hyaluronan (HA), and adopted three viscoelastic constitutive models to predict the linear/non-linear viscoelastic behavior of these aqueous solutions of HA with different molecular weights at different concentrations up to 20 mg/ml. A series of concentration equations are obtained to describe the influence of HA concentration on solution viscosity. Corresponding to dilute and semi-dilute concentration region, salt-free HA solutions have scaling relationship between specific viscosity and HA concentration as η_sp ∼ c^1.0 and η_sp ∼ c^3.5, respectively, while for 0.15 M NaCl HA solutions, the scaling exponents are 1.5 and 4.2, respectively. Simulation results indicate that these constitutive models have good applicability to describe quantitatively the rheological properties of HA entangled solutions under either dynamic or steady shear flow. In addition, the plateau modulus scaling of HA solutions can be well described by the concentration-dependent length scale.     

环氧固化剂硫脲改性四乙烯五胺的合成及性能研究

用硫脲改性四乙烯五胺合成了环氧树脂固化剂。通过测量初凝时间和接触角,讨论了反应时间、合成温度和单体投料比对固化剂性能的影响。通过热效应法考查了固化剂与环氧树脂的最佳配比。实验结果表明,反应时间为3 h,反应温度为130℃,四乙烯五胺与硫脲的质量比为1.4∶1时,合成的固化剂较好。当m固化剂∶m环氧=1∶4时,胶粘剂能在-5℃/8 d内固化,有效提高固化体系在低温下的固化能力。     

人工砂配制C60超高层泵送混凝土

本文主要研究利用人工砂配制高强度C60超高层(51层232.5m)一次性泵送混凝土,解决人工砂高强度混凝土在高扩展度(600mm)、高温季节3～4小时,离析沉底可泵性差现象;减少管道的摩擦及混凝土自身重力、泵送压力造成的混凝土坍落度损失、粘性增加;有效避免高强度大体积混凝土产生的裂缝。     

High-temperature fatigue behavior of SiC-coated carbon/carbon composites in oxidizing atmosphere

Tensile fatigue-stressed oxidation experiments were conducted at 1300 °C in oxidizing atmosphere to identify the failure modes and degradation mechanism of a SiC-coated carbon/carbon composite. Five peak fatigue stresses were selected between 90 and 150 MPa and the results showed that the higher the applied stress, the shorter the composite life. Electrical resistance of the composite was acquired in real-time. The composite resistance appeared a slight drop in the initial fatigue period and followed by a continuous increase until failure. Both the changes in modulus and resistance revealed the shrinking core mechanism in the fatigue-stressed oxidation experiments. A model was developed based on a half-cylinder oxidation pattern. Simulations were conducted on the basis of this model, and the results agreed with the experimental data fairly well.     

Risk‐sensitive filtering for nonlinear Markov jump systems on the basis of particle approximation

In this paper, the risk‐sensitive filtering method that relaxes the dependence on model accuracy is extended to nonlinear Markov jump systems (MJSs). In the method, the so‐called reference probability technique together with particle approximation is utilized to derive the risk‐sensitive filter in nonlinear non‐Gaussian framework. The novelty of the proposed approach is that a ‘risky’ interacting resampling step is performed to both moderate the modeling uncertainties and to solve the problem of particle explosion. A designer‐chosen parameter named risk‐sensitive parameter allows us to make a trade‐off between the filtering accuracy for the nominal model and the robustness to uncertainties. With a meaningful example, it shows that the developed method can outperform the widely used method‐particle filter and interacting multiple model‐particle filter in nonlinear MJSs with uncertainties. Copyright © 2011 John Wiley & Sons, Ltd.     

基于Web的机车工艺行程管理系统

在对机车工艺行程及其信息化的相关问题进行充分调研的基础上,提出了基于Web的机车工艺行程管理解决方案。提出了工艺行程管理优化指导思想,规范了机车工艺行程管理流程,实现了机车工艺行程管理信息化,取得了较好的效果。     

Synthesis of star polymethyl acrylate by SET-LRP at ambient temperature

The star-shaped polymethyl acrylate (PMA) was synthesized by single electron transfer living radical polymerization (SET-LRP) at 30 °C in dimethyl sulfoxide, using 2,2-dibromomethyl-1,3-dibromopropane as the multifunctional initiator, Cu⁰ powder and tris-(2-dimethylamino ethyl)amine (Me₆-TREN) as catalyst. The structure of polymer was analyzed by ¹H NMR, and the results showed that the star-shaped PMA had perfect chain ends (–Br) retention. In addition, the polymerization proceeded smoothly and the time dependence of ln([M]₀/[M]) was linear, which could indicate a first order propagation rate with respect to both radicals and monomer concentration, the polymerization was the living polymerization. The M _n and M _w/M _n of polymer were being measured by Gel Permeation Chromatography. The k _p^app = 0.0367 h⁻¹ and the conversion was 36.3% at 16 h, meanwhile the M _n^GPC of the polymer was 13,300 and the M _w/M _n was 1.40.