BiFeO3 films on steel substrate by the citrate method

We deposited BiFeO₃ films on stainless steel substrates using a simple low-temperature wet-chemical route. Bismuth and iron nitrates were used as metal source and citric acid as chelating agent to prepare a water solution and deposit the film by dipping the steel substrate in the viscous solution. We have investigated the composition, crystallinity and structure of the BiFeO₃ film on steel by X-ray diffraction, X-ray photoelectron spectroscopy, high resolution scanning electron microscopy, conventional and high resolution transmission electron microscopy, and energy dispersive spectroscopy techniques. The film deposited on the steel substrate has two sublayers: a very thin (about 100 nm) nanocrystalline layer, with crystallite size of few nanometers, and a thicker (below 1 μm) crystalline layer.     

Interference of EDTA in the treatment of metal plating wastewater by biosorption

BACKGROUND: The applicability of biosorption for the treatment of metal plating wastewater is adversely affected by the presence of complexing agents. To investigate this limitation on the removal of copper(II) onto peat, batch and column experiments were carried out using EDTA as the model complexing agent. The influence of pH and copper(II):EDTA mass ratios were evaluated for copper(II) concentrations between 5 and 100 mg Cu(II) dm^?3. RESULTS: EDTA negatively affected the copper(II) uptake of peat for pH > 5. Batch and column experiments showed that copper(II)‐EDTA complexes were not sorbed by peat. The leaks of copper(II) detected from the beginning of the column operation matched the copper(II)‐EDTA concentration in the feed solutions. To overcome the interference of EDTA, a novel approach based on the combination of peat + activated carbon was proposed. Nearly complete removal of copper(II) was maintained over 70 h in the treatment of a solution containing 20 mg Cu(II) dm^?3 with 11% of copper(II)‐EDTA complexes. CONCLUSION: A new mass transport model coupling copper(II) speciation in the feed and mass transfer rate‐controlled process simulated the copper(II) breakthrough curves in the presence of EDTA and could be used to successfully predict the breakthrough point. This work demonstrated that biosorption can also be applied for the treatment of wastewater containing complexing agents with the proper combination of sorbent materials. © 2012 Society of Chemical Industry     

How do practitioners use conceptual modeling in practice?

Much research has been devoted over the years to investigating and advancing the techniques and tools used by analysts when they model. As opposed to what academics, software providers and their resellers promote as should be happening, the aim of this research was to determine whether practitioners still embraced conceptual modeling seriously. In addition, what are the most popular techniques and tools used for conceptual modeling? What are the major purposes for which conceptual modeling is used? The study found that the top six most frequently used modeling techniques and methods were ER diagramming, data flow diagramming, systems flowcharting, workflow modeling, UML, and structured charts. Modeling technique use was found to decrease significantly from smaller to medium-sized organizations, but then to increase significantly in larger organizations (proxying for large, complex projects). Technique use was also found to significantly follow an inverted U-shaped curve, contrary to some prior explanations. Additionally, an important contribution of this study was the identification of the factors that uniquely influence the decision of analysts to continue to use modeling, viz., communication (using diagrams) to/from stakeholders, internal knowledge (lack of) of techniques, user expectations management, understanding models’ integration into the business, and tool/software deficiencies. The highest ranked purposes for which modeling was undertaken were database design and management, business process documentation, business process improvement, and software development.     

Learning domain ontologies for semantic Web service descriptions

High quality domain ontologies are essential for successful employment of semantic Web services. However, their acquisition is difficult and costly, thus hampering the development of this field. In this paper we report on the first stage of research that aims to develop (semi-)automatic ontology learning tools in the context of Web services that can support domain experts in the ontology building task. The goal of this first stage was to get a better understanding of the problem at hand and to determine which techniques might be feasible to use. To this end, we developed a framework for (semi-)automatic ontology learning from textual sources attached to Web services. The framework exploits the fact that these sources are expressed in a specific sublanguage, making them amenable to automatic analysis. We implement two methods in this framework, which differ in the complexity of the employed linguistic analysis. We evaluate the methods in two different domains, verifying the quality of the extracted ontologies against high quality hand-built ontologies of these domains.

Our evaluation lead to a set of valuable conclusions on which further work can be based. First, it appears that our method, while tailored for the Web services context, might be applicable across different domains. Second, we concluded that deeper linguistic analysis is likely to lead to better results. Finally, the evaluation metrics indicate that good results can be achieved using only relatively simple, off the shelf techniques. Indeed, the novelty of our work is not in the used natural language processing methods but rather in the way they are put together in a generic framework specialized for the context of Web services.     

On the semantics of noun compounds

This paper provides new insights on the semantic characteristics of two and three noun compounds. An analysis is performed using two sets of semantic classification categories: a list of 8 prepositional paraphrases previously proposed by Lauer [Designing statistical language learners: experiments on noun compounds, Ph.D. Thesis, Macquarie University, Australia] and a new set of 35 semantic relations introduced by us. We show the distribution of these semantic categories on a corpus of noun compounds and present several models for the bracketing and the semantic classification of noun compounds. The results are compared against state-of-the-art models reported in the literature.     

Covalent attachment of single-stranded DNA to carbon paste electrode modified by activated carboxyl groups

A new method of the electrode modification and DNA immobilization for a biosensor is reported. Outer layer of a conventional carbon paste electrode (CPE) was modified with carboxyl groups by mixing stearic acid with the paste. Single-stranded deoxyribonucleic acid was attached to the modified electrode through a linker - ethylenediamine. Immobilization process was performed in the presence of activators - water soluble 1-ethyl-3(3′-dimethylaminopropyl)-carbodiimide (EDC) and N-hydroxysulfosuccinimide (NHS). Stearic acid concentration and other experimental parameters of the procedure were optimized. Covalent immobilization of DNA on the electrode surface exhibits some advantages as compared to simple adsorption mainly due to the fact that nucleic acid chains are bound to an electrode surface by one end only and it ensures structural flexibility and increases hybridization without DNA leakage. Modified electrode with immobilized (21-mer) oligonucleotide as a specific probe was successfully applied in preliminary investigations for the detection of bar gene commonly used in genetically modified food.     

Der Einfluß der Silikatphase auf die Eigenschaften von Eisenerzsintern

Schrifttumsübersicht. Herstellung synthetischer Olivine. Ermittlung des kristallchemischen Aufbaues. Thermo-Differentialanalyse. Eigenschaften der synthetischen Kalziumolivine. Auftreten von Kalziumolivinen in Sintern. Einfluß der Silikatphase auf die Sintereigenschaften.     

Polycyclic aromatic hydrocarbon content in commercial Spanish fatty foods

The levels of polycyclic aromatic hydrocarbons (PAHs) were determined by reversed-phase high-performance liquid chromatography with fluorescence detection in different fatty foods from a Spanish market. The average concentration of the sum of total PAHs in edible vegetable oils was below 25 ng/g, whereas the sum of heavy PAHs did not surpass 5 ng/g. Olive pomace oils obtained before the summer of 2001 were an exception because they were highly contaminated. The effects of different technological processes, such as bleaching, deodorization, and hydrogenation, on PAH concentration in edible oils have been studied. The PAH profiles, as well as the influence of cooking procedures, of other fatty foods (margarine, mayonnaise, and oils from canned fishes) have been examined.