Physical and tribological properties of diamond films grown in argoncarbon plasmas

Nanocrystalline diamond films have been deposited using a microwave plasma consisting of argon, 2–10% hydrogen and a carbon precursor such as C₆₀ or CH₄. It was found that it is possible to grow the diamond phase with both carbon precursors, although the hydrogen concentration in the plasma was 1–2 orders of magnitude lower than normally required in the absence of the argon. Auger electron spectroscopy, X-ray diffraction measurements and transmission electron microscopy indicate the films are predominantly composed of diamond. Surface roughness, as determined by atomic force microscopy and scanning electron microscopy indicate the nanocrystalline films grown in low hydrogen content plasmas are exceptionally smooth (30–50 nm rms) to thicknesses of 10 m. The smooth nanocrystalline films result in low friction coefficients (μ = 0.04–0.06) and low average wear rates as determined by ball-on-disk measurements.     

Ultra-fast boriding of nickel aluminide

In this study, we explored the possibility of ultra-fast electrochemical boriding of nickel aluminide (Ni₃Al) in a molten borax electrolyte. Electrochemical boriding was performed at 950 °C for 15 min and at current densities ranging from 0.1 to 0.5 A/cm². The boride layers formed on the test samples were 50 to 260 μm thick depending on the current density. The mechanical, structural, and chemical characterization of the boride layers was carried out using a Vickers micro-hardness test machine, optical and scanning electron microscopes, and a thin film X-ray diffractometer. The hardness of boride layer was in the range from 800 to 1200 ± 50 HV depending on the load and the region from which the hardness measurements were taken. X-ray diffraction studies confirmed that the boride layers were primarily composed of Ni₃B, Ni₄B₃ and Ni₂₀AlB₁₄ phases. Structurally, the boride layer was very homogenous and uniformly thick across the borided surface area.     

Strength and elastic properties of structural lightweight concretes

The study presents the influence of characteristics of four aggregate types (two sintered lightweight fly ash aggregates, cold-bonded lightweight fly ash aggregate and normalweight crushed limestone aggregate) on the strength and elastic properties of concrete mixtures. Different models were also used in order to predict the strength and modulus of elasticity values of concretes. The results of this study revealed the achievement of manufacturing high-strength air-entrained lightweight aggregate concretes using sintered and cold-bonded fly ash aggregates. In order to reach target slump and air content, less amount of chemical admixtures was used in lightweight concretes than in normal-weight concrete, leading to reduction in production cost. The use of lightweight aggregates (LWA) instead of normalweight aggregates in concrete production slightly decreased the strength. The models given by codes, standards and software and equation derived in this study gave close estimated values to the experimental results.     

An investigation into the mechanical and tribological properties of plasma electrolytic oxidation and hard-anodized coatings on 6082 aluminum alloy

A ceramic coating on AA6082 aluminum alloy prepared by plasma electrolytic oxidation (PEO) has been studied and compared against a sulphuric acid hard-anodized coating on the same alloy. Surface morphology and microstructures of the coatings have been examined by scanning electron microscopy. X-ray diffraction is used to determine the phase composition of the coatings. The adhesion strength of the coatings has been evaluated using a scratch test method. The coating's mechanical properties such elastic modulus and hardness data have been generated using a dynamic ultra-microhardness tester. Sliding wear tests with different loading rates are performed on the coatings in order to assess their wear resistance. Test results show that the PEO treated samples exhibit significantly better mechanical properties compared to hard anodized samples. The elastic modulus and hardness of the PEO coating are 2-3 times greater than of the hard anodized coating and subsequently, an improved wear resistance of the PEO coating has been achieved. The mechanical properties of the coatings and their relations to their tribological performance are discussed.     

Cusp mirror—Heat pipe evacuated tubular solar thermal collector

A solar thermal collector was constructed based on an internal 1.15X cusp concentrator, thermal insulation involving a vacuum and selective absorber, and thermal transfer to a manifold via heat-pipe action. Performance of the collector was compared with that of an evacuated, selectively coated, flat-plate absorber equipped with flow-through heat transfer. It was shown that with single collector tubes, mirror losses lowered the optical efficiency of the cusp, heat-pipe collector below that of the flat plate, while the smaller absorber area of the heat pipe reduced thermal losses at absorber temperatures above ambient. Thus, a crossover in efficiency occurred such that the flat plate was more efficient at low while the cusp-heat pipe was more efficient at high . Testing of modules showed that manifold losses and gains could dominate these collector effects when the collector area approximately equaled the manifold area.     

A microwave method based on amplitude-only reflection measurements for permittivity determination of low-loss materials

A new method based on amplitude-only reflection measurements for complex permittivity determination of low-loss materials backed by a short-circuit termination is presented. There are two main advantages of the proposed method. First, it is insensitive to calibration plane shifts and phase uncertainties in reflection measurements of low-loss materials. Second, it does not require any additional test material with a thickness value different than that of the material under test. The disadvantage of the proposed method is that it is not convenient to apply for complex permittivity determination of dispersive low-loss materials. The method is validated by complex and amplitude-only scattering parameter measurements at X-band of a low-loss sample (polystyrene) fitted into a waveguide section. The method, as other non-resonant methods, can only provide a rough indication of the imaginary part of the permittivity for low-loss samples.     

To Integrate of Not to Integrate?

Turkish architecture over the last 150 years has been plagued by its preoccupation with its integration with the West. Should it be embracing or reflecting Western cultural, technical and professional standards? Uğur Tanyeli provides the background to this pessimistic context and describes how a new generation of architects over the last 10 years have transcended this predicament by producing work that turns away from this obsession with identity. Copyright © 2010 John Wiley & Sons, Ltd.     

Detailed analysis on thermal,microstructural, mechanical,and morphological features of side chain liquid crystalline polymer/isotactic polypropylene graft copolymers: Effect of grafted and ungrafted polymer units

The main scope of this comprehensive study is to investigate the effects of poly(p-benzophenoneoxycarbonylphenyl acrylate), poly(BPOCPA), which presenting as only graft units or both graft and ungrafted units in the matrix, on the fundamental features of isotactic polypropylene (IPP). The graft copolymerization of BPOCPA onto IPP was performed with the aid of bulk melt polymerization at varying monomer content levels ranging from 5% to 40%. The thermal behavior, crystal quality, mechanical performance, and surface morphology of the samples were investigated by means of differential scanning calorimeter, X-ray diffractometer (XRD), universal mechanical test, and scanning electron microscope (SEM) techniques. Thermal analyses depicted that there existed the noteworthy enhancements in both crystalline melting temperatures and percent crystallinities of matrix polymers. Furthermore, according to XRD results, a and b parameters increased significantly at low percentages of the graft units, while the parameter c decreased in all products in consistence with the content. As for the mechanical characterization, the grafting led to remarkable improvements in modulus, tensile and impact strength of the products. SEM micrographs indicated that the samples were completely homogeneous without any phase separation and the products exhibited brittle nature with some ductility.