以硅氧烷醇锂为催化剂的氟硅生胶的合成

介绍了单体三氟丙基甲基环三硅氧烷通过硅氧烷醇锂催化剂聚合成氟硅生胶,讨论了不同催化剂及其用量,原料中水分含量、不同乙烯基含量对氟硅生胶分子量的影响.     

盐湖沉积储层孔隙结构特征及演化模式--以马王庙油田为例

盐湖沉积条件下的沉积环境及储集层特征等具有与淡水沉积不同的特征,通过对江汉盐湖盆地马王庙地区储层孔隙结构特征的研究,揭示了孔隙结构的宏观及微观特征.该区新沟咀组下段砂岩储层孔隙类型以粒间溶孔为主,喉道主要为片状、弯片状及点状喉道.Ⅱ、Ⅲ油组的物性比Ⅰ油组好,平面上孔隙分布具分区性.孔喉配置主要为大孔中喉,次为大孔粗喉及中孔中喉.孔隙结构受沉积环境及成岩作用的影响.以马36井Ⅱ油组砂岩为例,建立了孔隙演化定量模式.     

Crack length measurements with a potential drop method: A finite element simulation

A potential drop method, as used for estimations of crack lengths during three-point-beind experiments, is studied. The mechanical state is calculated using a finite element method. The deformed body obtained is used for a subsequent calculation of the electrostatic state. Calculations are performed for both two- and three-dimensional models. The material is assumed to be elastic, linearly hardening plastic and electrostatically linear. Large deformations are considered. Further, the non-linearity caused by the load, depending on the contact area between the cylinder on which the load is applied and the specimen, is considered. The increased contact area did not influence the mechanical state very much but had a direct impact on the electrostatic state. The changes in the potential drop recordings due to deformation and electrical current passing through the load cylinder were shown to be considerable. The study explains, at least partly, the experimental observations. A more reliable registration of crack growth initiation is the main outcome of the analysis.     

Optically tuned superconductive-dielectric resonators with whispering-gallery modes

An analytical method is presented for calculating the resonant frequency andQ-factor of a superconducting dielectric disk resonator operating in millimeter-wave regime with whispering-gallery mode. Resonant frequency shift due to the optical generation of quasi-particles in superconducting film is investigated as a function of photon flux. An optically tunable resonant frequency of about 500 MHz is estimated, and good agreement is found between numerical results and experimental ones.     

溶质原子在再结晶运动晶界上偏聚的研究

Ｂ~（１０）（ｎ，α）Ｌｉ~７裂变反应的径迹显微照相技术被用来研究含硼Ｆｅ－３０％Ｎｉ合金高温热变形再结晶过程中硼在晶界上的偏聚行为，实验表明，含硼Ｆｅ－３０％Ｎｉ合金１０００℃热变形２０％再结晶过程中，运动晶界前方发生硼偏聚而后方发生贫硼现象，而在静止晶界上看不到硼偏聚，随着再结晶新晶粒的长大，运动晶界上的硼偏聚变弱。本文提出，可以用晶界对溶质原子热运动散射的量子理论来解释溶质原子在运动晶界上的偏聚现象。     

SAPO-34/SiO_2催化甲醇制烯烃

采用水热法合成了SAPO-34分子筛,并用X射线粉末衍射仪和扫描电子显微镜对SAPO-34分子筛的结构进行了表征,同时探讨了黏合剂种类、甲醇分压、催化剂粒径和硅源等对SAPO-34分子筛催化甲醇制烯烃(MTO)反应性能的影响。实验结果表明,在MTO反应中,三烯(乙烯、丙烯和丁烯)选择性在反应初期存在明显的诱导期;以S iO2为黏合剂合成的SAPO-34/S iO2催化剂不但可缩短MTO反应的诱导期,三烯选择性也较未添加黏合剂或以A l2O3为黏合剂时高1~2个百分点;且当催化剂活性明显下降时,三烯选择性下降的幅度较小。催化剂粒径、甲醇分压及硅源对催化剂的诱导期也有明显的作用。在甲醇分压低于19kPa、催化剂粒径0.25~0.38mm、S iO2为黏合剂、硅酸四乙酯为硅源时,SAPO-34/S iO2催化剂的MTO性能明显提高。     

深圳抽水蓄能电站上水库防渗分析

通过对深圳抽水蓄能电站上水库工程地质和水文地质条件分析,对库周渗漏和防渗进行了分析和论证,并对防渗处理措施提出建议。     

并联型有源电力滤波器的间接电流控制技术

对并联型电力有源滤波器建立了数学模型,详细地分析了在全数字控制下,谐波指令的生成和电流控制器的设计。提出了在d,q轴上运用矢量控制,通过控制变换器桥臂中点输出电压矢量达到控制电流的目的,并运用仿真给出了电压矢量和电流指令矢量的运动轨迹。仿真和初步并网实验的结果对理论分析进行了验证。     

Modeling lossy anisotropic dielectric waveguides with the method oflines

This paper presents a new formulation useful for modeling waveguides constructed from lossy inhomogeneous anisotropic media. Our approach is based on a pair of Sturm-Liouville type wave equations that have been derived to handle inhomogeneous, diagonalized complex permittivity and permeability tensors. The method of lines is then applied to these wave equations, and related field equations, creating an indirect eigenvalue problem that correctly models this class of structure. Some refinements to the method of lines are also proposed, particularly, regarding the construction of the modal matrices found in the eigenvalue problem. Using our approach, modal dispersion curves have been computed for millimeter-wave and optical structures. Comparisons made with results available from the literature validate our approach     

用HPLC法测定对二异丙苯的一氢过氧化物和二氢过氧化物

二过氧化氢对二异丙苯是二异丙苯氧化法生产对苯二酚的重要中间产物。本文用HPLC半制备柱制得一过氧化氢对二异丙苯和二过氧化氢对二异丙苯纯品,用光谱法确定其结构,建立了正相高效液相色谱测定方法。