Na+、K+离子交换对Co-Mo/MCM-41加氢脱硫催化剂的影响

 用偏硅酸钠和正硅酸乙酯作硅源制备了MCM-41（分别记作MCM-41(S)和MCM-41(T)）分子筛，并用Na₂C₂O₄和K₂C₂O₄对MCM-41(S)进行了碱金属离子交换改性。以质量分数0.8 %的二苯并噻吩（DBT）的十氢萘溶液为模型化合物，考察了不同MCM-41担载的Co-Mo硫化物催化剂对DBT的加氢脱硫反应性能。结果表明，MCM-41担载的Co-Mo催化剂加氢活性较低，DBT主要通过直接脱硫反应路径脱硫。其活性顺序为：Co-Mo/MCM-41(T)>Co-Mo/MCM-41(S)>Co-Mo/MCM-41(K)>Co-Mo/MCM-41(Na)。UV-Vis结果表明，部分Co与MCM-41(S)中少量Al发生相互作用，生成了CoAl₂O₄，是造成Co-Mo/MCM-41(S)活性降低的重要因素。而在Co-Mo/MCM-41(K)和Co-Mo/MCM-41(Na)中，除CoAl₂O₄物种之外，碱金属的引入还促进了Co₃O₄物种的形成，使其活性进一步降低。     

光纤光栅感温火灾探测报警系统在原油罐区的应用

通过对现有罐区火灾自动报警技术的认真考察、对比,在石西集中处理站原油罐区安装了光纤光栅感温火灾探测报警系统.该报警系统的传感信号是光的波长变化,传感器及其探测系统是靠光缆连接而进入被测现场,它具有高安全性、高可靠性、高绝缘性、高抗电磁干扰性、防潮耐蚀、寿命长等其他传统火灾探测报警系统无法比拟的优越性能.阐述了其系统构成和运行效果.该系统在石西集中处理站运用效果良好.     

HSG冻胶调剖堵水剂室内评价

针对吉林油田低渗透、裂缝油藏注水开发后期注水窜流严重的特点,研制出新型冻胶调剖堵水剂HSG。对HSG成胶前溶胶体系的表观黏度影响因素进行了分析,分析认为在相同剪切速率下溶胶体系表观黏度随共聚物浓度、矿化度、碱含量的增加而增大,并表现出剪切稀释特性,黏温测试表明溶胶体系表观黏度随温度升高而下降;对HSG成胶后冻胶体系的强度进行了测定,确定其屈服应力值为3500 Pa,振荡剪切应力扫描确定了冻胶体系的线性黏弹性区域,频率扫描确定该冻胶为强冻胶体系;2组并联填砂管选择注入试验表明,HSG溶胶体系具有良好的选择注入能力,能达到优先进入高渗透层的目的;20 m超长填砂管封堵试验表明,HSG溶胶体系的注入压力梯度为0.82 MPa/m,具有易于注入的特点,HSG成胶后的封堵强度为17.54 MPa/m,具有较强的封堵能力。该研究为HSG冻胶调剖堵水剂现场应用提供了借鉴。     

重复压裂裂缝转向时油藏数值模拟研究

裂缝转向的实现及选井、选层、优化设计等的数值模拟和机理是转向重复压裂需进一步研究解决的问题,为此,采用黑油模型,研究了在反九点注采井网中,不同储集层渗透率下,转向重复压裂的裂缝穿透率和导流能力等对采油动态的影响。研究表明,不论是渗透率高的地层还是渗透率低的地层,不利裂缝方位的边井最适合实施转向重复压裂且需要比常规重复压裂更大的缝长,而有利裂缝方位的边井和角井只需要与常规重复压裂相当的缝长;同时,转向重复压裂需要比常规重复压裂更高的裂缝导流能力。     

相关条件下基于N-P准则的分布式检测理论研究

本文针对并行网络、二元局部判决的情况,研究了在相关条件下基于N-P准则的分布式检测融合算法,给出了在联合概率密度已知和未知两种情况下的最优融合规则的理论推导及相应的解决方案,并在实验仿真的基础上,得到了部分有益的结论。     

一种的四进制CPM调制器的设计与FPGA实现

设计并实现了一种基于FPGA的四进制连续相位调制器（PCM）。该调制器的基带调制模块通过查表法实现，复杂度较低。仿真结果验证了设计的正确性。     

SIMPLIS环境中开关电源集成电路控制器模型的开发及应用

介绍现代开关电源行业仿真工作的意义和现状,以及专用仿真软件包SIM etrix/SIMPLIS的优点和不足。通过实例给出SIMPLIS环境中集成电路控制芯片的建模过程,并就其中的关键技术予以简单讨论。     

纳滤膜的污染成因及防止技术研究

结合科学实验研究成果分析了纳滤膜无机污染、有机污染和微生物污染三种主要污染的机理。首次提出了动态有机污染模型理论,并就纳滤膜污染的防止提供了一些有效可行的技术处理方案,为纳滤膜的推广应用提供参考。     

Pack cementation process for the formation of refractory metal modified aluminide coatings on nickel-base superalloys

The vapour phase compositions of a series of pack powder mixtures containing elemental Al and Hf or W powders as depositing sources and CrCl₃·6H₂O or AlF₃or CrF₃as activators were analysed in an attempt to further develop the pack cementation process to codeposit Al and Hf or W to form diffusion coatings on nickel base superalloys. The results suggested that Al could be codeposited with Hf, but not with W, from the vapour phase. Compared with both AlF₃and CrF₃, CrCl₃·6H₂O has been shown to be a more suitable activator for codepositing Al with Hf. The optimum coating temperature was identified to be in the range of 1050°C to 1150°C. Based on the thermochemical analysis, a series of coating deposition studies were undertaken, which confirmed that codeposition of Al and Hf could be achieved at a deposition temperature of 1100°C in the CrCl₃·6H₂O activated packs containing elemental Al and Hf powders. The coating obtained had a multilayer structure consisting of a Ni₇Hf₆Al₁₆top layer and a NiAl layer underneath, followed by a diffusion zone, which revealed that the coating was formed by the outward Ni diffusion. It is suggested that the compositions suitable for codeposition of Al and Hf could be effectively identified by comparing the vapour pressures of HfCl₄and HfCl₃with that of AlCl in the packs activated by chloride salts. It has also been experimentally demonstrated that, although W could not be deposited from the vapour phase, a high volume of fine W particles can be entrapped into the outer NiAl coating layer formed by the outward Ni diffusion using a modified pack configuration. This leads to the formation of a composite coating layer with W particles evenly distributed in a matrix of NiAl. It is suggested that this modified pack process could be similarly applied to develop nickel aluminide coatings containing other refractory metals that may not be codeposited with Al from the vapour phase.     

Breaking a remote user authentication scheme for multi-server architecture

Lin et al., (2003) proposed a remote user authentication scheme for multi-server architecture. In this paper, we breaks this scheme by giving an attack. Our attack allows an adversary to impersonate any user in the system, as long as a single authentication message of that user is observed.