Curing behavior and thermal and mechanical properties enhancement of tetraglycidyl‐4,4′‐diaminodiphenylmethane/4,4′‐diaminodiphenylsulfone using a liquid crystalline epoxy

A thermosetting resin system, based on tetraglycidyl‐4,4′‐diaminodiphenylmethane, has been developed via copolymerization with 4,4′‐diaminodiphenylsulfone in the presence of a newly synthesized liquid crystalline epoxy (LCE). The curing behavior of LCE‐containing resin system was evaluated using curing kinetics method and Fourier transform infrared spectroscopy. The effect of LCE on the thermal and mechanical properties of modified epoxy systems was studied. Thermogravimetric analysis indicated that the modified resin systems displayed a high T_0.05 and char yield at lower concentrations of LCE (≤5 wt%), suggesting an improved thermal stability. As determined using dynamic mechanical analysis and differential scanning calorimetry, the glass transition value increased by 9.7% compared to that of the neat resin when the LCE content was 5 wt%. Meanwhile, the addition of 5 wt% of LCE maximized the toughness with a 175% increase in impact strength. The analysis of fracture surfaces revealed a possible effect of LCE as a toughener and showed no phase separation in the modified resin system, which was also confirmed by dynamic mechanical analysis. © 2016 Society of Chemical Industry     

Studies on Decreasing Energy Consumption for a Freeze-Drying Process of Apple Slices

The shape, color, flavor, and rehydration capacity of freeze-dried (FD) products are all better than other dried products. However, the energy consumption during FD is very high, which limits the application of this drying method for common materials. In this article, microwave vacuum drying (MWVD) was applied before or after FD to decrease the energy consumption during FD. Moreover, energy consumption was divided into two parts: valid and invalid energy consumption. Apple slices were used as an example to calculate the saving percentage of invalid energy consumption by comparing combination drying with FD. Apple slices freeze dried for 8.28 h first and then dried by MWVD have the best appearance, with a savings of 39.20% in invalid energy consumption. But apple slices freeze dried for 6 h first followed by MWVD have the highest savings of invalid energy consumption, 54.02%, while still maintaining an acceptable appearance.     

Anisotropic compressive properties of porous CNT/SiC composites produced by direct matrix infiltration of CNT aerogel

Carbon nanotube‐reinforced silicon carbide composites (CNT/SiC) produced by direct infiltration of matrix into a porous CNT arrays have been demonstrated to possess a unique microstructure and excellent micro‐mechanical properties. However, the thickness of the array preforms is usually very small, typically less than 2 mm. Therefore, fabrication of macroscopic CNT/SiC composites by chemical vapor infiltration (CVI) process requires that the nanoscale fillers could form macroscopic architectures with an open pore network. Here, this study reports an experimental strategy for the fabrication of SiC matrix composites reinforced by CNT based on an ice‐segregation‐induced self‐assembly (ISISA) technique. Macroscopic CNT aerogel with well‐defined macroporous network was produced by ISISA technique and was subsequently infiltrated by SiC in a CVI reactor. After five CVI cycles, the porosity of as‐fabricated composites was 11.6±0.3% and the machined specimens exhibited lamellar structure with parallel lamellaes intersected at discrete angles. By observed, there are in fact five different representative anisotropic macrostructures, the compressive strengths of these five different loading modes with respect to lamella orientation were 933±55, 619±34, 200±45, 199±21, and 297±41 MPa, respectively, and the failure mechanisms were attributed to the anisotropic nature of the macrostructures. Energy dissipation toughening mechanism at the nanoscale such as CNT pull‐out was observed and the phase composition of the fabricated materials included β‐SiC, CNT, and SiO₂.     

Microstructure and mechanical properties of carbon/carbon composites with PyC/SiC/TiC multilayer interphases

Carbon/carbon composites with PyC/SiC/TiC multilayer interphases (CCs-PST) have been successfully prepared by a joint process of chemical vapor deposition and carbothermal reduction. Effect of the Ti(OC₄H₉)₄/C₆H₄(OH)₂ molar ratio on the morphology of TiC particles was investigated and the ratio was optimized as 8:1. When the Ti(OC₄H₉)₄/C₆H₄(OH)₂ molar ratio was 8:1, many homogeneously distributed TiC nanoparticles with the sizes of 100–500 nm on the fibers were observed. The structural evolution of CCs-PST was discussed and the mechanical properties of as-prepared materials were investigated by flexural and interlaminar shear tests. The resulted composites demonstrated a PyC and SiC mixed inner interphase with the thickness of 0.5–1 $\mathrm{\mu }\mathrm{m}$ and a TiC outer interphase with a thickness about 0.5 µm. Flexural strength of 201.45 ± 5.27 MPa and modulus of 21.21 ± 1.58 GPa showed a 41.7% and 7.83% improvement respectively as compared with that of the neat CCs. The interlaminar shear strength of CCs-PST was 66.71 ± 4.87 MPa, which was 51.20% higher than that of the CCs. The improved mechanical properties were attributed to the enhanced interface bond between fibers and matrix induced by the PST.     

Steroidal saponins from Asparagus dumosus

A new steroidal saponin, dumoside, characterized as (20S)-3 beta, 16 beta-dihydroxy pregn-5-ene-22-carboxylic acid (22, 16)-lactone-3-O-beta-chacotrioside, was isolated from the whole plant of Asparagus dumosus Baker and the structure was deduced from spectral data. In addition to dumoside three more steroidal saponins characterized as 3 beta-dihydroxy pregn-5,16-dien-20-one 3-O-beta-chacotrioside, 3 beta, 22 alpha, 26-trihydroxyfurost-5-ene-3-O-beta-chacotrioside-26-O- beta-D-glucopyranoside and its corresponding 22 alpha-O methoxy analogue were also isolated for the first time from this source. The structures have been identified with the help of FAB-MS, 1H NMR, 13C NMR and extensive 2D NMR spectroscopy, as well as comparison with reported spectroscopic data.     

Effect of raw materials on the pore morphologies of carbon foams prepared through templating method

The present paper reports about the effects of raw materials, processed through templating method, on the pore microstructures and pore size distribution of carbon foams (CFs). Biomaterials along with polyurethane and phenolic resin were employed to prepare CFs. To further investigate the adjustability of the pore microstructures and pore size distribution, several kinds of chemical additives/fillers, including activated charcoal, NaCl, and silicon, were used. Surface morphological studies were carried out using scanning electron microscope (SEM), and pore size distribution was analysed by high-pressure Hg porosimetry. The results showed that the structures of the precursor played a dominant role in determining the final pore microstructures. Chemical additives/fillers affect the average pore sizes, pore size distributions, and the pore walls. High amount of macropores are found in all the samples with the radius ranging from 2 to 4?μm. It is practical to adjust the pores using different raw materials and chemical additives/fillers.     

Simulation of multiphase boost DC-DC converter with the stable control strategy

The multiphase boost DC-DC converter with stable control strategy is presented. Multi- phase boost DC-DC converter is designed for high voltage and high power applications, and could be achieved by the adjustment of voltage doubler rectifiers on the secondary side of high frequency transformers. The stable control strategy for three phase boost DC-DC converter has been utilized during simulation in this study and this strategy can be extend to N-number of phases. The stable control strategy consists of only three voltage loops, which are sufficient for appropriate and efficient operation of three phase boost DC-DC converter. With the stable control strategy, the equal power balance sharing can be obtained between input and output. The stability of control strategy has been evaluated by simulating the multiphase boost DC-DC converter for the same and mismatch turn ratios of high frequency transformers. The simulation result is good and the objective of the strategy is a- chieved.