凝胶注模成形技术的研究与发展

凝胶注模成形是一种近净尺寸成形工艺，是制备形状复杂、成分均匀和可靠性高的陶瓷材料的理想成形工艺。笔者阐述了凝胶注模成形工艺过程和成形原理，以及国内外的研究现状，指出了凝胶注模成形技术的未来发展方向。     

矿山工程设计可靠性研究

本文讨论了矿山工程设计中地质储量、矿山工程建设、工艺系统、露天矿投资等的可靠性计算方法,据此可对矿山能否达到设计规模及预期效益作出评价,从而可采取相应对策。     

Atmospheric Dependence on Dielectric Loss of 1/6Ba5Nb4O15· 5/6BaNb2O6 Ceramics

Samples of 1/6Ba₅Nb₄O₁₅·5/6BaNb₂O₆ along with the pure end members, Ba₅Nb₄O₁₅ and BaNb₂O₆, were sintered under low oxygen partial pressure. The degradation mechanisms of dielectric loss in this reducing atmosphere have been studied. We found that the degradation occurred primarily due to the formation of oxygen vacancies caused by the reduction of Nb⁵⁺. This was determined by measuring the electrical conductivity, and through X-ray photoelectron spectroscopy. More importantly, the dielectric loss of 1/6Ba₅Nb₄O₁₅·5/6BaNb₂O₆ samples with higher temperature stability was further decreased on sintering in a reducing atmosphere. This observation has been explained by considering the increased porosity and formation of a reduced second phase, Ba_0.65NbO₃.     

烟丝整丝率变化率对卷烟卷接质量控制的影响研究

长期以来,烟丝的物理特征都被认为是影响卷烟质量的主要因素。随着生产工艺和企业烟丝标准的不断提高,如今烟丝的物理特征对卷烟质量的影响不再显著。研究人员转而将目光转向了烟丝的整丝率变化率。     

建筑工程项目管理的新型模式探究

建筑工程项目管理直接决定了建筑企业的经营战略和生产模式,从而影响到企业的市场竞争力。现阶段,建筑工程项目管理还存在一些问题,需要不断地创新其管理模式。针对建筑工程项目管理新型模式构建的重要性和相关策略进行了研究,为我国建筑行业的发展提供一定的参考。     

菲酐-纳米金修饰电极同时检测抗坏血酸、多巴胺和尿酸的研究

多孔结构的3,4,9,10-茈四甲酸二酐（PTCDA）作为骨架,用抗坏血酸做还原剂制备纳米金（GNPs）,制备了高催化活性的PrC—GNPs复合纳米材料。将该材料用于玻碳电极的修饰（GCE）,制得PTC—GNPs复合材料修饰的电极（PTC—GNPs／GCE）。该修饰电极能够同时对尿酸（UA）、多巴胺（DA）和抗坏血酸（AA）进行检测。分别使用循环伏安法（CV）和差分脉冲伏安法（DPV）对UA、DA和AA和在修饰电极上的电化学行为进行研究。实验结果表明,在pH=5．0的PBS缓冲体系中,该修饰电极对UA、DA和AA的线性响应范围分别为0．002～0．462mol／L、0．002～0．352mol／L和0．04～1．54mol／L。该传感在临床医学检测领域具有一定的应用前景。     

基于项目式高校单片机课程改革与实践

针对传统单片机课程教学中存在的弊端,提出了项目式教学方法。探讨了在项目设计过程中项目的选择、项目的情境设计、项目在教学过程中的实施等问题。以燃气控制器为项目案例,介绍了如何将项目教学方法融入到单片机的硬件和软件教学中。以项目为主线,逐层完成整个项目的开发,直观地展示项目式教学方法在单片机教学中的优越性。该教学方法能充分调动学生学习的积极性,激发其创新意识,帮助学生毕业之后更快地适应相关工作。     

基于NoSQL数据库的大数据存储技术的研究与应用

实际工程中采集和处理的数据量特别大,这对传统数据库技术提出巨大挑战。针对传统关系型数据库存储速度慢、对硬件要求高的缺点,提出一种以NoSQL数据库为基础的大数据处理方法,打破了传统数据库的关系模型,数据以一种自由的方式存储,而不依赖固定的表结构。该方法主要是将经验模态分解并与NoSQL数据库技术相结合,应用于大型结构件的变形监测中,构建出一个基于NoSQL数据库系统的大型结构件变形监测系统。仿真结果表明,该方法可以实现大型结构件变形监测数据的实时处理,在计算收敛性、算法稳定性和处理速度上都优于传统数据库技术。     

Corrosion and inhibition of aged 347 grade stainless steel boiler tubes

General and pitting corrosion of both service and laboratory aged 347 grade stainless steel superheater tubes have been investigated. SEM analysis showed the precipitate phases to have a double structure consisting of phase and carbide. EDA analysis of the precipitates indicated the [Cr]/[Fe] ratio to increase with exposure time. For both set of specimens, the general corrosion rate in 1m H₂SO₄ increased with aging whilst the pitting studies (in 3.5% NaCl) also indicated increased pitting susceptibility with aging. These trends are consistent with corrosion from the chromium depleted areas adjacent to the precipitates. Methoxypropylamine is effective as an inhibitor for pitting corrosion and the concentration required to prevent this form of attack increases with exposure time for both types of specimens.     

The role of Al in C-S-H: NMR, XRD, and compositional results for precipitated samples

X-ray diffraction, compositional analysis, and ²⁹Si and ²⁷Al MAS NMR spectroscopy of Al-substituted tobermorite-type C-S-H made by precipitation from solution provide significant new insight into the structural mechanisms of Al-substitution in this important and complicated phase. Al occurs in 4-, 5-, and 6-coordination (Al[4], Al[5], and Al[6]) and plays multiple structural roles. Al[4] occurs on the bridging tetrahedra of the drierkette Al-silicate chains, and Al[5] and Al[6] occur in the interlayer and perhaps on particle surfaces. Al does not enter either the central Ca-O sheet or the pairing tetrahedra of the tobermorite-type layers. Al[4] occurs on three types of bridging sites, Q³ sites that bridge across the interlayer; Q² sites that are charge balanced by interlayer Ca⁺², Na⁺, or H⁺; and Q² sites that are most likely charge balanced by interlayer or surface Al[5] and Al[6] through Al[4]-O-Al[5,6] linkages. Although the data presented here are for relatively well-crystallized tobermorite-type C-S-H with C/S ratios ≤ 1.2, comparable spectral features for hydrated white cement pastes in previously published papers[30], [31] and [32] [M.D. Andersen, H.J. Jakobsen, J. Skibsted, Incorporation of aluminum in the calcium silicate hydrate (C-S-H) of hydrated Portland cements: a high-field ²⁷Al and ²⁹Si MAS NMR investigation Inorg. Chem. 42 (2003) 2280-2287; M.D. Andersen, H.J. Jakobsen, J. Skibsted, Characterization of white Portland cement hydration and the C-S-H structure in the presence of sodium aliminate by ²⁷Al and ²⁹Si MAS NMR spectroscopy, Cem. Concr. Res. 43 (2004) 857-868; M.D. Andersen, H. J. Jakobsen, J. Skibsted, A new aluminum-hydrate phase in hydrated Portland cements characterized by ²⁷Al and ²⁹Si MAS NMR spectroscopy, Cem. Concr. Res., submitted for publication.] indicate the presence of similar structural environments in the C-S-H of such pastes, and by implication OPC pastes.