3D porous polymeric conductive material prepared using LbL deposition

In this work a 3D porous polymeric conducting material is derived from a multi-percolated polymer blend system. The work has focused on the preparation of low surface area porous substrates from polymer blends followed by the deposition of polyaniline conductive polymer (PANI) on the internal porous surface using a layer-by-layer (LbL) technique. The approach reported here allows for the percolation threshold concentration of polyaniline conductive polymer (PANI) to be reduced to values of no more than 0.19%. Furthermore, depending on the amount of PANI deposited, the conductivity of the porous substrate can be controlled from 10⁻¹⁵ S cm⁻¹ to 10⁻³ S cm⁻¹.Ternary and quaternary multi-percolated systems comprised of high-density polyethylene (HDPE), polystyrene (PS), poly(methyl methacrylate) (PMMA) and poly(vinylidene fluoride) (PVDF) are prepared by melt mixing and subsequently annealed in order to obtain large interconnected phases. Selective extraction of PS, PMMA and PVDF result in a fully interconnected porous HDPE substrate of ultra-low surface area and highly uniform sized channels. This provides an ideal substrate for subsequent polyaniline (PANI) addition. Using a layer-by-layer (LbL) approach, alternating poly(styrene sulfonate) (PSS)/PANI layers are deposited on the internal surface of the 3-dimensional porous polymer substrate. The PANI and sodium poly(styrene sulfonate) (PSS) both adopt an inter-diffused network conformation on the surface. The sequential deposition of PSS and PANI has been studied in detail and the mass deposition profile demonstrates oscillatory behavior following a zigzag-type pattern. The presence of salt in the deposition solution results in a more uniform deposition and more thickly deposited PSS/PANI layers. The conductivity of these samples was measured and the conductivity can be controlled from 10⁻¹⁵ S cm⁻¹ to 10⁻⁵ S cm⁻¹ depending on the number of deposited layers. In the case of a porous sample which can be crushed, applying a load to the substrate can be used as an additional control parameter. In that sample a high load results in higher conductivity with values as high as 10⁻³ S cm⁻¹ obtained. The work described above has focused on very low surface area porous substrates in order to generate a conductive device with the lowest possible concentration values of polyaniline, but high surface area substrates can also be readily prepared using this approach.     

Tribological properties of powder metallurgical tool steels used in powder compaction pressing dies

The tribological properties of two powder metallurgical (PM) tool steels, high and low nitrogen containing, are investigated by means of three different wear tests: ball‐on‐disc, rubber wheel and scratch test. The ball‐on‐disc tests showed two distinct friction curves corresponding to each material. In order to simulate the tribosystem existing in metal powder compaction dies, the rubber wheel and the scratch test were modified. The rubber wheel test was performed using ferrous powder instead of sand, and scratch testing was carried out by sliding a powder compact over the tool steels. The scratch tests indicated a higher steady‐state coefficient of friction for the low nitrogen containing PM steel as compared with the high nitrogen containing alloy. Additionally, the results from the rubber wheel tests were in agreement with industrial experiences, showing the low nitrogen containing tool steel to suffer from severe galling. Copyright © 2011 John Wiley & Sons, Ltd.     

Optimal design of a natural gas transmission network layout

Optimal design of a natural gas network, which is supposed to convey natural gas from a supply point in south of Iran to some delivery points in north and northwest of Iran, is presented in this paper. Sum of investment and operating costs constitutes the objective function of the present study. A wide range of design parameters, including the network layout, diameter of each pipeline, pressure value at each supply or delivery node, as well as number and locations of compressor stations (CSs) on each pipeline, were considered in the optimization problem. A Genetic Algorithm (GA) which exploits “optimal properties of single pipelines” was presented and used as the optimization tool. Short computation time and repeatability of results ensures achieving the global optimum solution and are positive features of the proposed optimization algorithm. The optimal network design obtained from the optimization procedure consisted of 2660 km of pipelines and 26 CSs. It required a total annual cost of about 366.15 M$/year. The results explain why the layout with the shortest total length is not the optimal choice.     

Interfacial coarsening of ternary polymer blends with partial and complete wetting structures

The coarsening of polymer mixtures is an important route towards major morphology modification in multiphase polymer systems. To date however the coarsening of ternary systems has not been significantly examined. In this study the phase coarsening mechanism via annealing for partial wetting, and complete wetting morphologies in ternary polymer blends is characterized. This is a route towards the examination of interfacial coarsening in polymer blends since ternary partially wet systems involve the presence of interfacial droplets while completely wet ternary systems are comprised of a complete interfacial layer. A partial wetting type of morphology is obtained for polybutylene succinate (PBS)/poly(lactic acid) (PLA)/polycaprolactone (PCL). Three different compositions for that system with composition ratios of ?_(PBS/PLA) = 1.5; ?_(PBS/PLA) = 3; and ?_(PBS/PLA) = 10 are prepared to show the effect of the concentration of the self-assembled PLA droplets located at the interface of PBS/PCL. As the concentration of PLA decreases, the growth rate of the PLA phase during the annealing process sharply decreases due to a significant increase of the “surface to volume ratio” of the PLA droplets required in order to cover the interface. In this case, due to the short inter-droplet distances between PLA droplets at the interface, coalescence is controlled by the drainage time. This mechanism is confirmed by the observation of a linear relationship between the third power of droplet size and annealing time. For the 37.5%PBS/12.5%PLA/50%PCL blend, the conservation of interfacial-angles confirms that the annealing time has no effect on the angle values between phases, as predicted by Harkins spreading theory.     

Modeling and economic analysis of gas engine heat pumps for residential and commercial buildings in various climate regions of Iran

There is an increasing trend in using heat pumps in air conditioning (heating/cooling) systems of residential and commercial buildings. The required power to drive the compressor of vapor compression heat pump cycles may be provided by either an electrical motor or an internal combustion engine. In this paper thermal modeling and economic analysis of gas engine heat pumps (GEHPs) are presented based on energy and mass balance equations as well as the gas engine operating parameters (such as thermal efficiency, fuel consumption and fuel mass flow rate) and heat pump operating parameters (such as evaporator and condenser capacity and compressor input power). Based on the modeling results and with estimating GEHP fuel consumption, the economic analysis of using gas engine heat pumps (in comparison with the electrical heat pumps) at various climate regions of Iran, for both residential and commercial (office) buildings, and for both cooling and heating modes, was performed. Appropriate cost functions for predicting GEHP capital investment were proposed. Three approaches including equivalent uniform annual cost (EUAC), the annual cost of energy consumption, and payback period were applied in the economic analysis.     

Fabrication of platinum coated nanoporous gold film electrode: A nanostructured ultra low-platinum loading electrocatalyst for hydrogen evolution reaction

The electrolytic hydrogen evolution reaction (HER) on platinum coated nanoporous gold film (PtNPGF) electrode is demonstrated. The deposition of platinum occurred as a spontaneous redox process in which a copper layer, obtained by underpotential deposition, was oxidized by platinum ions, which were reduced and simultaneously deposited. The present method could provide a very low Pt-loading electrode and the results demonstrated that ultra thin Pt coating effected efficiently and behaved as the nanostructured Pt for electrocatalytic hydrogen evolution reaction. The loading of Pt was calculated as 4.2 × 10⁻³ μg cm⁻² for PtNPGF electrode. The current density at −0.4 V and −0.8 V vs. Ag/AgCl was as high as 0.66 A μg⁻¹ Pt and 3 A μg⁻¹ Pt, respectively and the j₀ was evaluated as 0.03 mA cm⁻² or 8 mA μg⁻¹ Pt. The results indicated that increasing electrode area had no catalytic effect, but the nanostructure nature of as-fabricated electrode and submonolayer deposition of copper resulted in electrocatalytic activity for PtNPGF electrode.     

Thermoeconomic optimization of an ice thermal storage system for gas turbine inlet cooling

The gas turbine power output and efficiency decrease with increasing ambient temperature. With compressor inlet air cooling, the air density and mass flow rate as well as the gas turbine net power output increase. The inlet cooling techniques include vapor or absorption refrigeration systems, evaporative cooling systems and thermal energy storage (TES) systems. In this paper the thermoeconomic analysis of ice (latent) thermal energy storage system for gas turbine inlet cooling application was performed. The optimum values of system design parameters were obtained using genetic algorithm optimization technique. The objective function included the capital and operational costs of the gas turbine, vapor compression refrigeration system, without (objective function I) and with (objective function II) corresponding cost due to the system exergy destruction. For gas turbines with net power output in the range of 25-100 MW, the inlet air cooling using a TES system increased the power output in the range of 3.9-25.7%, increased the efficiency in the range 2.1-5.2%, while increased the payback period from about 4 to 7.7 years.     

Analysis of gas turbine operating parameters with inlet fogging and wet compression processes

Inlet fogging has been widely noticed in recent years as a method of gas turbine air inlet cooling for increasing the power output in gas turbines and combined cycle power plants. The effects of evaporative cooling on gas turbine performance were studied in this paper. Evaporative cooling process occurs in both compressor inlet duct (inlet fogging) and inside the compressor (wet compression). By predicting the reduction in compressor discharge air temperature, the modeling results were compared with the corresponding results reported in literature and an acceptable difference percent point was found in this comparison. Then, the effects of both evaporative cooling in inlet duct, and wet compression in compressor, on the power output, turbine exhaust temperature, and cycle efficiency of 16 models of gas turbines categorized in four A–D classes of power output, were investigated. The results of this analysis for saturated inlet fogging as well as 1% and 2% overspray are reported and the prediction equations for the amount of actual increased net power output of various gas turbine nominal power output are proposed. Furthermore the change in values of physical parameters and moving the compressor operating point towards the surge line in compressor map was investigated in inlet fogging and wet compression processes.     

Numerical Study of Reinforced Soil Segmental Walls Using Three Different Constitutive Soil Models

A numerical finite-difference method (FLAC) model was used to investigate the influence of constitutive soil model on predicted response of two full-scale reinforced soil walls during construction and surcharge loading. One wall was reinforced with a relatively extensible polymeric geogrid and the other with a relatively stiff welded wire mesh. The backfill sand was modeled using three different constitutive soil models varying as follows with respect to increasing complexity: linear elastic-plastic Mohr-Coulomb, modified Duncan-Chang hyperbolic model, and Lade’s single hardening model. Calculated results were compared against toe footing loads, foundation pressures, facing displacements, connection loads, and reinforcement strains. In general, predictions were within measurement accuracy for the end-of-construction and surcharge load levels corresponding to working stress conditions. However, the modified Duncan-Chang model which explicitly considers plane strain boundary conditions is a good compromise between prediction accuracy and availability of parameters from conventional triaxial compression testing. The results of this investigation give confidence that numerical FLAC models using this simple soil constitutive model are adequate to predict the performance of reinforced soil walls under typical operational conditions provided that the soil reinforcement, interfaces, boundaries, construction sequence, and soil compaction are modeled correctly. Further improvement of predictions using more sophisticated soil models is not guaranteed.