δ-Tocomonoenol: A new vitamin E from kiwi (Actinidia chinensis) fruits

A new vitamin E, δ-tocomonoenol, has been isolated from Actinidia chinensis (kiwi) fruits. The new structure, 2,8-dimethyl-2-(4,8,12-trimethyltridec-11-enyl)chroman-6-ol, has been elucidated on the basis of EIMS, 1D, and 2D NMR spectral data. GC–MS analysis of peels and pulps of kiwi showed that the new compound, together with δ-tocopherol, is mainly present in the fruit peel, whilst α-tocopherol is present in a similar amount in both matrices. The compound was tested for its radical-scavenging and antioxidant capabilities, by measuring its ability to scavenge DPPH (2,2′-diphenyl-1-picrylhydrazyl radical) and anion superoxide radical, and inhibit the formation of methyl linoleate conjugated diene hydroperoxides and TBARS (thiobarbituric acid reactive species).     

Performance and robustness of block constraint preconditioners in finite element coupled consolidation problems

Block constraint preconditioners are a most recent development for the iterative solution to large‐scale, often ill‐conditioned, coupled consolidation problems. A major limitation to their practical use, however, is the somewhat difficult selection of a number of user‐defined parameters (at least 4) in a more or less optimal way. The present paper investigates the robustness of three variants of the block constraint preconditioning in relation to the above parameters. A theoretical analysis of the eigenspectrum of the preconditioned matrix provides relatively simple bounds of the eigenvalues as a function of these parameters. A number of test problems used to validate the theoretical results show that both the mixed constraint preconditioner (MCP) combined with the symmetric quasi‐minimal residual (SQMR) solver and the MCP triangular variant (T‐MCP) combined with the bi‐conjugate gradient stabilized (Bi‐CGSTAB) are efficient and robust tools for the solution to difficult Finite Element‐discretized coupled consolidation problems. Moreover, the practical selection of the user‐defined parameters is relatively easy as a stable behavior is observed for a wide range of fill‐in degree values. The theoretical bounds on the eigenspectrum of the preconditioned matrix may help to suggest the most appropriate parameter combination. Copyright © 2009 John Wiley & Sons, Ltd.     

Computational flowfield analyses of hypersonic problems with reacting boundary layer

A mathematical model able to deal with high temperature gas effects in hypersonic flow fields is presented. In order to assess this model, four typical hypersonic applications are considered. The numerical results are presented and compared with experimental data. The effects of the catalyticity of the materials on the heat fluxes are also highlighted.     

A combined approach for characterisation of fresh and brined vine leaves by X-ray powder diffraction,NMR spectroscopy and direct infusion high resolution mass spectrometry

X-ray powder diffraction was combined, for the first time, with Nuclear Magnetic Resonance spectroscopy and direct infusion mass spectrometry to characterise fresh and brined grape leaves. Covariance analysis of data generated by the three techniques was performed with the aim to correlate information deriving from the solid part with those obtained for soluble metabolites. The results obtained indicate that crystalline components can be correlated to the metabolites contained in the grape leaves, paving the way to the use of X-ray diffraction analysis for food fingerprinting purposes. Moreover it was ascertained that, differently from most of the metabolites present in the fresh vine leaves, linolenic acid (an omega-3-fatty acid) and quercetin-3-O-glucuronide (a polyphenol metabolite) do not undergo sensible degradation during the brining process, which is used as preservative method for the grape leaves.     

Microdroplet-based multiplex PCR on chip to detect foodborne bacteria producing biogenic amines

The development of fast, reliable and culture-independent molecular tools to detect bacteria producing biogenic amines deserves the attention of research and ultimately of the food industry in order to protect consumers' health. Here we present the application of a simple, low-cost, fast and sensitive method to perform microdroplet-based multiplex PCR, directly on a food matrix, for the simultaneous detection of bacterial genes involved in biogenic amine biosynthesis. After inoculating wine with Lactobacillus brevis IOEB 9809, cell lysis and DNA amplification are performed in one single step, without preliminary nucleic acid extraction or purification treatments. The assay is performed in about 30 min, requiring 150 nL of starting sample and it enables the detection of down to 15 bacterial cells. With respect to traditional culture techniques, the speed, the simplicity and the cheapness of this procedure allow an effective monitoring of microbial cells during food-making and processing.     

A non-conventional approach for crack problems in piezoelectric media under electromechanical loading

In this paper the elastostatic solution of an inclined crack problem has been analyzed. The approach is analogous to the one proposed over the past years for orthotropic materials by Piva andViola (1988) (Eng Fract Mech, 29: 535–548), and it may be considered an alternative to the mathematical formalisms currently used. A general expression of the stress field is determined in terms of complex potentials. The stress distribution and the displacement field in the proximity of the crack tip are finally obtained. An expression of the energy release rate is provided in terms of the field intensity factors. Numerical results are presented and discussed under different remote electro-mechanical loading conditions and varying the crack inclination. Particular attention has been focused on the effect of the lateral load on the fracture quantities and on the direction of the incipient branching angle.     

Combined Effects of Parallel and Series Detention Basins for Flood Peak Reduction

A simple analytical method is proposed that allows a preliminary evaluation of the overall efficiency of a detention basin system for flood risk reduction in a specific target section. Solutions are provided both for parallel and series systems, under some simplifying assumptions concerning the linearity of detention basin, river network and watershed responses. Further, for the series configuration a regressive model is proposed for the computation of the overall efficiency, because of the complexity of analytical solution. A case study is also presented, where the overall efficiency of a system of nine detention basins is computed by means of both the analytical and the regressive model. Results are discussed to assess the different influence of detention basins in parallel or in a series system.     

Special Issue: Water Engineering and Management in a Changing Environment

The paper is the introduction to the special issue Water Engineering and Management in a Changing Environment which presents a set of the most innovative contributions at the EWRA Symposium, held in Catania, Italy on 2011.