Unveiling the role of Fe3O4in polymer spin valve near Verwey transition

The spinterface formed between ferromagnetic(FM)electrode and organic materials is vital for performance optimization in organic spin valve(OSV).Half-metallic Fe₃O₄with drastic change in structure,conductivity and magnetic property near Verwey transition can serve as an intrinsic spinterface regulator.However,such modulating effect of Fe₃O₄in OSV has not been comprehensively investigated,especially below the Verwey transition temperature(Tv).Here,we highlight the important role of Fe₃O₄electrode in reliable-working and controllable Fe₃O₄/P3HT/Co polymer spin valves by investigating the magnetoresistance(MR)above and below 7V.In order to distinguish between different contributions to charge transport and related MR responses,the systematic electronic and magnetic characterizations were carried out in full temperature range.Particularly,the first-order metal-insulator transition in Fe₃O₄has a dramatic effect on the MR enhancement of polymer spin valves at 7V.Moreover,both the conducting mode transformation and MR line shape modulation could be accomplished across 7V.This research renders unique scenario to multimodal storage by external thermodynamic parameters,and further reveals the importance of spin-dependent interfacial modification in polymer spin valves.     

单相硼化物的制备及摩擦磨损性能研究

为了深入研究渗硼层中硼化物的性能，采用真空感应熔炼法制备单相硼化物材料。观察分析制备的硼化物微观组织，测试其力学性能。采用MMU-5G型销-盘式摩擦磨损试验机，在干摩擦条件下，研究了不同载荷下单相硼化物的摩擦学性能，观察其磨损表面形貌特征，探讨其磨损方式。结果表明：制备的硼化物为单一相，试样纯度高，试样的平均显微硬度为HV2065，平均断裂韧性值为1.68 MPa·m1/2；硼化物的断口处没有宏观的塑性变形，断口齐平光亮，表现为脆性断裂特征；干摩擦条件下随着载荷从10 N增加到30 N，硼化物的摩擦因数先降低后增加，20 N载荷时达到最小值，而其磨损量随着载荷的增加不断上升；随着载荷从10 N增加到30 N，磨损表面的粗糙度先逐渐上升后急剧上升； 10~20 N载荷下，硼化物的磨损以磨粒磨损为主，而25~30 N载荷下，硼化物的主要磨损方式从磨粒磨损转变为脆性破损。     

Multi-objective layout optimization for an orbital propellant depot

Structural and Multidisciplinary Optimization - The overall layout optimization design of an orbital propellant depot involves the optimization of shape, size, and positions of propellant tanks in...     

氢化物原子荧光光谱法测定酱油中微量铅的方法研究

建立了一种快速、高效的QuEChERS-高效液相色谱-质谱联用法（QuEChERS-HPLC-MS/MS）测定谷类杂粮制品中脱氧雪腐镰刀菌烯醇（DON）、3-乙酰脱氧雪腐镰刀菌烯醇（3-ADON）、15-乙酰脱氧雪腐镰刀菌烯醇（15-ADON）和玉米赤霉烯酮（ZON）共4种真菌毒素。样品前处理采用乙腈-水溶剂提取，经Florisil+C18+无水硫酸镁净化后检测。以0.10%甲酸-乙腈作为流动相，在质谱检测器的多反应监测模式下进行分析。结果表明，4种真菌毒素在各自的线性范围内线性关系良好，相关系数R2均大于0.999，回收率在85.1%～102.0%，相对标准偏差（RSD）为2.11%～6.22%。该方法具有前处理简单、净化效果好、灵敏度高和检测速度快的优点，适用于谷类杂粮制品中DON、3-ADON、15-ADON 和ZON的分析和定量检测。     

数据挖掘技术在软件系统中的应用

随着高新科学技术的发展,科学家研究出的利于人类工作生活的技术程序越来越多,大部分技术主要集中在如何帮助人们简化平时的工作量,能快速查找到自己所需要的信息,毕竟现代社会,工作效率和工作质量是关键。数据挖掘技术就具备这样的特点,数据挖掘技术在软件系统的应用将大大降低我们的工作量,提高我们的工作效率。现在我们研究数据挖掘技术在软件系统的应用,分析它是如何发挥其作用的,希望能提高使用该挖掘技术人员的使用效率。     

Facile construction of composition-tuned ruthenium-nickel nanoparticles on g-C3N4 for enhanced hydrolysis of ammonia borane without base additives

Developing high-efficiency and low-cost catalysts for hydrogen evolution from hydrolysis of ammonia borane (AB) is significant and critical for the exploitation and utilization of hydrogen energy. Herein, the in-situ fabrication of well-dispersed and small bimetallic RuNi alloy nanoparticles (NPs) with tuned compositions and concomitant hydrolysis of AB are successfully achieved by using graphitic carbon nitride (g-C₃N₄) as a NP support without additional stabilizing ligands. The optimized Ru₁Ni_7.5/g-C₃N₄ catalyst exhibits an excellent catalytic activity with a high turnover frequency of 901 min^?1 and an activation energy of 28.46 kJ mol^?1 without any base additives, overtaking the activities of many previously reported catalysts for AB hydrolysis. The kinetic studies indicate that the AB hydrolysis over Ru₁Ni_7.5/g-C₃N₄ is first-order and zero-order reactions with respect to the catalyst and AB concentrations, respectively. Ru₁Ni_7.5/g-C₃N₄ has a good recyclability with 46% of the initial catalytic activity retained even after five runs. The high performance of Ru₁Ni_7.5/g-C₃N₄ should be assigned to the small-sized alloy NPs with abundant accessible active sites and the synergistic effect between the composition-tuned Ru–Ni bimetals. This work highlights a potentially powerful and simple strategy for preparing highly active bimetallic alloy catalysts for AB hydrolysis to generate hydrogen.