Preparation of molecularly imprinted fluorescence sensor based on carbon quantum dots via precipitation polymerization for fluorescence detection of tetracycline

A facile and effective method was proposed to prepare the molecularly imprinted fluorescence sensor with carbon quantum dots, which were modified vinyl groups by acrylic acid on the surface. The obtained fluorescence composite material was investigated by transmission electron microscope and Fourier transform infrared spectra. After the experimental conditions were optimized, a linear range of 1.0–60 μmol L⁻¹ was obtained and the detection limit was 0.17 μmol L⁻¹. The novel fluorescence sensor can be successfully used to detect tetracycline in real samples. This study provides a convenient strategy for selective recognition and rapid detection of tetracycline in the complex environment.     

Polymer hydrogel cross-linked by inorganic nanoparticles for removing trace metal ions

Hydrogels for absorbing metal ions in wastewater have attracted more attentions in the environmental field especially for recent years. The removal efficiency of hydrogel adsorbents for eliminating metal ions is highly related with the effective contact between adsorbents and adsorbates. However, poor water absorption capacity of the hydrogel adsorbents would restrict on the expose of adsorption sites to the targeted subjects, causing undesirable removal ratio (RR) especially for metal ions at trace level. Thereby, the reported hydrogel adsorbents mainly focus on the removal of high content but not the trace level of metal ions so far. In this work, poly(acrylamide) (PAM)/poly(acrylic acid) (PAA)/Ca(OH)₂ composite hydrogel is applied to adsorb trace metal ions. Swelling ratio of such PAM/PAA/Ca(OH)₂ gel reaches 2,530 g/g, resulting in effective exposure of active sites and further expected RR for trace metal ions. The RRs of such adsorbent for Cu²⁺ (initial concentration C₀ = 0.064 mg/L), Al³⁺ (C₀ = 0.27 mg/L), Co²⁺ (C₀ = 0.59 mg/L), Cr⁶⁺ (C₀ = 0.52 mg/L), Mn²⁺ (C₀ = 0.55 mg/L), Ni²⁺ (C₀ = 0.59 mg/L), Zn²⁺ (C₀ = 0.65 mg/L), Ag⁺ (C₀ = 1.08 mg/L), and La³⁺ (C₀ = 1.39 mg/L) are 56.6, 80.8, 41.3, 29.3, 34.6, 44.6, 55.9, 45.8, and 35.5%, respectively. This work broadens the application of hydrogel adsorbent for eliminating trace metal ions from polluted water.     

High-Tg porous polyimide films with low dielectric constant derived from spiro-(adamantane-2,9′(2′,7′-diamino)-fluorene)

Porous polyimide (PI) films with low dielectric constants and excellent thermal properties have been a pressing demand for the next generation of high-performance, miniature, and ultrathin microelectronic devices. A series of novel porous PI films containing fluorenyl-adamantane groups were prepared successfully via thermolysis of poly(ethylene glycol) (PEG) added in the PI matrix. The cross-sectional morphologies of porous PI films showed closed pores with diameters ranging from 135 to 158 nm, which were uniform and regular in shape without interconnectivity. These porous PI films exhibited excellent thermal properties with a glass-transition temperature at 376 °C whereas the 5% weight loss temperature in air excess of 405 °C due to enhanced rigidity afforded by fluorenyl-adamantane groups. Accompanied by thermolysis content of PEG increasing from 0 to 20 wt %, the density of porous PI films decreased, and the corresponding porosity grew significantly from 0 to 11.48%. Depending on porosity, the dielectric constant and dielectric loss of porous PI films significantly declined from 2.89 to 2.37 and from 0.050 to 0.021, respectively. These excellent properties benefit the as-prepared porous PI films for application as interlayer dielectrics, integrated circuit chips, or multichip modules in microelectronic fields. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47313.     

具有底水边界的水平井压力不稳态特征分析及认识

根据水平井三维渗流特征，在底水油藏情形仍假定顶面为不渗透隔层所封闭，底部则是恒压边界，水平井渗流表现为早期径向流以及稳定流动期，由此进行常规试井分析。以TKxxDH井为例，通过水平井的静压、压恢试井资料结果的对比分析，阐述了不稳定试井资料的应用，为此类油藏油井模型的选择及效果评价提供了可借签的经验。     

大牛地气田气井无阻流量的确定方法研究

大牛地气田气井试井大多采用一点法，由于气层渗透性差，测试时间短，流压很难达到稳定，计算的无阻流量往往偏高，且无法获得正确的产能方程。通过气田多口井修正等时试井数据进行统计分析，获得了一点法试井在不同生产时间下计算无阻流量的经验公式；利用气田修正等时试井的二项式方程系数曰，计算惯性阻力系数并经过曲线回归处理获得了经验关系式，很好地解决了一点法试井计算产能方程的问题。     

分组密码算法芯片验证

介绍了分组密码算法芯片验证的流程、内容和方法,详细介绍了分组密码算法芯片的验证技术——测试基准。     

共面波导(CPW)馈电单极子天线的设计与研究

给出一种工作于900MHz的共面波导(CPW)馈电单极子天线的设计。该单极子天线以共面波导的中心导带为辐射单极子，以中心导带两边的金属导体作反射板，结构简单紧凑。但是由于天线与共面波导之间缺少有效的隔离，造成天线性能受共面波导尺寸的影响较严重。本文通过模拟计算和实验测量详细分析了共面波导尺寸的变化对天线性能的影响，给出了结合共面波导尺寸设计的工作在900MHz的单极子天线结构数据。     

减粘裂化分馏塔顶系统的腐蚀及防护

辽河石化分公司减粘裂化装置改炼辽河超稠油的减压渣油后 ,分馏塔顶系统由HCl -H2 S -HCN -有机酸 -H2 O引起的电化学腐蚀严重 ,其中油水分离器局部腐蚀速率达 3.1mm/a ,12AlMoV管束的空冷器运行不足两个月即发生泄漏。塔顶系统采用BZH - 1中和缓蚀剂、无机氨BZH - 913油溶性缓蚀剂综合注剂方案 ,使腐蚀得到控制     

西门子全集成自动化理念初探

系统阐述了全集成自动化理念的内涵，指出其特点在于统一的数据管理、统一的编程组态、统一的通讯以及无与伦比的开放性，其中采用WINCC与STEP7两个软件进行了说明，井提出全集成自动化应用将是今后自动化技术发展应用的方向。