Two superparamagnetic and heat resistant xanthene based poly(ether-imide) nanocomposites were successfully synthesized. Field emission scanning electron microscopy, transmission electron microscope, X-ray diffraction, thermal gravimetric analysis, vibrating sample magnetometer, Energy-dispersive X-ray spectroscopy and Fourier-transform infrared (FTIR) techniques were used for studying the morphology, crystalline phase, thermal stability and magnetization properties of the nanocomposites. The neat form of the corresponding poly(ether-imide) was also prepared by thermal imidization method and its structure was confirmed by FTIR, proton nuclear magnetic resonance (
1H NMR), UV–Vis and photoluminescence (PL) spectroscopies. In order to investigate the effects of modifying the surface of Fe
3O
4 nanoparticles on thermal properties of the nanocomposites, the surface of Fe
3O
4 nanoparticles was coated with SiO
2 and polysuccinimide (PSI), sequentially. Then, both the unmodified Fe
3O
4 and surface-modified Fe
3O
4 (Fe
3O
4@SiO
2–PSI) nanoparticles were used as fillers for the polymer matrix. According to the results, the prepared nanocomposites were superparamagnetic and showed higher thermal stability in comparison to the neat poly(ether-imide). Furthermore, poly(ether-imide)/Fe
3O
4@SiO
2–PSI (PIEN 10b) nanocomposite showed higher thermal stability and dispersed better in the polymer matrix [in comparison to poly(ether-imide)/Fe
3O
4 (PIEN 10 a)] due to the presence of imide groups and high hydroxyl content of the functional Fe
3O
4 nanoparticles which caused high interactions between poly(ether-imide) and functional Fe
3O
4. Furthermore, the presence of methyl, ether and bulky xanthene groups in the poly(ether-imide(backbone improved the solubility of the neat polymer in organic solvents. These properties can be very helpful for extending new applications of poly(ether-imide)s.
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