Analysis of Phytochemical Composition of Camellia oleifera Oil and Evaluation of its Anti-Inflammatory Effect in Lipopolysaccharide-Stimulated RAW 264.7 Macrophages

In China, Camellia oleifera oil (COO) is not only a common edible oil but also a traditional remedy widely applied to ameliorate a variety of illnesses associated with inflammation, such as mouth ulcers, thrush, eczema, etc. However, there has been a lack of relevant biological research on the anti-inflammatory capacity of COO, and the specific bioactive lipid phytochemicals contributing to the anti-inflammatory effect need further research. In this study, the RAW 264.7 macrophages model was used to investigate the anti-inflammatory capacity of COO. Our data showed that 33–200 μg/mL COO markedly inhibited the lipopolysaccharide lipopolysaccharide (LPS)-stimulated nitric oxide (NO.) secretion via the suppression of Nos2 and Cox-2 expression. The enzyme immunoassay confirmed that COO also exhibited a strong suppressive effect on the expression of proinflammatory cytokines such as Tnf-α and Il-6. To further explore the correlation between the anti-inflammatory effects and the lipid phytochemicals in COO, 10 samples were collected and screened for their chemical compositions. It was interestingly demonstrated that the polyphenol extracts of COO play a vital role in its anti-inflammatory properties. In addition, an oil-in-water (O/W) emulsion-based system was also developed to deliver the liposoluble COO into the cells, and the feasibility of this system was confirmed. Our research confirms the anti-inflammatory potential of COO and highlights that the main functional ingredient is polyphenol extracts. This may provide a scientific basis for the comprehensive utilization and development of COO and related functional foods.     

古建筑木结构透榫节点力学模型研究

为研究古建筑木结构透榫节点的M-θ力学模型，在分析透榫节点构造特征与受力机理的基础上，建立其数值模型，用透榫节点的试验数据验证了该数值模型的正确性，并分析了节点缝隙、木材横纹弹性模量和大榫头长度对透榫节点受弯承载力的影响。根据受力分析结果，建立以弹性点、屈服点与极限点为特征点的三折线多参数M-θ力学模型，其结果与多数的试验结果基本吻合，并将该力学模型应用于木构架的受力分析。研究结果表明：透榫节点的滞回耗能能力强，节点的变形主要集中在榫头处。当榫头与卯口之间的缝隙增大时，节点的受弯承载力降低。随木材横纹弹性模量的提高和大榫头长度的增加，节点的受弯承载力有一定提高。文章建立的M-θ力学模型能较好反映透榫节点的受力过程，适用于木构架的受力分析，其荷载 位移骨架曲线与试验结果基本吻合。研究成果可为古建筑木结构的维修与保护提供参考。     

Fine-tuned,molecular-composite,organosilica membranes for highly efficient propylene/propane separation via suitable pore size

Fine-tuned, molecular-composite, organosilica membranes were fabricated via the co-condensation of organosilica precursors bis(triethoxysilyl)acetylene (BTESA) and bis(triethoxysilyl)benzene (BTESB). Fourier transform infrared and UV–vis spectra confirmed the co-condensation behaviors of BTESA and BTESB. The evolution of the network structure indicated that the incorporated BTESB decreased the membrane pore size, which was determined by a modified gas translation model according to the steric effect of the phenyl groups. The incorporation of BTESB to BTESA finely tuned the membrane structure and endowed the resultant composite membrane with improved separation properties. The BTESAB 9:1 membrane (molar ratio of BTESA/BTESB was 9:1) exhibited high C₃H₆ permeance at 4.5 × 10⁻⁸ mol m⁻² s⁻¹ Pa⁻¹ and a C₃H₆/C₃H₈ permeance ratio of 33 at 50°C. One of the most important developments of this study involved clearly defining the relationship between membrane pore size and C₃H₆/C₃H₈ separation performance for organosilica membranes in single and binary separation systems.     

含钒废弃物中钒的回收研究现状及展望

金属钒具备一系列优越性质,在许多领域有着广泛的应用。综述了从含钒钢渣、提钒尾渣、失活催化剂以及钒电池失效电解液等含钒废弃物中回收钒的方法,主要阐述了各种方法的原理、优缺点及发展趋势,介绍了回收钒的新工艺并指出提钒工艺的未来发展方向。     

铝碳质长水口用低铝抗氧化涂层的研制

为抑制铝碳质长水口使用过程中石墨的氧化，其表面会涂覆含 20%~30%Al₂O₃的抗氧化涂层，但切割丝钢等特种钢冶炼过程必须严格控制钢液中夹杂的 Al₂O₃的含量，因此需要制备低氧化铝含量的抗氧化涂层。本文通过调节涂料组成、加水量和水玻璃加入量制备了低铝抗氧化涂层，并利用扫描电镜分析了抗氧化实验后试样断口的显微结构。结果表明：以粘土粉、钾长石粉和硅砂为主要原料，添加 10%硼砂的涂料可在 800 ℃形成良好的釉层，此时涂料中 A12O3的含量可降至 12%，得到了低铝涂料；当加入占涂料质量 80%的水和 40%的水玻璃时，涂层具有最佳的涂覆性能和抗氧化性能，涂层和长水口基体结合致密，保护了长水口中的石墨不被氧化。     

Effects of structural characteristics on microwave dielectric properties of low-loss (Zn1-xNix)ZrNbTaO8 ceramics

Low-loss (Zn_1-xNi_x)ZrNbTaO₈ (0.02?≤?x?≤?0.10) ceramics possessing single wolframite structure are initiatively synthesized by solid-state route. Based on the results of Rietveld refinement, complex chemical bond theory is used to establish the correlation between structural characteristics and microwave performance in this ceramic system. A small amount of Ni²⁺ (x?=?0.06) in A-site with the fixed substitution of Ta⁵⁺ in B-site can effectually raise the Q?×?f value of ZnZrNb₂O₈ ceramic, embodying a dense microstructure and high lattice energy. The dielectric constant and τ_f are mainly affected by bond ionicity and the average octahedral distortion. The (Zn_0.94Ni_0.06)ZrNbTaO₈ ceramic sample sintered at 1150?°C for 3?h exhibits an outstanding combination of microwave dielectric properties: ε_r =?27.88, Q?×?f?=?128,951?GHz, τ_f =?–39.9?ppm/°C. Thus, it is considered to be a candidate material for the communication device applications at high frequency.     

Dependence of Lamellar Eutectic Growth with Convection on Boundary Conditions and Geometric Confinement: A Phase-Field Lattice-Boltzmann Study

Metallurgical and Materials Transactions B - Simulating eutectic growth with convection is challenging because of the enormous computing demand resulting from the required domain size compared with...     

乌拉根锌矿排土场稳定性分析

排土场的稳定性研究是露天矿山安全性管理的重点，也是矿山可持续发展的关键。以乌拉根锌矿排土场为例，在岩土工程勘察的基础上，利用Geo slope软件，运用极限平衡法和有限元法对排土场边坡危险剖面在正常工况下及降雨入渗工况下的稳定性进行数值模拟。计算结果表明，正常工况下，边坡处于基本稳定状态；降雨入渗后，边坡安全系数降低3.9%，处于欠稳定状态，应加强排土场降雨预报和监测管理。